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131.
Gookyoung Heo Yosuke Kimura Elena McDonald-Buller William P.L. Carter Greg Yarwood David T. Allen 《Atmospheric environment (Oxford, England : 1994)》2010,44(40):5365-5374
Alkenes are important in photochemical smog formation in southeast Texas due to their high emissions, especially from industrial sources in and around Houston, and their high reactivities. Therefore, properly characterizing the chemistry of alkenes in condensed mechanisms used in regional photochemical models is important in understanding the formation of ozone and other photochemical air pollutants in Houston. The performance of three versions of the SAPRC condensed chemical mechanism family, for predicting ozone and radical formation, was compared. Simulations were compared to environmental chamber data and ambient data. The analyses showed that separately modeling individual alkenes reactions (especially propene for southeast Texas) has the potential to lead to more accurate simulations of alkene chemistry. Caution must be exercised in un-lumping, however. Testing with different formulations of the 1-butene + O3 reaction demonstrated the complexity and interconnectedness in choices of stoichiometric parameters for un-lumped species and the extent to which lumped mechanisms are un-lumped. 相似文献
132.
Effects of urbanization on the population structure of freshwater turtles across the United States 下载免费PDF全文
David R. Bowne Bradley J. Cosentino Laurel J. Anderson Christopher P. Bloch Sandra Cooke Patrick W. Crumrine Jason Dallas Alexandra Doran Jerald J. Dosch Daniel L. Druckenbrod Richard D. Durtsche Danielle Garneau Kristen S. Genet Todd S. Fredericksen Peter A. Kish Mary Beth Kolozsvary Frank T. Kuserk Erin S. Lindquist Carol Mankiewicz James G. March Timothy J. Muir K. Greg Murray Madeline N. Santulli Frank J. Sicignano Peter D. Smallwood Rebecca A. Urban Kathy Winnett‐Murray Craig R. Zimmermann 《Conservation biology》2018,32(5):1150-1161
Landscape‐scale alterations that accompany urbanization may negatively affect the population structure of wildlife species such as freshwater turtles. Changes to nesting sites and higher mortality rates due to vehicular collisions and increased predator populations may particularly affect immature turtles and mature female turtles. We hypothesized that the proportions of adult female and immature turtles in a population will negatively correlate with landscape urbanization. As a collaborative effort of the Ecological Research as Education Network (EREN), we sampled freshwater turtle populations in 11 states across the central and eastern United States. Contrary to expectations, we found a significant positive relationship between proportions of mature female painted turtles (Chrysemys picta) and urbanization. We did not detect a relationship between urbanization and proportions of immature turtles. Urbanization may alter the thermal environment of nesting sites such that more females are produced as urbanization increases. Our approach of creating a collaborative network of scientists and students at undergraduate institutions proved valuable in terms of testing our hypothesis over a large spatial scale while also allowing students to gain hands‐on experience in conservation science. 相似文献
133.
Davis Greg B. Rayner John L. Donn Michael J. 《Environmental science and pollution research international》2023,30(8):19520-19535
Environmental Science and Pollution Research - Can we hope for autonomous (self-contained in situ) sensing of subsurface soil and groundwater pollutants to satisfy relevant regulatory criteria?... 相似文献
134.
Measurements of groundwater velocity in discrete rock fractures 总被引:1,自引:0,他引:1
Novakowski K Bickerton G Lapcevic P Voralek J Ross N 《Journal of contaminant hydrology》2006,82(1-2):44-60
Estimating groundwater velocity in fracture networks using a Darcy or cubic law calculation is complicated by the wide distribution of fracture aperture often found in these systems and by the difficulty in measuring hydraulic head in discrete fracture features. Although difficult to conduct in a fractured rock setting, the point dilution method can be utilized to collect direct measurements of groundwater velocity in individual fractures. To compare measured against calculated velocities, more than 100 point dilution experiments were conducted within a 35 x 35 m area of a single fracture and in discrete fracture features within a fracture network at a larger scale. The dilution experiments were conducted by isolating a fracture feature in a borehole, measuring the hydraulic aperture, and measuring the decay of an injected tracer due to the advective groundwater flux across the fracture. Groundwater velocity was estimated using the hydraulic aperture and the rate of decay of the injected tracer. Estimates of the local hydraulic gradient were calculated via the cubic law using the velocity estimate and the hydraulic aperture. The results of the tests conducted in the single fracture show variable (1 to 33 m/day) but on average higher velocities in comparison to that measured during a natural gradient tracer experiment conducted previously (in which the effects of matrix diffusion were accounted for) and to that which would be calculated using the cubic law. Based on these results, it was determined that the best estimate of the average groundwater velocity, at the scale of the measurement area used for the cubic law calculations, could only be obtained using the largest apertures in the aperture distribution. Variability of the velocity measurements was also observed over time. Increases in velocity were attributed to the effect of rainfall although concurrent increases in hydraulic gradient were not detected (likely within the tolerance of the measuring devices). The groundwater velocities measured in the fracture network varied over a wider range than at the scale of the single fracture (from 2 to 388 m/day). No correlation, however, was observed between the size of the fracture aperture and measured velocity. 相似文献
135.
