A RIFFLE STABILITY INDEX TO EVALUATE SEDIMENT LOADING TO STREAMS1

ABSTRACT: Riffles in moderately entrenched stream reaches with gradients of 2 percent to 4 percent that have received excessive sediment from upstream have a distinctly different and higher proportion of smaller mobile particles than riffles in systems that are in dynamic equilibrium. The mobile fraction on the riffle can be estimated by comparing the relative abundance of various particle sizes present on the riffle with the dominant large particles on an adjacent bar. Riffle particles smaller than the dominant large particles on the bar are interpreted as mobile. The mobile percentile of particles on the riffle is termed “Riffle Stability Index” (RSI) and provides a useful estimate of the degree of increased sediment supply to riffles in mountain streams. The RSI addresses situations in which increases in gravel bedload from headwaters activities is depositing material on riffles and filling pools, and it reflects qualitative differences between reference and managed watersheds. The RSI correlates well with other measures of stream channel physical condition, such as V and the results of fish habitat surveys. Thus, it can be used as an indicator of stream reach and watershed condition and also of aquatic habitat quality.     

EFFECTS OF CLIMATE CHANGE ON WATER RESOURCES IN THE DELAWARE RWER BASIN1

ABSTRACT: The effects of potential climate change on water resources in the Delaware River basin were determined. The study focused on two important water-resource components in the basin: (1) storage in the reservoirs that supply New York City, and (2) the position of the salt front in the Delaware River estuary. Current reservoir operating procedures provide for releases from the New York City reservoirs to maintain the position of the salt front in the estuary downstream from freshwater intakes and ground-water recharge zones in the Philadelphia metropolitan area. A hydrologic model of the basin was developed to simulate changes in New York City reservoir storage and the position of the salt front in the Delaware River estuary given changes in temperature and precipitation. Results of simulations indicated that storage depletion in the New York City reservoirs is a more likely effect of changes in temperature and precipitation than is the upstream movement of the salt front in the Delaware River estuary. In contrast, the results indicated that a rise in sea level would have a greater effect on movement of the salt front than on storage in the New York City reservoirs. The model simulations also projected that, by decreasing current mandated reservoir releases, a balance can be reached wherein the negative effects of climate change on storage in the New York City reservoirs and the position of the salt front in the Delaware River estuary are minimized. Finally, the results indicated that natural variability in climate is of such magnitude that its effects on water resources could overwhelm the effects of long-term trends in precipitation and temperature.     

Field testing of particulate matter continuous emission monitors at the DOE Oak Ridge TSCA incinerator. Toxic Substances Control Act

A field study to evaluate the performance of three commercially available particulate matter (PM) continuous emission monitors (CEMs) was conducted in 1999-2000 at the US Department of Energy (DOE) Toxic Substances Control Act (TSCA) Incinerator. This study offers unique features that are believed to enhance the collective US experience with PM CEMs. The TSCA Incinerator is permitted to treat PCB-contaminated RCRA hazardous low-level radioactive wastes. The air pollution control system utilizes MACT control technology and is comprised of a rapid quench, venturi scrubber, packed bed scrubber, and two ionizing wet scrubbers in series, which create a saturated flue gas that must be conditioned by the CEMs prior to measurement. The incinerator routinely treats a wide variety of wastes including high and low BTU organic liquids, aqueous, and solid wastes. The various possible combinations for treating liquid and solid wastes may present a challenge in establishing a single, acceptable correlation relationship for individual CEMs. The effect of low-level radioactive material present in the waste is a unique site-specific factor not evaluated in previous tests. The three systems chosen for evaluation were two beta gauge devices and a light scattering device. The performance of the CEMs was evaluated using the requirements in draft Environmental Protection Agency (EPA) Performance Specification 11 (PS11) and Procedure 2. The results of Reference Method 5i stack tests for establishing statistical correlations between the reference method data and the CEMs responses are discussed.     

Influence of quaternary ammonium on sorption of selected metal cations onto clinoptilolite zeolite

Clay minerals and zeolites have large cation exchange capacities, which enable them to be modified by cationic surfactant to enhance their sorption of organic and anionic contaminants. In this study, the influence of quaternary ammonium surfactants on sorption of five metal cations (Cs+, Sr+, La3+, Pb2+, and Zn2+) onto a clinoptilolite zeolite was investigated. Generally, the metal cation sorption capacity and affinity for the zeolite decreased, indicating that presorbed cationic surfactants blocked sorption sites for metal cations, as the surfactant loading on the zeolite increased. Cesium and Pb2+ sorption was affected to a small extent, indicating that selective sorption for Cs+ and specific sorption for Pb2+ play an important role in addition to cation exchange. Sorption of cationic surfactants on zeolite preloaded with different metal cations showed a strong correlation with the chain length of the surfactant tail group, while the roles of the charges and types of the metal cations were minimal. As the chain length increases, the critical micelle concentration decreases and the surfactant molecules become more hydrophobic, resulting in progressive bilayer coverage. Desorption of presorbed metal cations by cationic surfactants was strongly affected by the surfactant chain length and metal type. More metal cations, particularly Sr2+ and Zn2+, desorbed with an increase in surfactant chain length. The results, in combination with those from organic and oxyanion sorption on surfactant-modified zeolite, may be used for future surfactant modification to target sorption and desorption of a specific type of contaminant or a mixture of different types of contaminants.     

WATER HARVESTING TREATMENT EVALUATION AT GRANITE REEF1

ABSTRACT: Yearly runoff efficiencies (total runoff/total precipitation), threshold retentions (precipitation needed to initiate runoff), and runoff-efficiencies-after-thresholds were determined for several water-harvesting catchment treatments at the Granite Reef test site. This information was found to be useful for showing (1) overall performance of catchments with time; (2) the distribution of the precipitation among runoff, surface retention, and infiltration; (3) why, how, and when certain treatments weathered and failed; (4) when to repair treatments; and (5) how to design catchments (size, site preparation, material selection, etc.). New impermeable membranes with smooth surfaces yielded nearly 100% of the precipitation. An asphalt-fiberglass treatment continues this high efficiency after 10 years of weathering – polyethylene after 8; efficiency of butyl sheeting was high initially but decreased rapidly after 9 years weathering. A standard roofing treatment retained up to 30% of the precipitation in the gravel covering. A concrete catchment lost as much as 50% of the total precipitation through micropores and surface cracks. Silicone treatments rapidly lost repellancy and efficiency, while paraffin treatments have weathered 5 years with little loss of efficiency.     

Interpreting dynamics of aquatic resources: A perspective for resource managers

Since the presentation of the Leopold Report (Leopold et al. 1963) to the United States Secretary of the Interior, recommendations in the document for managing natural park resources on the ecosystem level have been included in the management policies of the National Park Service. In many instances, however, management programs have continued to focus on individual resource problems, without apparent concern for the ecological consequences on ecosystems. Without knowledge of the interrelationships of ecosystem components, solving one problem may result in other resource problems. Graphic approaches are presented as potential tools to view these complex interrelationships relative to the needs of the resource manager. Interpreting the dynamics of aquatic systems is emphasized.