Design and field application of an automated cartridge sampler for VOC concentration and flux measurements

One of the major limitations in advancing the understanding of tropospheric ozone and aerosol generation and developing strategies for their control is the technical ability to accurately measure volatile organic compounds (VOCs). This paper describes the design of a constant flow VOC sampler. The versatile sampler can be used for fully automated concentration and flux measurements of VOCs. The sampler incorporates a microprocessor control unit and provides highly accurate mass flow control and significant ease of operation. Sampling sequences can be programmed directly or by remote control through a PC. All important operational parameters necessary for a complete sampling audit trail are logged. Compact weatherproof housings and low power consumption allow operation at remote sites and locations which are sensitive to disturbances or have restricted access. Inner wetted surfaces of the sampler are constructed from non-contaminating materials that do not sorb or emit VOC, and thus permit the collection of representative samples even in environments with very low VOC concentrations. The cartridge magazine provides a maximum of 20 sequential cartridge samples, which allows for long-term air quality assessments. In the dual channel mode, two samples can be collected simultaneously through two independent sample loops, providing ten sequential sample pairs. This design allows the parallel collection of (a) quality assurance backup samples, (b) samples on two different types of cartridges/sorbents to allow a variety of analyses, or (c) differential samples for flux measurements using enclosure, aerodynamic profile, or relaxed eddy accumulation (REA) methods. Field applications including airplane profile measurements above a tropical rainforest area, as well as gradient and REA measurements over a mid-latitude mixed forest stand are described, and demonstrate the validity and flexibility of the system. In particular, the application of the VOC sampler as an integrated part of a REA system is emphasized.     

Speciation of nickel in Canadian subbituminous and bituminous feed coals, and their ash by-products

The nickel species in the feed coals and ash by-products from seven Canadian power plants (including one with a fluidized bed combuster) burning local subbituminous and bituminous coals with sulfur contents ranging from 0.22 to 3.6% have been examined using nickel XANES spectroscopy. XANES spectroscopy of Ni in coal and coal derived ash is complicated by a poor signal : noise ratio due to fluorescence of the much more abundant iron in the coal. Nevertheless, it has proved possible to show that the Ni environment in coals varies from largely oxidic species to mixtures of Ni-containing oxide and sulfide species. The nickel in one oxidized coal appears to be present as nickel sulfate. Nickel in all bottom and fly ash samples examined appears also to be present largely in oxygen anion environments. With the exception of one fly ash sample, for which the Ni exhibited spectral features similar to those for Ni(2+) in spinel or oxide phases, the nickel in the bottom and fly ash samples appears to exist largely as Ni(2+) in environments similar to those reported for Ni in silicate glasses. The data obtained indicate that the presence of potentially carcinogenic nickel sulfides in ash by-products from combustion of these coals is unlikely.     

Effects of Disturbance on Nitrogen Export from Forested Lands of the Chesapeake Bay Watershed

The objective of this research project is to develop, test, validate, and demonstrate an analytical framework for assessing regional-scale forest disturbance in the mid-Atlantic region by linking forest disturbance and forest nitrogen export to surface waters at multiple spatial scales. It is hypothesized that excessive nitrogen (N) leakage (export) from forested watersheds is a potentially useful, integrative "indicator" of a negative change in forest function which occurs in synchrony with changes in forest structure and species composition. Our research focuses mainly on forest disturbance associated with recent defoliations by the gypsy moth larva (Lymantria dispar) at spatial scales ranging from small watersheds to the entire Chesapeake Bay watershed. An approach for assessing the magnitude of forest disturbance and its impact on surface water quality will be based on an empirical model relating forest N leakage and gypsy moth defoliation that will be calibrated using data from 25 intensively-monitored forested watersheds in the region and tested using data from more than 60 other forested watersheds in Virginia. Ultimately, the model will be extended to the region using spatially-extensive data describing: 1) the spatial distribution of dominant forest types in the mid-Atlantic region based on both remote sensing imagery and plot-scale vegetation data; 2) the spatial pattern of gypsy moth defoliation of forested areas from aerial mapping; and 3) measurements of dissolved N concentrations in streams from synoptic water quality surveys.     

Computational molecular species delimitation and taxonomic revision of the gecko genus <Emphasis Type="Italic">Ebenavia</Emphasis> Boettger, 1878

Cryptic species have been detected in many groups of organisms and must be assumed to make up a significant portion of global biodiversity. We study geckos of the Ebenavia inunguis complex from Madagascar and surrounding islands and use species delimitation algorithms (GMYC, BOLD, BPP), COI barcode divergence, diagnostic codon indels in the nuclear marker PRLR, diagnostic categorical morphological characters, and significant differences in continuous morphological characters for its taxonomic revision. BPP yielded ≥?10 operational taxonomic units, whereas GMYC (≥?27) and BOLD (26) suggested substantial oversplitting. In consequnce, we resurrect Ebenavia boettgeri Boulenger 1885 and describe Ebenavia tuelinae sp. nov., Ebenavia safari sp. nov., and Ebenavia robusta sp. nov., increasing the number of recognised species in Ebenavia from two to six. Further lineages of Ebenavia retrieved by BPP may warrant species or subspecies status, but further taxonomic conclusions are postponed until more data become available. Finally, we present an identification key to the genus Ebenavia, provide an updated distribution map, and discuss the diagnostic values of computational species delimitation as well as morphological and molecular diagnostic characters.     