Resource planning and management in British Columbia, Canada, has been steadily moving towards more active public participation. While government agencies have long been required to consult the general public during the course of land or resource use planning, the 1990s brought in a period of more intense public involvement. In terms of resource planning, this led to the creation of several new planning processes. Given that there is now considerable experience with the Commission on Resources and Environment (CORE) and the Land and Resource Management Plan (LRMP) processes, it is time for an appraisal. In particular, the paper examines the public's perceptions of these processes with respect to 'what works well' and 'what needs improvement'. The results highlight a number of areas to which process designers and managers should direct attention. There are three key items of note. First, there are generally low levels of awareness by respondents of public consultation processes in their community. Second, there is a need for access to timely, relevant and readable information throughout the course of the process in order to keep participants and the public as up-to-date as possible. Finally, there must be greater clarity about the process itself, including mandates, participants and decision-making powers. 相似文献
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The oxidation of SO2 is commonly regarded as a major driver for new particle formation (NPF) in the atmosphere. In this study, we explored the connection between measured mixing ratio of SO2 and observed long-term (duration > 3 hr) and short-term (duration <1.5 hr) NPF events at a semi-urban site in Toronto. Apparent NPF rates (J30) showed a moderate correlation with the concentration of sulfuric acid ([H2SO4]) calculated from the measured mixing ratio of SO2 in long-term NPF events and some short-term NPF events (Category I) (R2 = 0.66). The exponent in the fitting line of J30 ~ [H2SO4]n in these events was 1.6. It was also found that SO2 mixing ratios varied a lot during long-term NPF events, leading to a significant variation of new particle counts. In the SO2-unexplained short-term NPF events (Category II), analysis showed that new particles were formed aloft and then mixed down to the ground level. Further calculation results showed that sulfuric acid oxidized from SO2 probably made a negligible contribution to the growth of >10 nm new particles. 相似文献
140.
Jim Graham Nick Young Catherine S. Jarnevich Greg Newman Paul Evangelista Thomas J. Stohlgren 《Environmental management》2013,52(4):929-938
Habitat suitability maps are commonly created by modeling a species’ environmental niche from occurrences and environmental characteristics. Here, we introduce the hyper-envelope modeling interface (HEMI), providing a new method for creating habitat suitability models using Bezier surfaces to model a species niche in environmental space. HEMI allows modeled surfaces to be visualized and edited in environmental space based on expert knowledge and does not require absence points for model development. The modeled surfaces require relatively few parameters compared to similar modeling approaches and may produce models that better match ecological niche theory. As a case study, we modeled the invasive species tamarisk (Tamarix spp.) in the western USA. We compare results from HEMI with those from existing similar modeling approaches (including BioClim, BioMapper, and Maxent). We used synthetic surfaces to create visualizations of the various models in environmental space and used modified area under the curve (AUC) statistic and akaike information criterion (AIC) as measures of model performance. We show that HEMI produced slightly better AUC values, except for Maxent and better AIC values overall. HEMI created a model with only ten parameters while Maxent produced a model with over 100 and BioClim used only eight. Additionally, HEMI allowed visualization and editing of the model in environmental space to develop alternative potential habitat scenarios. The use of Bezier surfaces can provide simple models that match our expectations of biological niche models and, at least in some cases, out-perform more complex approaches. 相似文献