阳澄湖浮游植物群落结构与环境因子的典范对应研究

2013年4月（春季）和10月（秋季）对阳澄湖6个点位的浮游植物群落结构进行了调查,共发现浮游植物8门91属184种,其中硅藻门为阳澄湖的主要优势门类,硅藻门中的小环藻属占主要优势种.对六个点位的浮游植物结构组成与9个环境因子的关系进行典范对应分析,结果表明东湖南与中湖北的浮游植物群落结构与其他4个点位差异性较大,pH、高锰酸盐指数、总磷、氨氮、水温是影响浮游植物分布的主要环境因子.     

明矾石在水体微藻去除中的应用研究

以温州市某大学校区内富营养化水体为研究对象,采用本地明矾石对含藻水体进行混凝除藻、除浊实验研究,分别进行投加量、搅拌强度、搅拌时间、静置时间及pH值对微藻去除效率的影响研究,以获得处理工艺的最佳条件,为恢复河流水体生态自净功能提供理论基础.试验中对投加明矾石前后,水体中浊度、总磷、氨氮和总氮进行了测定,结果表明：明矾石最佳投加量为0.35 g/L,最佳搅拌方式为200 rpm搅拌4 min;最佳静置时间为25 min;在碱性或中性水体的处理效果尤佳.     

H2S、NH3混合臭气在生物滴滤池中的净化研究

研究了生物滴滤塔净化含H2S与NH3臭气最佳的生态条件为:在温度为25 ℃、气体通气量为0.4 m3/h、营养盐喷淋量为8.0 L/h、入口H2S质量浓度712.80-948.80 mg/m3、入口NH3质量浓度422.20-795.40 mg/m3、pH值7.0-8.0之间的情况下,去除效率可达90%以上.生物滴滤塔在处理H2S和NH3混合气时,塔内pH值保持在6.5-8.5之间,此pH值对反应器中优势菌的生长繁殖不会造成太大影响,对处理效果影响不大,因此反应过程可不用对pH值进行调节,节约运行成本.     

黄孢原毛平革菌处理染料废水过程中细胞结构损伤效应研究

利用透射电子显微镜观察分析白腐真菌(黄孢原毛平革菌)在处理染料废水活性艳红X-3B过程中,染料和盐度对黄孢原毛平革菌的细胞结构产生的毒性作用.结果表明:活性艳红X-3B染料对黄孢原毛平革菌产生生物毒性作用,且随着染料浓度的增加,细胞受损伤程度不断加深.加入100 mg/L的染料活性艳红X-3B后,黄孢原毛平革菌菌丝细胞形态发生变化,出现质壁分离现象;染料浓度进一步加大,菌丝细胞超微结构受到损伤逐渐严重.染料废水中的盐度对黄孢原毛平革菌细胞也会造成损伤,且损伤程度随盐度增大而增大.NaCl浓度为3 g/L时,菌丝细胞发生质壁分离;而当NaCl加入量高于8 g/L时,细胞膜受损,线粒体、细胞核呈现空泡化,表现为受到不可逆的损伤.染料和盐双因子对黄孢原毛平革菌细胞的损伤效应表现为其损伤程度与单因子作用一致,且染料的影响作用占主导.     

Seasonal and spatial occurrence and distribution of atmospheric polycyclic aromatic hydrocarbons (PAHs) in rural and urban areas of the North Chinese Plain

Passive air sampling (PAS) was employed to study the occurrence of gaseous and particle-bound PAHs in the North Chinese Plain. The averaged concentrations of gaseous and particle-bound PAHs were 485 ± 209 ng/m³ and 267 ± 161 ng/m³, respectively. The PAHs concentrations at urban sites were generally higher than those at rural ones with ratios <1.5 in spring, summer and fall, but differences between them were not significant for the wintertime and annually averaged concentrations. This urban-rural distribution pattern was related to the PAHs emission sources. PAHs spatial variation can be partially (49%) explained by emission with a simple linear regression method. Both the gaseous and particle-bound PAHs were highest in winter and lowest in summer, with winter/summer ratios of 1.8 and 8, respectively. Emission strength was the most important factor for the seasonality.     

