Selenium geochemistry of paddy soils in Yangtze River Delta

Selenium (Se) content both in total and bioavailable forms were very low (25-35 and 9.5 micrograms/kg, respectively) in waterlogged paddy soils in the central Yangtze River Delta. This was due to changes in geochemistry and the inherent properties of the parent materials of these lowland paddy soils. The very low Se content (23 micrograms/kg) in the parent material resulted in low total Se content in the soil. The main chemical changes under long-term waterlogged conditions are depletion of molecular oxygen, decrease of redox potential, and reduction of Fe (III) to Fe (II) and SeO3(2-) to Se0. This led to low availability of Se in soils, and subsequently low Se content (29 micrograms/kg) in brown rice grain produced in this region. It has been suspected that low Se content in staple food might be one of the major reasons for a high infection rate of the intestine and stomach cancers and the higher death rate caused by these diseases in the region. Foliage spray of Na2SeO3 at early heading stage of rice plant growth improved the Se content of brown rice grain, hull, and straw, and would improve human and animal health.     

Effect of Compatibilizing Agent on the Properties of Highly Crystalline Composites Based on Poly(lactic acid) and Wood Flour and/or Mica

This article contains a concept of the mechanical properties improvement of the highly crystalline poly(lactic acid) (PLA) and filled composites. PLA as a semi-crystalline thermoplastic polymer was plasticized with poly(ethylene glycol) and filled with 30 vol% of organic and/or inorganic filler. The degree of crytallinity was intentionally increased by annealing. The filler/polymer matrix interphase was modified with the addition of 4, 4′-Methylenediphenyl diisocyanate (MDI). The effect of compatibilizing as well as plasticizing agent on the thermal and mechanical properties, the water-absorption behaviour and crystallization characteristics were studied. The results indicated that high content of filler and crystallites have a strong influence on the composite′s mechanical properties despite of the plasticizer content, showing a high Young modulus. The MDI seems to react in preference easy with plasticizing agent and then alternatively with filler due to the low functionality of commercial PLA grade.     

Treatment of municipal wastewater using a contact oxidation filtration separation integrated bioreactor

A new contact oxidation filtration separation integrated bioreactor (CFBR) was used to treat municipal wastewater. The CFBR was made up of a biofilm reactor (the upper part of the CFBR) and a gravitational filtration bed (the lower part of the CFBR). Polyacrylonitrile balls (50 mm diameter, 237 m²/m³ specific surface, 90% porosity, and 50.2% packing rate) were filled into the biofilm reactor as biofilm attaching materials and anthracite coal (particle size 1–2 mm, packing density 0.947 g/cm³, non-uniform coefficient (K₈₀ = d₈₀/d₁₀) < 2.0) was placed into the gravitational filtration bed as filter media. At an organic volumetric loading rate of 2.4 kg COD/(m³ d) and an initial filtration velocity of 5 m/h in the CFBR, the average removal efficiencies of COD, ammonia nitrogen, total nitrogen and turbidity were 90.6%, 81.4%, 64.6% and 96.7% respectively, but the treatment process seemed not to be effective in phosphorus removal. The average removal efficiency of total phosphorus was 60.1%. Additionally, the power consumption of the CFBR was less than 0.15 kWh/m³ of wastewater treated, and less than 1.5 kWh/kg BOD₅ removal.     

Strain-based design criteria of pipelines

Traditional pipeline design analysis methods presented in various codes are usually based on limit stress criteria. However, these methods may be inapposite to modern steels, especially for displacement controlled loads such as ground displacement load. Strain limits, including ovalization limit, tensile strain limit and compression strain limit, are compared in this paper based upon various codes and recommendations. In addition, most factors of strain limits are also reviewed respectively.     

