PAA改性纳米铁强化还原降解水中亚甲基蓝

利用纳米零价铁去除水中各类污染物是近年来的研究热点,但纳米零价铁颗粒在水中的团聚会导致反应活性降低,研究通过在纳米铁颗粒制备过程中添加分散剂聚丙烯酸(PAA),提高其分散性,强化其在水中反应活性,合成改性纳米零价铁颗粒(PAA-Fe),并首次用于降解水中的亚甲基蓝.对其SEM、TEM、XRD和比表面积表征结果表明,与未改性原始纳米零价铁颗粒相比,PAA-Fe颗粒表面较光滑,团聚减少、颗粒粒径减小,比表面积增大.改性剂PAA添加浓度为0.1 g·L-1时,经过60 min降解反应,PAA改性纳米铁颗粒对亚甲基蓝的脱色率为98.84%,较未改性颗粒脱色率提高了27.32%.改性纳米铁颗粒对亚甲基蓝的脱色效果受初始溶液的p H值、初始溶液的浓度、PAA-Fe投加量和反应温度影响.PAA-Fe与亚甲基蓝的脱色反应符合假一级反应动力学规律.     

Detecting Insect Pollinator Declines on Regional and Global Scales

Recently there has been considerable concern about declines in bee communities in agricultural and natural habitats. The value of pollination to agriculture, provided primarily by bees, is >$200 billion/year worldwide, and in natural ecosystems it is thought to be even greater. However, no monitoring program exists to accurately detect declines in abundance of insect pollinators; thus, it is difficult to quantify the status of bee communities or estimate the extent of declines. We used data from 11 multiyear studies of bee communities to devise a program to monitor pollinators at regional, national, or international scales. In these studies, 7 different methods for sampling bees were used and bees were sampled on 3 different continents. We estimated that a monitoring program with 200–250 sampling locations each sampled twice over 5 years would provide sufficient power to detect small (2–5%) annual declines in the number of species and in total abundance and would cost U.S.$2,000,000. To detect declines as small as 1% annually over the same period would require >300 sampling locations. Given the role of pollinators in food security and ecosystem function, we recommend establishment of integrated regional and international monitoring programs to detect changes in pollinator communities. Detección de Declinaciones de Insectos Polinizadores a Escalas Regional y Global     

Towards sustainable community‐based natural resource management in the indigenous Meqmegi community in Taiwan: Rethinking impacts of local participation

This paper examines approaches for local resident participation in community‐based natural resource management (CBNRM); focusing particularly on the potential impacts that local participation imposes on the natural environment. This study used qualitative methods to collect data, and selected Meqmegi, an indigenous community in Taiwan, as a case study. The findings indicate that many opportunities can be created that stimulate a community to participate in natural resource management; moreover, residents are prone to use their own ways to participate. Therefore, although local participation is praised for its people‐oriented way of natural resource management, impacts from the participation process will ultimately be imposed on the environment. We suggest that more consideration be given to the environmental conditions during the process of local participation via CBNRM to make sure that impacts on the environment are positive, and lead to a truly sustainable future.     

旅游交通弱势群体景区偏好与可达度研究——以大学生秦岭景区旅游为例

针对交通弱势群体的旅游可达问题,通过RBF插值法对秦岭景区大学生的偏好度与公共交通可达度(PTA)之间的关系进行研究.研究发现:①现实偏好度(AP)和潜在偏好度(PP)的高聚集区和低分散区吻合,而其他区域的差异较大,AP呈阶梯状变化而PP分布均衡；②可达性较高区域中的AP与PP吻合,而在较低区域中差异较大；③邻近中心城镇区域中PP与PTA呈正相关,而远离中心城镇区域中两者的影响不大.因此,提高公共交通可达度有助于实现旅游的民生功能.     

