Use of the light absorption coefficient to monitor elemental carbon and PM2.5--example of Santiago de Chile

The optical absorption coefficient, particulate matter with an aerodynamic diameter <2.5 microm, and elemental carbon (EC) have been measured simultaneously during winter and spring of 2000 in the western part of Santiago, Chile (Pudahuel district). The optical measurements were carried out with a low-cost instrument recently developed at the University of Santiago. From the data, a site-specific mass absorption coefficient of 4.45+/-0.01 m2/g has been found for EC. In addition, a mass absorption coefficient of 1.02+/-0.03 m2/g has been obtained for PM2.5. These coefficients can be used during the colder months (May-August) to obtain EC concentration or PM2.5 from a measurement of the light absorption coefficient (sigmaa). The high correlation that has been found between these variables indicates that sigmaa is a good indicator of the degree of contamination of urbanized areas. The data also show an increase in PM2.5 and EC concentration during winter and an increase in the ratio of EC to PM2.5. When the EC/PM2.5 ratio is calculated during rush hour (7:00 a.m.-11:00 a.m.) and during part of the night (9:00 p.m.-2:00 a.m.), it is found that the increase is caused by higher concentration levels of EC at night. These results suggest that the rise in the EC concentration is caused by emissions from heating and air mass transport of pollution from other parts of the city, while traffic contribution remains approximately constant.     

Ecotoxicological studies of environmental samples from Buenos Aires area using a standardized amphibian embryo toxicity test (AMPHITOX).

The toxicity of 34 environmental samples from potentially polluted and reference stations were evaluated by means of the AMPHITOX test from acute to chronic exposure according to the toxicity found in each sample. The samples were obtained from surface and ground water, leaches, industrial effluents and soils. The data, expressed in acute, short-term chronic and chronic Toxicity Units (TUa, TUstc and TUc) resulted in a maximal value of 1000 TUc, found in a leach, while the lower toxicity value was 1.4 TUa corresponding to two surface water samples. In five samples (four providing from reference places) no toxicity was detected. The results point out the possibility of evaluating the toxicity of a wide diversity of samples by means of AMPHITOX as a customized toxicity test. The fact that almost all samples with suspected toxicity in rivers and streams from the Metropolitan area of Buenos Aires city resulted toxic, indicates the need of enhanced stewardship of chemical substances for environmental and human health protection purposes.     

Pesticide levels in surface waters in an agricultural-forestry basin in Southern Chile

Residues of five pesticides in surface water were surveyed during 2001 and 2003 in the Traiguen river basin in Southern Chile. Simazine, hexazinone, 2,4-D, picloram herbicides and carbendazim fungicide were selected through a pesticide risk classification index. Six sampling stations along the river were set up based on agricultural and forestry land use. The water sampling was carried out before and after the pesticide application periods and in correspondence to some rain events. Pesticides were analyzed by HPLC with DAD detection in a multiresidue analysis. During 2001, in the first sampling campaign (March), the highest concentrations of pesticides were 3.0 microg l(-1) for simazine and hexazinone and 1.8 microg l(-1) for carbendazim. In the second sampling (September), the highest concentration were 9.7 microg l(-1) for 2,4-D, 0.3 microg l(-1) for picloram and 0.4 microg l(-1) for carbendazim. In the last sampling period (December), samples indicated contamination with carbendazim fungicide at levels of up to 1.2 microg l(-1). In sampling carried out on May 2003, no pesticides were detected. In October 2003, the highest concentrations of pesticides were 4.5 microg l(-1) for carbendazim and 2.9 microg l(-1) for 2,4-D. Data are discussed in function of land use and application periods of the products, showing a clear seasonal pattern pollution in the Traiguen river. Risk assessment for these pesticides was calculated by using a risk quotient (RQ = PNEC/PEC). For picloram the calculated RQ < was 0, which indicates that no adverse effects may occur due to the exposure to this herbicide in the Traiguen river basin. For 2,4-D, simazine, hexazinone, carbendazim RQ > 1, meaning that adverse effects could occur and it is necessary to reduce pesticide exposure in surface waters. It is recommended to continue with a pesticide monitoring program and the implementation of ecotoxicological testing with local and standardized species in order to consider the probability of effects occurrence, with less uncertainty. Thus, it will be more feasible to make some recommendations to regulatory agencies regarding the pesticide use.     

Biogas upgrading by cryogenic techniques

Environmental Chemistry Letters - The scarcity of fossil fuels and the worldwide pollution have led the scientific community to seek renewable energy alternatives. In particular, biogas has become...     

Educating citizens about their coastal environments: beach profiling in the Coastwatch project

The Coastwatch (CW) project is aimed at monitoring the coastline with the involvement of volunteers. Between 2003 and 2007 a beach profiling method was informally proposed to CW participants in Portugal as an extra activity to include in the surveys. Beach profiling contributes to a better understanding of coastal processes by providing quantitative information on the spatial/temporal evolution of beaches, which is crucial for coastal management. The profiling method proposed to the CW project is based on the physical principle of communicating vessels, and only requires a simple and inexpensive homemade ??profiler??. The simplicity of putting together and using the profiler, added to the arithmetic straightforwardness of data analysis, makes this method adequate for several kinds of users and for most levels of education. Eight workshops were held that included a classroom explanation of the method, the construction of a profiler, the actual profiling of a beach, and a final classroom session of data processing and graphing. About 140 participants received such training, and several among them independently undertook beach profiling. Surveyed participants found the workshop and the beach profiling method interesting and useful, and considered it a valuable tool for teaching and for management. External stakeholders (coastal managers) highlighted the importance of beach profiling data for management decisions and considered that this method produces robust data, even when carried out by volunteers. Further advantages of the application of the method, in the context of coastal management initiatives, for scientists, managers, and volunteers are discussed.     

Space for equity: socioeconomic variations in the provision of public parks in Hermosillo,Mexico

This article examines the intersection between globalisation and allocation of open public space by testing the spatial equity hypothesis in Hermosillo, Mexico, a regional city impacted directly by global processes. Availability and accessibility of public parks were examined using a geographic information system and neighbourhoods were stratified into quintiles based on socioeconomic status. Overall, the analysis shows that the amount of public park space in Hermosillo is substandard and its distribution reveals a pattern of spatial inequity affecting primarily residents of poor neighbourhoods. We argue that as the economy of the city grows increasingly integrated into global circuits, the global-to-local connection materialises in an unequal competition between globalised spaces and local public space. This, in turn, leads to further relegation of neighbourhoods that are already on the margins of urban equity regarding access to public parks. This study extends prior research conducted in developed countries to a city in a developing nation and fills a vacuum of information that potentially can contribute to a more equitable development in Hermosillo.