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Yue Zhang Hongsheng Zhang Luping Ni Qilin Zhou Weihong Guo Chifei Wu 《Journal of Polymers and the Environment》2010,18(4):647-653
Recycled poly(ethylene terephthalate) (R-PET) was blended with 15–30 wt% of styrene–ethylene/butylenes–styrene (SEBS) block
copolymer and maleic anhydride grafted SEBS (SEBS-g-MA). Effects of nucleation and toughening of the elastomers were evaluated
systematically by study of morphology, crystallization, thermal and mechanical properties of the blend. The addition of 30 wt%
SEBS promoted the formation of co-continuous structure of the blend and caused the fracture mechanism to change from strain
softening to strain hardening. Addition of SEBS-g-MA resulted in significant modification of phase morphology and obviously
improved the impact strength. The compatibilization reaction of PET with SEBS-g-MA accelerated the crystallization of PET
and increased the crystallinity. The shifts in glass transition temperature of PET towards that of SEBS-g-MA and the higher
modulus for R-PET/SEBS-g-MA (70/30) blend found by DMA are also indications of better interactions under the conditions of
compatibilization and interpenetrating structure. 相似文献
957.
Hui Zhang Yanli Li Xiaogang Wu Yanjun Zhang Daobin Zhang 《Waste management (New York, N.Y.)》2010,30(11):2096-2102
The influence of different variables on the removal of ammonia nitrogen and COD from landfill leachate was investigated in a three-dimensional electrochemical reactor. Box–Behnken statistical experiment design and the response surface methodology were used to investigate operating condition effects, such as current density, activated carbon to water ratio and the reaction time, on ammonia nitrogen removal efficiency and COD removal efficiency. The positive and negative effects of variables and the interaction between variables on ammonia nitrogen removal and COD removal were determined. The response surface methodology models were derived based on the results and the response surface plots were developed accordingly. 相似文献
958.
Ru-Ling Tseng Keng-Tung Wu Feng-Chin Wu Ruey-Shin Juang 《Journal of environmental management》2010,91(11):2208-2214
This study uses rate parameters in pseudo-first-order (PFO) and pseudo-second-order (PSO) equations (k1 and k2qe, respectively) to judge the extent for approaching equilibrium in an adsorption process. Out of fifty-six systems collected from the literature, the adsorption processes with a k2qe value between 0.1 and 0.8 min?1 account for as much as 70% of the total. These are classified as fast processes. This work compares the validity of PFO and PSO equations for the adsorption of phenol, 4-chlorophenol (4-CP), and 2,4-dichlorophenol (2,4-DCP) on activated carbons prepared from pistachio shells at different NaOH/char ratios. The activated carbons, recognized as microporous materials, had a surface area ranging from 939 to 1936 m2/g. Findings show that the adsorption of phenol, 4-CP, and 2,4-DCP on activated carbons had a k2qe value of 0.15–0.58 min?1, reflecting the fast process. Evaluating the operating time by rate parameters revealed that k2qe was 1.6–1.8 times larger than k1. These findings demonstrate the significance of using an appropriate kinetic equation for adsorption process design. 相似文献
959.
Rui Xu Peter E. Mortimer Rong Ping Kuang Jun He Wu Di Zhang Fang Yin 《Journal of environmental science and health. Part. B》2013,48(8):651-657
This study focuses on assessing the impact of sublethal doses of paraquat on the survival, the emergence, the life span and the parasitic behavior of Diaeretiella rapae M’Intosh (Hymenoptera: Braconidae). The impact of sublethal doses was measured at room temperature using different densities of the cabbage aphid Brevicoryne brassicae. The results reveal that the field dose of paraquat caused 100% mortality in D. rapae. The percentage emergence of D. rapae decreased from 80.5% in the control group to 71.5% when treated with the lowest concentration of paraquat. Similarly, the life span of parasitoids that emerged from the mummy treated with paraquat also decreased significantly. Oviposition capability and ovipositor thrusting frequency of D. rapae also treated with sublethal dose paraquat decreased significantly along with a shortened patch residence time in the foraging area. 相似文献
960.
Xu Bentuo Wu Minghong Pan Chenyuan Sun Yan Yuan Debao Tang Liang Xu Gang 《Environmental science and pollution research international》2017,24(16):14409-14416
Environmental Science and Pollution Research - Hydroxylated polyhalodiphenyl ethers (HO-PXDEs) have attracted considerable scientific interest as examples of emerging aquatic pollutants. However, a... 相似文献