Fl?chenauswahl und ?kosystemares Monitoring in den Biosph?renreservaten Schorfheide-Chorin und Spreewald

Für die Biosph?renreservate (BR) Schorfheide-Chorin und Spreewald (Land Brandenburg) wurde ein handlungsorientiertes, kostengünstiges, arbeitsteiliges Konzept für die ?kosystemare Umweltbeobachtung (?UB) entwickelt, dessen methodische Entwicklung auch auf andere Schutzgebiete übertragbar ist. Hierzu werden neben statistischen Auswertungen fl?chenhaft vorliegender Informationen auch weitere Kriterien wie Naturn?he, Seltenheit und Ma?nahmenbezug durch das Einbringen von Expertenwissen systematisch genutzt, um so die Besonderheiten und Eigenarten der beiden behandelten Gro?schutzgebiete zu erfassen und in gewissem Umfang zu wichten und so gezielt auch Fragestellungen naturschutzfachlicher Relevanz nachzugehen. Nach einer Inventarisierung der vorhandenen ?kosysteme wurden auf der Basis der Auswahlkriterien

CONJUNCTIVE USE OF SEA AND FRESH WATER RESOURCES: AN INTEGER PROGRAMMING APPROACH1

ABSTRACT Mathematical models are formulated for selection of water resources projects to meet the future additional water requirements of a given region at the minimum present worth cost. The projects available are surface water reservoirs and desalination plants. The modles are used for selecting both the development sequence of projects and their optimum sizes. Decisions with regard to planning time horizon and discount rates are made outside of the mathematical model. The algorithm used for solving these models is an integer programming routine using the implicit enumeration technique. Some computational results are presented for a hypothetical case.     

FLOOD PLAIN MODELING1

Computer simulation of river basin hydrology has rapidly progressed from an interesting academic exercise to a practical engineering procedure of increasing utility. Mathematical models of the many interrelated processes which occur in a basin have been developed along with efficient numerical procedures for their solution. The present paper is concerned with a particular model which has been used to describe the transformation of a temporally and spatially varying rainfall into a time history of stage and discharge on a flood plain. Although developed principally as a model of the physical processes involved, it is envisioned that the model can serve as one component of an information system for flood plain planning and management. The model consists of the following elements: (i) a rainfall simulation which generates stochastic inputs to the model according to specified rainfall statistics, (ii) a catchment-runoff model which converts the rainfall to surface runoff, (iii) a flood stage model which converts the surface runoff to time histories of flood stage and discharge. The model has been used to investigate the effect of various structural flood control measures in a basin and, in particular, to establish frequency-stage information for each of these. Of particular interest in development of the model have been recurring and partially unanswered questions relative to the proper balance among availability of data for use in the model, data requirements of the model and the objectives of the outputs produced by the model.     

由洪水泛滥的教训谈国家统一灾害管理

本文系统分析和总结了美国在洪泛平原管理中的经验教训，研究了减灾措施、行为反应及国家长期减灾目标等方面的内容，从综合的角度提出了统一的国家减灾计划。     

Reproducing or dispersing? Using trait based habitat templet models to analyse Orthoptera response to flooding and land use

Habitat templet theory predicts that habitat provides the templet on which evolution shapes species’ multiple traits and thus their characteristic life-history strategies. By analysing entire trait communities (multiple species and traits) in this framework we can enhance our understanding of how species composition changes as environmental constraints vary across the landscape. Here, we study multiple traits of floodplain Orthoptera communities under the influence of two different sources of disturbance, land use and seasonal flooding.The application of two recently developed statistical techniques - qualitative RLQ analysis and subsequent fourth-corner permutation tests - revealed two different life history strategies in Orthoptera as a response to ecological disturbances, resulting from land use management and seasonal flooding. Orthoptera species seem to have developed two complementary strategies: (i) the high active dispersal-low reproduction strategy in intensive land use situations and (ii) the high passive dispersal-high reproduction strategy in areas with high flood disturbance. Disturbance gradients act as trait filters allowing only particular trait combinations i.e. species with particular preadaptations to survive, whereas others go regionally extinct. Reproduction and dispersal capacity seem to be inversely associated with the disturbance gradients. Ovariole number, taken as the measure for reproduction, showed significant phylogenetic signal, which could potentially confound this relationship. Nonetheless, RLQ analyses coupled with fourth-corner permutation tests proved a powerful tool to reveal and disentangle different evolutionary strategies.