Corn residue level and manure application timing effects on phosphorus losses in runoff

Growing interest in corn (Zea mays L.) silage utilization on Wisconsin dairy farms may have implications for nutrient losses from agricultural lands. Increasing the silage cutting height will increase residue cover and could reduce off-site migration of sediments and associated constituents compared with conventional silage harvesting. We examined the effects of residue level and manure application timing on phosphorus (P) losses in runoff from no-till corn. Treatments included conventional corn grain (G) and silage (SL; 10- to 15-cm cutting height) and nonconventional, high-cut (60-65 cm) silage (SH) subjected to different manure application regimes: no manure (N) or surface application in fall (F) or spring (S). Simulated rainfall (76 mm h(-1); 1 h) was applied in spring and fall for two years (2002-2003), runoff from 2.0- x 1.5-m plots was collected, and subsamples were analyzed for dissolved reactive phosphorus (DRP), total phosphorus (TP), and P mass distribution in four particle size classes. Total P and DRP loads were inversely related to percent residue cover, but both TP and DRP concentrations were unaffected by residue level. Manure application increased DRP concentrations in spring runoff by two to five times but did not significantly affect DRP loads, since higher concentrations were offset by lower runoff volumes. Spring manure application reduced TP loads in spring runoff by 77 to 90% compared with plots receiving no manure, with the extent of reductions being greatest at the lower residue levels (<24%). The TP concentration in sediments increased as particle size decreased. Manure application increased the TP concentration of the 0- to 2-microm fraction by 79 to 125%, but elevated the 2- to 10- and 10- to 50-microm fractions to a lesser extent. Recent manure additions were most influential in enriching transported sediments with P. By itself, higher residue cover achieved by high-cutting silage was often insufficient to lower P losses; however, the combination of manure application and higher residue levels significantly reduced P losses from corn fields harvested for silage.     

Fatal embryo chondral damage associated with fluoroquinolones in eggs of threatened avian scavengers

Stabled livestock reared in housed conditions are often subjected to intensive treatments with veterinary drug, which residues may be present in livestock meat ingested by scavengers, but nothing is known about their presence in eggs of wild birds and their potential detrimental effects on breeding success. We searched for residues of veterinary drugs and other toxicants in infertile and embryonated unhatched eggs of griffon vultures (Gyps fulvus) and red kites (Milvus milvus), two threatened avian scavengers. Quinolones (ciprofloxacin and enrofloxacin) were found in most unhatched eggs of both scavenger species clearly associated with severe alterations in the development of embryo cartilage and bones that could preclude embryo movements and subsequently normal development, pre-hatch position and successful hatching. The detrimental effects on developing eggs of veterinary drugs from livestock operations may help to explain reduced breeding success of avian scavengers.     

Biogeochemical characterization of surface waters in the Aljustrel mining area (South Portugal)

Aljustrel mining area (South Portugal) is a part of the Iberian Pyrite Belt and encloses six sulfide mineral masses. This mine is classified of high environmental risk due to the large tailings’ volume and acid mine drainage (AMD)-affected waters generated by sulfides’ oxidation. The use of biological indicators (e.g., diatoms) revealed to be an important tool to address the degree of AMD contamination in waters. Multivariate analysis has been used as a relevant approach for the characterization of AMD processes. Cluster analysis was used to integrate the significant amount and diversity of variables (physicochemical and biological), discriminating the different types of waters, characterized by the high complexity occurring in this region. The distinction of two main marked phenomena was achieved: (1) the circumneutral-Na-Cl water type (sites DA, PF, BX, BF, RO, CB), expressing the geological contributions of the Cenozoic sediments of Sado river basin, with high diatom diversity (predominating brackish diatoms as Entomoneis alata); and (2) the acid–metal-sulfated water type (sites BM, JU, RJ, AA, MR, BE, PC, AF), reflecting both the AMD contamination and the dissolution of minerals (e.g., silicates) from the hosting rocks, potentiated by the extremely low pH. This last group of sites showed lower diatom diversity but with typical diatoms from acid- and metal-contaminated waters (e.g., Pinnularia aljustrelica). In addition to these two water types, this hierarchical classification method also allowed to distinguish individual cases in subclusters, for example, treated dams (DC, DD), with alkaline substances (lime/limestone), that changed the physicochemical dynamics of the contaminated waters.

     

Residue level and manure application timing effects on runoff and sediment losses

There is growing interest in evaluating the effects of corn silage harvesting methods on erosion control. Increasing the silage cutting height will increase residue cover and could conceivably minimize off-site migration of sediments compared with conventional silage harvesting. The effects of residue level and manure application timing on runoff and sediment losses from no-till corn were examined. Treatments included conventional corn grain (G) and silage (SL) and nonconventional, high-cut (60-65 cm) silage (SH). Corn harvesting treatments were subjected to different manure application regimes: no manure (N) or surface application in fall (F) or spring (S). Simulated rainfall (76 mm/h; 1 h) was applied in spring and fall for two years (2002-2003), runoff from 2.0- x 1.5-m plots collected, and a subsample analyzed for sediment concentration and aggregate size distribution. Runoff volume was inversely related to residue cover. Manure addition to silage plots reduced spring runoff by 71 to 88%, attributable to an increase in soil organic matter content, compared with SH-N and SL-N. Differences in sediment concentration between SH and SL were not significant. For silage plots, spring-applied manure had the greatest influence on sediment export reducing it by 84 to 93% in spring runoff compared with corresponding N plots. Sediment loads were also 85 to 97% lower from SH-S compared with SL-N in all four seasons. Except for spring 2003, sediment export was lower from G compared with SL. The combination of manure and higher residue associated with high-cut silage often lowered sediment export compared with low-cut silage. Nearly identical aggregate size distributions were observed in sediments from SH and SL plots. High residue levels combined with spring-applied manure led to enrichment in the clay-sized fraction of runoff sediment. Recently applied manure and higher residue levels achieved by high-cutting silage can substantially lower sediment losses in spring runoff when soil is most susceptible to erosion.     

Characterisation of sequential leachate discharges of mining waste rock dumps in the Tinto and Odiel rivers

Mining waste rock dumps (WRDs) are potential sources of pollution, which after rainfall produce leachate discharges, loaded with acid mining drainage (AMD). The discharges generally occur in two phases: initial rapid leaching over a period of 1-7 days, followed by a period of variable duration during which leaching decelerates. The relative preponderance of each phase depends on the characteristics of the WRD, including its antecedent hydrological condition, and the temporal pattern and amount of rainfall.     

Application of cluster analysis to the geochemistry zonation of the estuary waters in the Tinto and Odiel rivers (Huelva,Spain)

The combination of acid water from mines, industrial effluents and sea water plays a determining role in the evolutionary process of the chemical makeup of the water in the estuary of the Tinto and Odiel rivers. This estuary is in the southwest of the Iberian Peninsula and is one of the estuarine systems on the northwest coast of the Gulf of Cádiz. From the statistical treatment of data obtained by analyzing samples of water from this system, which is affected by industrial and mining pollution processes, we can see how the sampling points studied form two large groups depending on whether they receive tidal or fluvial influences. Fluvial input contributes acid water with high concentrations of heavy metal, whereas industrial effluents are responsible for the presence of phosphates, silica and other nutrients. The estuarine system of the Tinto and Odiel Rivers can be divided into three areas – the Tinto estuary, the Odiel estuary and the area of confluence – based on the physical – chemical characteristics of the water.