The influence of degree of substitution on blend miscibility and biodegradation of cellulose acetate blends

In this account, we report our findings on blends of cellulose acetate having a degree of substitution (DS) of 2.49 (CA2.5) with a cellulose acetate having a DS of 2.06 (CA2.0). This blend system was examined over the composition range of 0–100% CA2.0 employing both solvent casting of films (no plasticizer) and thermal processing (melt-compressed films and injection molding) using poly(ethylene glycol) as a common plasticizer. All thermally processed blends were optically clear and showed no loss in optical quality after storage for several months. Thermal analysis and measurement of physical properties indicate that blends in the middle composition range are partially miscible, while those at the ends of the composition range are miscible. We suggest that the miscibility of these cellulose acetate blends is influenced primarily by the monomer composition of the copolymers. Bench-scale simulated municipal composting confirmed the biodestructability of these blends and indicated that incorporation of a plasticizer accelerated the composting rates of the blends.In vitro aerobic biodegradation testing involving radiochemical labeling conclusively demonstrated that both the lower DS CA2.0 and the plasticizer significantly enhanced the biodegradation of the more highly substituted CA2.5.While this work was in progress, Robert Gardner was struck with cancer and died on June 6, 1995. This paper is dedicated to his memory and to his contributions as a friend and colleague.     

A statistical approach to the regional use of critical loads

The premise of this paper is that: (1) effects of spatial heterogeneity of watershed response to acid deposition must be considered when models are used to set abatement policies, and (2) the evaluation of critical chemical values is a better measure off the effects of abatement policies than the comparison of deposition values to critical loads. The authors used Monte Carlo methods to apply a site-specific version of the RAINS-Lake-Model to a regional data set from The Netherlands. Statistical methods were then used to identify the important parameters affecting the spatial and temporal response, i.e. a change in pH, of watersheds to acid deposition and a subset of sensitive and insensitive watersheds were derived. The results show that the failure to subset a region into sensitive and insensitive zones may result in an erroneous estimation of the effect of abatement policies based on critical loads alone.     

Artificial neural network-derived trends in daily maximum surface ozone concentrations

Interannual variability in meteorological conditions can confound attempts to identify changes in ozone concentrations driven by reduced precursor emissions. In this paper, a technique is described that attempts to maximize the removal of meteorological variability from a daily maximum ozone time series, thereby revealing longer term changes in ozone concentrations with increased confidence. The technique employs artificial neural network [multilayer perceptron (MLP)] models, and is shown to remove more of the meteorological variability from U.S. ozone data than does a Kolmogorov-Zurbenko (KZ) filter and conventional regression-based technique.     

Polystyrene/wood composites and hydrophobic wood coatings from water-based hydrophilic-hydrophobic block copolymers

The combination of synthetic thermoplastic polymers and wood is normally problematic because wood surfaces are hydrophilic while typical thermoplastic polymers are hydrophobic. A possible solution is to use block copolymer coupling agents. In this work we show the use of a potentially useful synthetic method of producing hydrophilic-hydrophobic block copolymers as hydrophobic coatings and coupling agents in polystyrene/wood flour composites. In particular, wood veneers are coated with water-based emulsions of hydrophilic-hydrophobic block copolymers from styrene and methacrylic acid. Dried coated surfaces are shown to become hydrophobic through dynamic contact angle measurements. When wood flour is coated with the hydrophilic-hydrophobic block copolymer based on styrene and acrylic acid, significant improvement in the ultimate tensile properties of composites formed from coated wood flour/polystyrene mixtures is realized. Since no volatile organic compounds (VOCs) are used in coating wood surfaces and subsequent composite production, improvement in mechanical properties of thermoplastic/wood flour composites are shown to occur in environmentally responsible formulations.     

Characterization of phosphorus species in biosolids and manures using XANES spectroscopy

Identification of the chemical P species in biosolids or manures will improve our understanding of the long-term potential for P loss when these materials are land applied. The objectives of this study were to determine the P species in dairy manures, poultry litters, and biosolids using X-ray absorption near-edge structure (XANES) spectroscopy and to determine if chemical fractionation techniques can provide useful information when interpreted based on the results of more definitive P speciation studies. Our XANES fitting results indicated that the predominant forms of P in organic P sources included hydroxylapatite, PO(4) sorbed to Al hydroxides, and phytic acid in lime-stabilized biosolids and manures; hydroxylapatite, PO(4) sorbed on ferrihydrite, and phytic acid in lime- and Fe-treated biosolids; and PO(4) sorbed on ferrihydrite, hydroxylapatite, beta-tricalcium phosphate (beta-TCP), and often PO(4) sorbed to Al hydroxides in Fe-treated and digested biosolids. Strong relationships existed between the proportions of XANES PO(4) sorbed to Al hydroxides and NH(4)Cl- + NH(4)F-extractable P, XANES PO(4) sorbed to ferrihydrite + phytic acid and NaOH-extractable P, and XANES hydroxylapatite + beta-TCP and dithionite-citrate-bicarbonate (DCB)- + H(2)SO(4)-extractable P (r(2) = 0.67 [P = 0.01], 0.78 [P = 0.01], and 0.89 [P = 0.001], respectively). Our XANES fitting results can be used to make predictions about long-term solubility of P when biosolids and manures are land applied. Fractionation techniques indicate that there are differences in the forms of P in these materials but should be interpreted based on P speciation data obtained using more advanced analytical tools.     