低碳经济与湖南转变经济发展方式

湖南在加快转变经济发展方式的进程中,从"一化三基"到"四化两型"的战略升级,更加注重培育以低碳排放为特征的新的经济增长点,把环保作为转变发展方式的"闸门"和"调节阀",着力推进自主创新,培育战略性新兴产业,建设低碳城市,全面推进湘江流域环境综合整治,打造湘潭九华示范区"两型"产业平台,多措并举发展低碳经济,在新的更高起点上推动湖南又好又快发展.     

Catalytic hydrothermal depolymerization of nylon 6

Depolymerization of nylon 6 to produce ε-caprolactam using an environmentally friendly heteropoly acid catalyst was studied at temperatures between 553 and 603 K in water. The products of depolymerization were analyzed qualitatively and quantitatively by means of mass spectrometry and high-performance liquid chromatography. The results showed that the depolymerized product was mainly ε-caprolactam with a little 6-aminocaproic acid and oligomers. The phosphotungstic heteropoly acid used as a catalyst can improve the hydrolysis rate and yield of ε-caprolactam. The optimum hydrolysis conditions for ε-caprolactam yield were as follows: phosphotungstic heteropoly acid content, 3%; reaction temperature, 573 K; and reaction time, 85 min. Under these conditions, the yield of ε-caprolactam was 77.96%. In the temperature range 553–603 K, the activation energy of 3% phosphotungstic heteropoly acid-catalyzed depolymerization was evaluated as 77.38 kJ/mol, which is lower than the 86.64 kJ/mol value for no catalyst.     

Experimental study on the mitigation via an ultra-fine water mist of methane/coal dust mixture explosions in the presence of obstacles

In this paper, experimental investigations were performed for the mitigation via an ultra-fine water mist of methane/coal dust mixture explosions in the presence of obstacles to reveal the effects of the obstacles in this scenario. Two PCB piezo-electronic pressure transducers were used to acquire the pressure history, a Fastcam Ultima APX high-speed video camera was used to visualize both the process of the mixture explosion and its mitigation. The diameters of the coal dust, the types of obstacles and the volumes of ultra-fine water mist were varied in the tests. The parameters of the explosion overpressure and the range of critical volume flux of the ultra-fine water mist for explosion mitigation were determined. The results show that the mixture explosion and its mitigation are primarily influenced by the number, shape and set locations of the obstacles. When the volume flux of the water mist is larger than a certain amount, the mixture explosions and the effects of obstacles can be completely mitigated with the ultra-fine water mist.     

Adsorption and Desorption Characteristics of Semiconductor Volatile Organic Compounds on the Thermal Swing Honeycomb Zeolite Concentrator

Abstract

The use of a honeycomb zeolite concentrator and an oxidation process is one of the most popular methods demonstrated to control volatile organic compound (VOCs) emissions from waste gases in semiconductor manufacturing plants. This study attempts to characterize the performance of a concentrator in terms of the removal efficiencies of semiconductor VOCs (isopropyl alcohol [IPA], acetone, propylene glycol methyl ether [PGME], and propylene glycol monomethyl ether acetate [PGMEA]) under several parameters that govern the actual operations. Experimental results indicated that at inlet temperatures of under 40 °C and a relative humidity of under 80%, the removal efficiency of a zeolite concentrator can be maintained well over 90%. The optimal rotation speed of the concentrator is between 3 and 4.5 rph in this study. The optimal rotation speed increases with the VOCs inlet concentration. Furthermore, reducing the concentration ratio helps to increase the removal efficiency, but it also increases the incineration cost. With reference to competitive adsorption, PGMEA and PGME are more easily adsorbed on a zeolite concentrator than are IPA and acetone because of their high boiling points and molecular weights.     

南黄海6.1级地震前巢湖地下水位前兆异常特征的分析

详细介绍了 1996年 11月 9日南黄海 6 1级地震前 ,巢湖地下水动态观测网中 3口水井所记录到的水位经标准差、剩余值数据处理得到的前兆异常。其异常时间以中短期为主 ,不同步。此外还对降雨对井水位的影响以及如何提高地震预报的准确性等问题进行了讨论。