Iodine-129 and plutonium isotopes in Arctic kelp as historical indicators of transport of nuclear fuel-reprocessing wastes from mid-to-high latitudes in the Atlantic Ocean

Iodine-129:iodine-127 ratios were determined using accelerator mass spectrometry in 34 Arctic marine algae collected between 1930 and 1993. A smaller set (5) of marine algae were also analyzed mass spectrometrically to determine plutonium-isotope ratios. The ¹²⁹I:¹²⁷I ratio increased as much as three orders of magnitude from a mean of <1×10⁻¹¹ (atom/atom) in the pre-nuclear era (before 1945) to nearly 1000×10⁻¹¹ in 1993 for marine algae collected from the Novaya Zemlya archipelago separating the Barents and Kara Seas. The predominant basis for the higher ratios in the Novaya Zemlya kelps appears to be upcurrent sources of ¹²⁹I from nuclear fuel-reprocessing facilities at Sellafield (UK) and La Hague (France). Relatively high ²⁴¹Pu:²³⁹Pu ratios (compared to observed bomb fallout at boreal latitudes, decay corrected to the date of collection) also corroborate the influence of non-fallout sources. The small size of the data set precludes determining if there are significant contributions of ¹²⁹I and other radionuclides from Russian sources. In contrast, marine algae collected between 1969 and 1993 in the Bering, Beaufort and East Siberian Seas had much lower ¹²⁹I:¹²⁷I ratios (mean=14.04×10⁻¹¹±3.15 SD) than those observed in the European Arctic. The narrow range of ratios in Ameriasian Arctic kelps, and the modest change over that time period, indicate that there were no major contributions of non-fallout ¹²⁹I to North American Arctic surface waters at the time that the algae were collected. The potential for timing the transport of fuel-reprocessed ¹²⁹I through analysis of additional archived samples is outlined. Received: 10 November 1997 / Accepted: 24 February 1998     

The impact of monetary liquidity on Chinese aluminum prices

By expanding Frankel and Rose's (2009) theoretical model to consider the interaction of commodity prices with both money liquidity and expectation formation, this paper empirically studies the long-run relationship and short-term dynamics between aluminum prices and money liquidity via Vector autoregressive (VAR) and Impulse Response Function methodologies. Our results show that: (1) a cointegration relationship between money liquidity and Chinese aluminum prices exists, and monetary liquidity positively significantly influences the price over long periods; (2) a structural change has been found during the 2008 Financial Crisis and the change of Chinese monetary policies; and (3) the negative impact of production capacity mechanism on aluminum prices coexists with the positive impact of financial asset returns mechanism, to allow for varied market expectations on aluminum prices within and outside China.     

The Ecological and Environmental Characteristics and Conservation of the Wetlands in the Changjiang Estuary, China

The natural wetlands in the Changjiang Estuary, China are important ecologically. The total area of the wetlands in the Changjiang Estuary amounts to 215000 ha. The wetlands consist of littoral and sandy estuarine island areas, and are rich in biological resources. There are 136 species of vascular plant, 150 species of bird, and 68 species of benthic macro-invertebrate in the wetlands. However, the wetland in the Changjiang Estuary is a vulnerable ecosystem. Development of the wetland is mainly influenced by intensive human reclamation, pollution, movement of sediments in the Changjiang River, and the effects of tides and waves. Investigations have shown that maintaining biodiversity, providing resources for the living organisms, purifying environments and resisting natural hazards could be regarded as important functions for the protection of the wetlands. It is proposed that sustainable principles should be supported in developing the wetlands in the future.     

Soil organic carbon decomposition and carbon pools in temperate and sub-tropical forests in China

