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161.
162.
使用湿式空气氧化技术与生物技术联合处理TNT精制阶段所产生的红水,研究了湿式空气氧化过程中反应温度、反应时间、初始压强和pH值对流出物的COD值与流出物可生化性的影响规律。研究结果表明,随着反应温度和反应初始压强的升高、反应时间的延长、催化剂投加量的增加和反应pH值的降低,出水COD值均有所下降。在温度为300℃、初始压强为14MPa、反应时间为2h、pH值为5,3、铁盐催化剂添加量为2g的条件下,出水COD值为498mg/L,COD去除率可达到99.27%。在温度为300℃、初始压强为11MPa、反应时间为1h、pH值为3、添加1g铁盐催化剂的条件下:反应流出物的BOD5/COD值为0.301,此时可生化性已经得到很好改善。通过生物方法对反应流出物后续处理发现,湿式空气氧化技术处理TNT红水在反应温度300℃以上,反应流出物均可生物降解。 相似文献
163.
Li Shifeng Guo Yang Xiao Min Zhang Tan Yao Shuhua Zang Shuyan Fan Hongtao Shen Yanming Zhang Zhigang Li Wenxiu 《Environmental science and pollution research international》2019,26(12):12014-12024
Environmental Science and Pollution Research - In this study, Mn-doped MgAl-layered double hydroxides (LDHs) were successfully synthesized for efficient removal arsenate from aqueous solution. The... 相似文献
164.
Guo Jun-Xiong Pan Jie Wang Jing Wang Fei Shi Hong-Xin 《Environmental science and pollution research international》2019,26(20):20499-20509
Environmental Science and Pollution Research - Drinking water containing environmental endocrine disruptor compounds (EDCs) endangers human health, and researching the purification process of... 相似文献
165.
Yuan-Na Xing Ying Guo Mei Xie Ru-Lang Shen 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1382-1387
A solid-phase microextration-based sampling method was employed to determine the concentrations of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and its metabolites, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (DDD), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethene (DDE) and 1-chloro-2,2-bis(p-chlorophenyl)ethene (DDMU), in two estuarine bays, Daya Bay and Hailing Bay, of South China. Six DDT components including p,p′-DDT, o,p′-DDD, p,p′-DDD, o,p′-DDE, p,p′-DDE, and p,p′-DDMU were detected in Hailing Bay, while only p,p′-DDD was found in Daya Bay. p,p′-DDD was the most abundant DDT component in both bays, sharply different from the previous finding in the water column of the Palos Verdes Shelf, California, USA that p,p′-DDE was prevalent. In addition, the occurrence of p,p′-DDMU (with a range of 0.047-0.21 ng/L in Hailing Bay) has not been reported around the globe, and its presence in our study region appeared to stem from dehydrochlorination of p,p′-DDD, favored under aerobic conditions, but further investigations are clearly needed to confirm the mechanism for generation of DDMU in estuarine environments. 相似文献
166.
提出了一种利用移动监测技术研究区域大气环境中PM2.5/PM10空间分布的方法,并在2004年12月进行了宁波市全市域PM2.5/PM10空间分布的研究。数据显示:相同路径所代表的地区PM2.5和PM10具有很好的相关性,多数路径上PM2.5与PM10数据的相关系数平方在0.95以上,而不同路径上PM2.5与PM10的比值不同。文中给出了宁波市PM2.5/PM10污染的空间分布图,直观地显示出PM2.5/PM10污染的空间分布情况,突出了污染的重点点位和地区。 相似文献
167.