Non-aromatic hydrocarbons in surface sediments near the Pearl River estuary in the South China Sea

Surface sediment samples at 4 sites along an offshore transect from outer continental shelf off the Pearl River estuary to the shelf slope region of the northern South China Sea, have been analyzed for total organic carbon (TOC), total nitrogen (TN), solvent extractable organic matter (EOM) and non-aromatic hydrocarbons. TOC, TN and EOM show distinct spatial variations. Their highest values are all recorded at the shelf slope region. EOM varies from 18.70-38.58 microgg(-1) dry sediment and accounts for 0.20-0.72% of the TOC contents. The non-aromatic hydrocarbons are an important fraction of EOM. Their contents range from 3.43-7.06 microgg(-1) dry sediment. n-Alkanes with carbon number ranging from 15-38 are identified. They derive from both biogenic and petrogenic sources in different proportions. Results of isoprenoid hydrocarbons, hopanes and steranes also suggest possible petroleum contamination.     

城市垃圾处理与管理对策研究

对北京、天津、上海、重庆、广州等１７个城市垃圾的调查,结果表明,近１０年,上述城市垃圾总量的增长城市化关系密切,城市垃圾的组分受经济发展,生活水平、消费行为方式的影响,地域差异显著;城市垃圾处理技术欠完善,管理体制不合理,急需通过市场化动作国吧改善。     

西部地区加快开发应当克服“资源近视症”

本文从分析我国传统的经济增长方式入手,通过对资源近视症”的表现及后果的分析,提出西部西地区,特别是西部少数民族地区只有树立全面的资源观,立足优势,面向市场,抓住机遇,合理开发资源和利用资源,才能走出一条符合本民族,本地区实际的可持续发展之路。     

Effects of Compounded Curing Agents on Properties and Performance of Urea Formaldehyde Resin

The effects of three compounded curing agents on the properties and performance of the urea-formaldehyde (UF) resin were investigated in this study. The compounded curing agents were prepared by mixing ammonium chloride with hexamethylenetetramine, citric acid, and oxalic acid respectively at a ratio of 1:1, named N-H, N–CA, and N–OA, respectively. The curing process, crystallinity, and physical properties were measured, and the three-ply plywood was fabricated to measure its prepress strength, wet shear strength, and formaldehyde emission. Results showed that the compounded curing agents N–CA and N–OA enhanced the initial viscosity, crosslinking density and thermal stability of UF resin. Additionally, the prepress strength of the plywood bonded by UF resin with N–CA and N–OA increased by 82 and 111% respectively compared to the UF resin with NH₄Cl, and the wet shear strength increased by 14 and 16%, the formaldehyde emission decreased by 19 and 42% respectively. However, owing to the short pot-life of these curing agent limited their storage time, the curing agents N–CA and N–OA should be applied to fabricate plywood in winter for obtaining a better bond strength and a lower formaldehyde emission. While the UF resin with N–HT showed a suitable pot-life, so it could be applied to fabricate plywood in summer for long time storage and avoiding procuring problem.     

Linking landscape development intensity within watersheds to methyl-mercury accumulation in river sediments

An indicator of the disturbance of natural systems, the landscape development intensity (LDI) index, was used to assess the potential for land-use within watersheds to influence the production/accumulation of methyl-mercury (MeHg) in river sediments. Sediment samples were collected from locations impacted by well-identified land-use types within the Mobile-Alabama River Basin in Southeastern USA. The samples were analyzed for total-Hg (THg) and MeHg concentrations and the obtained values correlated to the calculated LDI indexes of the sampled watersheds to assess the impact of prevalent land use/land cover on MeHg accumulation in sediments. The results show that unlike THg, levels of MeHg found in sediments are impacted by the LDI indexes. Overall, certain combinations of land-use types within a given watershed appear to be more conducive to MeHg accumulation than others, therefore, pointing to the possibility of targeting land-use practices as potential means for reducing MeHg accumulation in sediments, and ultimately, fish contamination.