Decomposition of soil organic carbon (SOC) is a critical component of the global carbon cycle, and accurate estimates of SOC decomposition are important for forest carbon modeling and ultimately for decision making relative to carbon sequestration and mitigation of global climate change. We determined the major pools of SOC in four sites representing major forest types in China: temperate forests at Changbai Mountain (CBM) and Qilian Mountain (QLM), and sub-tropical forests at Yujiang (YJ) and Liping (LP) counties. A 90-day laboratory incubation was conducted to measure CO(2) evolution from forest soils from each site, and data from the incubation study were fitted to a three-pool first-order model that separated mineralizable soil organic carbon into active (C(a)), slow (C(s)) and resistant (C(r)) carbon pools. Results indicate that: (1) the rate of SOC decomposition in the sub-tropical zone was faster than that in the temperature zone, (2) The C(a) pool comprised approximately 1-3% of SOC with an average mean residence time (MRT) of 219 days. The C(s) pool comprised approximately 25-65% with an average MRT of 78 yr. The C(r) pool accounted for approximately 35-80% of SOC, (3) The YJ site in the sub-tropical zone had the greatest C(a) pool and the lowest MRT, while the QLM in the temperature zone had the greatest MRT for both the C(a) and C(s) pools. The results suggest a higher capacity for long-term C sequestration as SOC in temperature forests than in sub-tropical forests.     

The role of arbuscular mycorrhiza in zinc uptake by red clover growing in a calcareous soil spiked with various quantities of zinc

Three pot experiments were conducted to investigate the role of arbuscular mycorrhiza (AM) in Zn uptake by red clover. Plants inoculated with Glomus mosseae and uninoculated controls were grown in a sterile calcareous soil in 'Plexiglas' (Acrylic) containers with two nylon net partitions (30 microm mesh) to separate the central root zone from the two outer hyphal zones. The effects of mycorrhiza on plant growth and Zn uptake changed dramatically with increasing Zn addition level (range 0-1200 mg kg(-1)) in the root zone. With Zn addition levels <300 mg kg(-1), added Zn did not affect plant yield and above the critical level plant yield gradually decreased but was always higher for mycorrhizal than for controls. Below the critical Zn application rate (50 mg kg(-1)), Zn uptake was enhanced while above this level Zn translocation to the shoots decreased. At all Zn addition levels, mycorrhizal colonization increased Zn absorption and accumulation in the roots, and this may help to explain the alleviation of Zn toxicity at high Zn application rates. As expected, AM colonization enhanced P nutrition and hence yield at all added Zn levels studied. Efforts were made to obtain direct evidence for hyphal contribution to Zn uptake by applying both Zn to the hyphal growth zone and additional P to the root zone to avoid the 'growth dilution effect'. The data demonstrate that mycorrhizal hyphae could absorb Zn directly from the soil and then transfer it to the plant roots. The hyphal contribution to Zn uptake by the host plant reached its maximum value at the Zn addition level of 50 mg kg(-1), in which Zn uptake via the extramatrical hyphae comprised 22% of total uptake, thus confirming the critical Zn application level found previously.     

Population dynamics of farmland ladybug resources and dominant species in Nyingchi,Tibet, China北大核心CSCD

捕食性瓢虫是重要的天敌昆虫,有利于害虫的生物防治.为查清西藏林芝地区农田瓢虫资源与种群现状,明确优势种类及种群动态和规律,对林芝不同生态区域的青稞、小麦、油菜3种作物农田开展瓢虫资源调查研究,同时选取固定样地定期进行种群动态分析.结果显示:林芝地区农田瓢虫分为2个亚科4个族10个属,共13种,其中11种为捕食性瓢虫.主要优势瓢虫种类为横斑瓢虫、多异瓢虫、二星瓢虫.其中横斑瓢虫在全部调查样地中均有分布,在农田中总体优势度指数、相对多度为最高.3种优势瓢虫在不同作物中种群动态变化规律存在差异,其中横斑瓢虫虫口密度长期高于其余优势瓢虫,且与蚜虫密度曲线有较为明显的重合现象.横斑瓢虫种群密度峰值主要集中在6月中旬至7月上旬,但在不同作物农田中具体峰值时期存在差异.可见,林芝地区农田不同种类瓢虫之间有较大数量差异,在不同生态区域与作物环境下具有不同的种群特征,但是优势瓢虫种类与种群规律较为明确,可用于农田蚜虫生物防治;结果可为保护当地重要昆虫资源及开展生物防治提供基础数据支撑.(图4表6参23)