Comparison of photochemical behavior of various humic substances in water: I. Sunlight induced reactions of aquatic pollutants photosensitized by humic substances

Humic substances are shown to photosensitize transformations of several types of synthethic chemicals that do not photoreact when exposed to sunlight in distilled water. In most cases, photoproducts were the same in colored natural waters and in solutions of soil-derived humic substances, including those obtained commercially. Kinetic studies in sunlight indicated that the efficiencies of the reactions photosensitized by humic substances of various origins were the same within a factor of 2.     

Development of emission factors for polycarbonate processing

Emission factors for selected volatile organic compounds (VOCs) and particulate emissions were developed while processing eight commercial grades of polycarbonate (PC) and one grade of a PC/acrylonitrile-butadiene-styrene (ABS) blend. A small commercial-type extruder was used, and the extrusion temperature was held constant at 304 degrees C. An emission factor was calculated for each substance measured and is reported as pounds released to the atmosphere/million pounds of polymer resin processed [ppm (wt/wt)]. Scaled to production volumes, these emission factors can be used by processors to estimate emission quantities from similar PC processing operations.     

Kinship and food availability influence cannibalism tendency in early-instar wolf spiders (Araneae: Lycosidae)

For potentially cannibalistic animals such as spiders, the ability to recognize and avoid kin and/or preferentially cannibalize non-relatives would permit exploiting conspecifics as prey while minimizing loss of inclusive fitness. We investigated the effects of relatedness and availability of alternative food on cannibalism tendency in pairs of juvenile Hogna helluo (Walckenaer), a North American wolf spider (Araneae: Lycosidae). For second-instar spiderlings (dispersing stage), cannibalism was more likely among pairs of non-sibs than pairs of sibs and, interestingly, was also more likely when other prey were available. We found no evidence of increased cannibalism in pairings involving broods of greatest average size disparity, indicating that size differences are unlikely to explain differences in cannibalism tendency. Additionally, the relative number of deaths from cannibalism or other causes did not increase with increasing risk of starvation. For third-instar spiderlings, which had lived independently of their mother and sibs following dispersal, cannibalism rates were very high in all treatments and there were no significant effects of relatedness or food availability. Our results suggest that spiders with predominantly solitary lifestyles may bias cannibalism toward non-kin during the juvenile associative period, and that this effect is lost in the subsequent instar. Results are discussed in the context of several potential mechanisms that might result in differential cannibalism.Communicated by M. Elgar     

A national critical loads framework for atmospheric deposition effects assessment: I. Method summary

The United States Environmental Protection Agency (EPA), with the assistance of the US Department of Energy (DOE) and the National Oceanographic and Atmospheric Administration (NOAA) is examining the utility of a critical loads approach for evaluating atmospheric pollutant effects on sensitive ecosystems. A critical load has been defined as, “a quantitative estimate of an exposure to one or more pollutants below which significant harmful effects on specified sensitive elements of the environment do not occur according to present knowledge.” Working in cooperation with the United Nations Economic Community for Europe’s (UN-ECE) Long Range Transboundary Air Pollution (LRTAP) Convention, the EPA has developed a flexible, six-step approach for setting critical loads for a range of ecosystem types. The framework is based on regional population characteristics of the ecosystem(s) of concern. The six steps of the approach are: (1) selection of ecosystem components, indicators, and characterization of the resource; (2) definition of functional subregions; (3) characterization of deposition within each of the subregions; (4) definition of an assessment end point; (5) selection and application of models; and (6) mapping projected ecosystem responses. The approach allows for variable ecosystem characteristics and data availability. Specific recognition of data and model uncertainties is an integral part of the process, and the use of multiple models to obtain ranges of critical loads estimates for each ecosystem component in a region is encouraged. Through this intercomparison process uncertainties in critical loads projections can be estimated. The research described in this article has been funded by the US Environmental Protection Agency. This document has been prepared at the EPA Environmental Research Laboratory in Corvallis, Oregon, through contract #68-C8-0006 with Man Tech Environmental Technology, Inc. It has been subjected to the agency’s peer and administrative review and approved for publication. Mention of trade names or commercial products does not constitute endorse ment or recommendation for use.     

Wetland boundary and land-use planning in southern Ontario,Canada

There is a general lack of understanding of wetland processes and a general paucity of scientific research to predict the effects of development on wetland boundary. This paper presents the results of a survey of wetland managers as to how they delineate wetland boundaries, define compatible land uses, and restrict land uses adjacent to wetland boundaries. A major finding from the survey is that 75% of land-use planners and wetland managers failed to identify any compatible land use or restricted land use for development proposals that may affect provincially significant wetlands. The government agencies overwhelmingly lack adequate methodologies and/or criteria to delineate and protect wetland boundaries. The paper closes with a plea to consider dynamic hydrological factors in land-use planning.     

Incentive compensation as an injurious condition of work: A study of labelling

A recursive causal model is presented in which individual and work factors are hypothesized to be predictive of workers' labelling an incentive compensation program as potentially injurious to their well-being. The individual factors include the dispositional variable, negative affectivity, and financial needs and resources. The work factors consist of prior incentive compensation, experienced job insecurity, and experienced control. The model was tested using questionnaire responses of 165 managers and professionals. While it was found that the overall model did not fit the data that well, negative affectivity was found to be positively associated and experienced control negatively associated with the incentive compensation program being labelled negatively. The somewhat surprising finding that financial needs and resources were not found to be significantly associated with labelling is discussed. The importance of disposition and experienced control for the labelling of potentially threatening or harmful job conditions as well as some hypothesized antecedents of control also are discussed.