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511.
At the national scale, forest cover in Guatemala declined at an annual rate of 1.2% during the past quarter century because of settlement that removed primary forests in the northern region of the country; however, the majority of the population of Guatemala still resides in the densely populated central highlands and has extracted timber and fuelwood from adjacent forests for centuries. Using baseline data recorded in 1987 and 1996, this article reexamined the sustainability of a municipal-communal pine forest in San José La Arada, a municipality in eastern Guatemala. The pine forest declined from the period 1987 to 1996 because of overextraction of timber and fuelwood. Forest structure and forest use were reexamined from the period 1996 to 2007 to test the hypothesis that the forest continued to decline. Forest characteristics such as stand density, basal area, tree height, and evidence of forest use were measured to replicate the procedures from previous work at the study area. To understand changes in forest structure and forest use in the context of the rise in remittances and the introduction of decentralized forest governance that emerged since 1996, a household survey was conducted in two adjacent villages. Forest structure improved from 1996 to 2007. From 1996 to 2007, forest characteristics such as stand density, basal area, tree height, and forest regeneration improved and evidence of forest use decreased in the municipal-communal pine forest. The influence of large amounts of remittances from the United States and other regions of Guatemala to households in the adjacent villages and the decentralization of forest governance largely explains the shift toward forest sustainability in San José La Arada.  相似文献   
512.
513.
ABSTRACT: Constructed wetlands have recently gained popularity as an alternative method for wastewater treatment. This paper compares two design methodologies currently used for constructed wetlands; Tennessee Valley Authority (TVA) and the Environmental Protection Agency (EPA) methods. A discussion of parameters for both methods is given and a wetland treatment system is designed for an individual residence with typical BOD5 loads and flow rates. Calculation results revealed significant discrepancies in the required constructed wetlands volume, and thus detention time, stemming from inherent differences in the design methodologies. The EPA method relies heavily on plug flow kinetics, and is therefore sensitive to changes in the reaction rate constant and media porosity. Conversely, TVA determines the surface area by sizing in accordance with a recommended hydraulic loading criterion and is affected only by the hydraulic flow rates. This study concluded that a constructed wetland is a viable option under design considerations that are not favorable for traditional on-site wastewater treatment methods. However, it is recommended that conservative values for flow and loading rates be assumed to assure complete treatment for either of the design methods.  相似文献   
514.
Winter Quarters Bay (WQB) is a small embayment located adjacent to McMurdo Station, the largest researchbase in Antarctica. The bay is approximately 250 m wide andlong, with a maximum depth of 33 m. Historically, trashfrom the McMurdo Station was piled on the steep shoreline ofWQB, doused with fuel and ignited. That practice hasceased, and the adjacent land area has been regraded tocover the residual waste. The bottom of WQB remainslittered with drums, equipment, tanks, tires, cables, andother objects, especially the southeastern side of the baywhere dumping took place. Sediments are contaminated withPCBs, metals, and hydrocarbon fuels. The objectives of this study were to map the distributionof organic contaminants in WQB, assess the toxicity of WQB sediments using a simple microbial test, anddetermine correlations between toxicity and contaminantlevels. The study suggests that adverse ecological effectshave occurred from one or more of the contaminants found inWQB but the source of the toxic impacts to bay sedimentsremains unknown. Whole sediment toxicity was onlycorrelated with oil-equivalent while solvent extracts ofsediments were correlated with PAHs and oil-equivalent. Theauthors recommend that an integrated research plan bedeveloped that focuses on determining what additionalinformation is needed to make informed decisions on possibleremediation of WQB.  相似文献   
515.
The performance of an integrative passive sampler that consists of a C18 Empore disk sorbent receiving phase fitted with low density polyethylene membrane was optimised for the measurement of time-weighted average concentrations of hydrophobic micropollutants in water. A substantial improvement of sampling characteristics including the rate of sampling and the sampling precision was achieved by decreasing the internal sampler resistance to mass transfer of hydrophobic organic chemicals. This was achieved by adding a small volume of n-octanol, a solvent with high permeability (solubility [times] diffusivity) for target analytes, to the interstial space between the receiving sorbent phase and the polyethylene diffusion-limiting membrane.  相似文献   
516.
Electrical resistance heating (ERH) is an in situ treatment for soil and groundwater remediation that can reduce the time to clean up volatile organic compounds (VOCs) from years to months. The technology is now mature enough to provide site owners with both performance and financial certainty in their site‐closure process. The ability of the technology to remediate soil and groundwater impacted by chlorinated solvents and petroleum hydrocarbons regardless of lithology proves to be beneficial over conventional in situ technologies that are dependent on advective flow. These conventional technologies include: soil vapor recovery, air sparging, and pumpand‐treat, or the delivery of fluids to the subsurface such as chemical oxidization and bioremediation. The technology is very tolerant of subsurface heterogeneities and actually performs as well in low‐permeability silts and clay as in higher‐ permeability sands and gravels. ERH is often implemented around and under buildings and public access areas without upsetting normal business operations. ERH may also be combined with other treatment technologies to optimize and enhance their performance. This article describes how the technology was developed, how it works, and provides two case studies where ERH was used to remediate complex lithologies. © 2005 Wiley Periodicals, Inc.  相似文献   
517.