Yu Ren Aijun Ding Tao Wang Xinhua Shen Jia Guo Jiamin Zhang Yan Wang Pengju Xu Xinfeng Wang Jian Gao Jeffrey L. Collett 《Atmospheric environment (Oxford, England : 1994)》2009,43(9):1702-1711
Measurement of ambient gas-phase total peroxides was performed at the summit of Mount Tai (Mt. Tai, 1534 m above sea level) in central-eastern China during March 22–April 24 and June 16–July 20, 2007. The hourly averaged concentration of peroxides was 0.17 ppbv (± 0.16 ppbv, maximum: 1.28 ppbv) and 0.55 ppbv (± 0.67 ppbv, maximum: 3.55 ppbv) in the spring and summer campaigns, respectively. The average concentration of peroxides at Mt. Tai, which is in a heavily polluted region, was much lower than hydrogen peroxide measurements made at some rural mountain sites, suggesting that significant removal processes took place in this region. An examination of diurnal variation and a correlation analysis suggest that these removal processes could include chemical suppression of peroxide production due to the scavenging of peroxy and hydroxy radicals by high NOx, wet removal by clouds/fogs rich in dissolved sulfur dioxide which reacts quickly with peroxides, and photolysis. These sinks competed with photochemical sources of peroxides, resulting in different mean concentrations and diurnal pattern of peroxides in the spring and summer. A principal component analysis was conducted to quantify the major processes that influenced the variation of peroxide concentrations. This analysis shows that in the spring photochemical production was an important source of peroxides, and the major sink was scavenging during upslope transport of polluted and humid air from the lower part of the planetary boundary layer (PBL) and wet removal by synoptic scale clouds. During the summer, highly polluted PBL air (with high NOx) was often associated with very low peroxides due to the chemical suppression of HO2 by high NOx and wet-removal by clouds/fogs in this sulfur-rich atmosphere, especially during the daytime. Higher concentrations of peroxides, which often appeared at mid-nighttime, were mainly associated with subsidence of air masses containing relatively lower concentrations of NOy. 相似文献
168.
Songjun Guo Sheng Wen Xinming Wang Guoying Sheng Jiamo Fu Ping Hu Yingxin Yu 《Atmospheric environment (Oxford, England : 1994)》2009,43(22-23):3489-3495
Formaldehyde and acetaldehyde are two most abundant carbonyls in ambient air. Biogenic emission has been proposed as a significant source other than anthropogenic emissions and atmospheric secondary formation. Here at a forest site in South China, the carbon isotopic compositions of formaldehyde and acetaldehyde emitted from leaves of three tree species (Litsea rotundifolia, Canarium album and Castanea henryi) were measured in comparison with the bulk carbon isotopic compositions of tree leaves. δ13C data of the emitted aldehydes (from ?31‰ to ?46‰) were quite different for tree species, which were all more depleted in 13C than the tree-leaf bulk δ13C values (from ?27‰ to ?32‰). Formaldehyde in ambient air at the forest site had δ13C values different from those of leaf-emitted formaldehyde, indicating other sources for ambient formaldehyde apart from direct emission from leaves, most probably the photooxidation of biogenic hydrocarbon like isoprene and monoterpene. The δ13C differences of acetaldehyde between ambient data and those of tree leaves emission were less than 1‰, implying direct biogenic emission as the dominant source. 相似文献
169.
伞罩型湿式脱硫除尘塔入口结构优化模拟 总被引:1,自引:1,他引:0
利用商用CFD软件Fluent,采用k-ε湍流模型和SIMPLE算法,对新型伞罩型湿式脱硫除尘塔内的三维两相流场进行数值模拟,发现了塔内烟气入口处流场所存在的不均匀性。为将其流场调节均匀从而提高脱硫除尘效率,在数值模拟的基础上提出在入口处加装直导流板、阶梯导流板和弯曲导流板,并分析塔内y=0截面速度的分布,以及z=0.21 m截面上的颗粒浓度、速度和压力等参数的分布。结果表明:通过加装阶梯导流板和弯曲导流板均可以将流场调节均匀,达到较理想状态,从而实现高效净化气体的目的。模拟结果对设备的优化设计和实际运行有一定的指导作用。 相似文献
170.
利用烧结脱硫灰制备胶凝材料的研究 总被引:3,自引:0,他引:3
研究了烧结烟气半干法脱硫灰复掺矿渣、钢渣,辅之外加剂,制备胶凝材料的可行性。结果表明,采用改性脱硫灰(GXTLH)、钢渣、矿渣及水泥熟料再混磨制备的复合胶凝材料,具有良好的安定性等水化性能和力学性能;当GXTLH 掺入量为20%、CFII 1.5%、减水剂0.5%及水泥熟料23%时,矿渣掺量在12%~44%、钢渣掺量11%~44%之间制备的胶凝材料初凝时间、终凝时间、力学性能满足GB13592-92《钢渣矿渣水泥标准》;矿渣与钢渣比、水泥熟料及外加剂等掺量一定,GXTLH掺量超过30%时,GXTLH胶凝材料的抗压抗折强度均有所下降。 相似文献