Sustainable shrimp fishery management recommendations for a coastal lagoon in Baja California Sur,Mexico

The Baja California Peninsula is considered México's most productive in terms of commercial fisheries. Very few quantitative assessments of the economic importance of this region exist, especially considering artisanal fisheries and their relationships with ecological data. Datasets from government records on shrimp capture in Magdalena Bay, an arid coastal lagoon of Baja California Sur were collected, analysed and correlated with ecological data. Over the 10-year period analysed, fisheries from Magdalena Bay made up 27.5% of the shrimp capture of the state, contributing over US$15.5 million to the economy of the country. The impressive value of this resource warrants considerable attention in the design of land-use plans for the future of the region. Analysis of ecological and economical data on shrimp fishery activities in the Magdalena Bay region enables us to propose recommendations to enhance the sustainable development of the local inhabitants. A thorough assessment of the potential value of alternative economic activities should be conducted to determine their potential to provide similar productive use of the natural resources of the region as the shrimp fishery. Also, from a more specific management viewpoint, harvest rates of small shrimp in the channels should be reduced.     

Energy efficiency and conservation for individual Americans

Americans make up only 4% of the world population, yet currently consume 25% of the world’s fossil fuels. The U.S. imports 63% of its oil and it is predicted that by 2020 the U.S. will be importing 95% of its oil resources. Over the past century, ample and affordable supplies of fossil fuels have powered the growth and prosperity of the economies of the US and other countries. Within this century, world oil supplies will decline while demand is projected to continue to increase, suggesting that we will have to transition to different fuels or become much more energy efficient or both. Looking ahead to the near decades, estimates are that consumers will have to reduce their energy use by at least 50%. This reduction will be necessary in large part due the decline in the availability of conventional oil and gas, but also because the U.S. population will continue to grow in number. Although government action is important, individuals too often discount their ability to make significant contributions to solving such major problems. This investigation identifies how informed and concerned individuals can collectively conserve fossil energy. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. An erratum to this article can be found at     

Influence of Restoration Age and Riparian Vegetation on Reach‐Scale Nutrient Retention in Restored Urban Streams

In urban watersheds, stormwater inputs largely bypass the buffering capacity of riparian zones through direct inputs of drainage pipes and lowered groundwater tables. However, vegetation near the stream can still influence instream nutrient transformations via maintenance of streambank stability, input of woody debris, modulation of organic matter sources, and temperature regulation. Stream restoration seeks to mimic many of these functions by engineering channel complexity, grading stream banks to reconnect incised channels, and replanting lost riparian vegetation. The goal of this study was to quantify these effects by measuring nitrate and phosphate uptake in five restored streams in Charlotte and Raleigh, North Carolina, with a range of restoration ages. Using nutrient spiraling methods, uptake velocity of nitrate (0.02‐3.56 mm/min) and phosphate (0.14‐19.1 mm/min) was similar to other urban restored streams and higher than unimpacted forested streams with variability influenced by restoration age and geomorphology. Using a multiple linear regression approach, reach‐scale phosphate uptake was greater in newly restored sites, which was attributed to assimilation by algal biofilms, whereas nitrate uptake was highest in older sites potentially due to greater channel stability and establishment of microbial communities. The patterns we observed highlight the influence of riparian vegetation on energy inputs (e.g., heat, organic matter) and thereby on nutrient retention.     

The role of personal experience in frequency of rainwater tank maintenance and policy implications

Domestic rainwater tanks have a long history in Australia, although more recently they have been common only in remote and rural areas. However, in some urban areas, recent drought conditions have led to the promotion of rainwater tanks to supplement domestic water supplies. Evidence suggests that water tank maintenance may be insufficient in many cases, leading to problems with water quality and the potential spread of vector-borne disease. Drawing on research into the impact of personal experience (i.e. procedural knowledge) relating to pro-environmental behaviour, a survey of urban residents with mandated rainwater tanks (N?=?746) was conducted. The study assessed whether past personal history of living with a tank influenced the frequency of tank maintenance behaviours. Analyses indicated that both childhood and prior adult experience with rainwater tanks were important in predicting adequate tank maintenance behaviour, particularly among males. The results also showed that attitudinal perceptions of water culture did not influence maintenance behaviour, whereas direct past experiences did, suggesting an important role for procedural knowledge. These results are discussed with reference to the promotion of tank maintenance and other pro-environmental behaviours through the development of future environmental policies designed to foster the development of pro-environmental skills to empower citizens.