The long-term mobility of trace metals has been cited as a potential hazard by critics of EPA 503 rule governing the land application of biosolids. The objectives of this study were to assess the accumulation of Cu, Ni, Cd, and Zn within the soil profile; the distribution of exchangeable, specifically adsorbed, organic, and oxide fractions of each metal; and mass balance of Cu, Ni, and Zn 17 yr after a single biosolids application. Biosolids were applied to 1.5- x 2.3-m confined plots of a Davidson clay loam (fine, kaolinitic, thermic Rhodic Kandiudult) in 1984 at 0, 42, 84, 126, 168, and 210 Mg ha(-1). The highest biosolids application supplied 4.5, 750, 43, and 600 kg ha(-1) of Cd, Cu, Ni, and Zn, respectively. Soils were sampled to a depth of 0.9 m and sectioned into 5-cm increments after separating the Ap horizon. Total (EPA-3050B), bioavailable (Mehlich-I), sequential extraction, and dispersible clay analyses were performed on samples from the control, 126 Mg ha(-1), and 210 Mg ha(-1) treatments. Trace metals are still concentrated in the top 0.2 m with slight enrichment down to 0.3 m. More than 85% of applied Cu, Ni, and Zn are still found in the topsoil where biosolids was incorporated and 95% or more of the applied metals were accounted for with mass balance calculations. Mehlich-I results showed a slight increase in metal concentration down to 0.35 m. Biosolids application increased the concentrations of trace metals in all the extracted fractions. The major portions of Cu, Zn, and Ni are associated with the metal-oxides fraction. Dispersible clay content and water-soluble metal contents were low and except for water-soluble Zn they were not affected by biosolids application. Results from this study showed that 17 yr after biosolids application there was negligible movement of trace metals through the soil profile and consequently there is little risk of contamination of ground water at this site.  相似文献   
518.
A wide array of organic chemicals occur in biosolids and other residuals recycled to land. The extent of our knowledge about the chemicals and the impact on recycling programs varies from high to very low. Two significant challenges in regulating these materials are to accurately determine the concentrations of the organic compounds in residuals and to appropriately estimate the risk that the chemicals present from land application or public distribution. This paper examines both challenges and offers strategies for assessing the risks related to the occurrence of organic compounds in residuals used as soil amendments. Important attributes that must be understood to appropriately characterize and manage the potential risks for organic chemicals in biosolids include toxicity and dose response, transport potential, chemical structure and environmental stability, analytical capability in the matrix of interest, concentrations and persistence in waste streams, plant uptake, availability from surface application versus incorporation, solubility factors, and environmental fate. This information is complete for only a few chemicals. Questions persist about the far greater number of chemicals for which toxicity and environmental behavior are less well understood. This paper provides a synopsis of analytical issues, risk assessment methodologies, and risk management screening alternatives for organic constituents in biosolids. Examples from experience in Wisconsin are emphasized but can be extrapolated for broader application.  相似文献   
519.
ABSTRACT: Starting in 1998, a study was conducted to characterize storm water quality from predominant land use types in a coastal watershed along the south central coast of Florida, namely citrus, pasture, urban, natural wetland, row crop, dairy, and golf courses. Sixty‐three sampling sites were located at strategic points on drainage conveyances for each of seven specific land use areas. Runoff samples were collected following storm events that met defined rainfall criteria for a period of 30 months. Nitrogen (N), phosphorus (P), heavy metals, pesticides, and other water quality parameters were determined, and the results were analyzed to compare and characterize land uses as relative sources for these constituents in runoff. Results showed that runoff from most land use types had low dissolved oxygen concentration and that sediment and nutrient concentrations were closely related to land use, particularly to the amount of fertilizer applied in each land use. Among the eight heavy metals tested, copper was the most frequently detected and was mostly associated with runoff from citrus and golf course land uses. High levels of arsenic were also detected in golf course runoff. The most frequently detected pesticide was simazine from citrus. The information and methodologies presented may facilitate pollution source characterization and ecological restoration efforts.  相似文献   
520.
ABSTRACT: An analysis is undertaken to determine the conditions under which membrane desalination becomes an economically preferable alternative for treating brackish water supplies. While membrane desalination is more expensive than conventional treatment, it affords benefits beyond those of conventional processes by reducing salinity related damages. An important and largely unexplored issue regards how the added cost of desalination compares to its benefits in terms of damages avoided. A comparative analysis is undertaken over a range of scenarios with the objective of identifying the treatment technology the leads to the lowest “total economic cost,” a term described by the sum of costs related to supply, treatment, and salinity related damages. Using data from a representative region, desalination yields the lowest total economic cost for source waters that exceed “threshold” salinity concentrations below 1,000 mg/l total dissolved solids (TDS). In instances where standard conventional processes require upgrades to maintain compliance with pending regulations (e.g., disinfection byproducts), the cost gap between membrane and conventional processes is reduced and the threshold concentration lowered. Given the inherent uncertainty in both treatment cost and damage estimates, a sensitivity analysis is conducted to determine which factors have the greatest impact on the treatment decision. Results suggest that considering salinity related damages when selecting a treatment technology makes membrane desalination of brackish waters economically attractive under a wider range of circumstances.  相似文献   
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