Feed-forward dose control of wastewater chlorination using on-line pH and ORP titration

In this study, a simple automatic pH-ORP titration device was developed for identifying the various ammonia concentrations and chlorine dose requirements for wastewater chlorination by identifying the peaks in the ORP-slope profiles and knees/valleys in the pH profiles. In addition, breakpoint chlorination experiments have shown that the ORP values at the monochloramine humps and breakpoints are linearly correlated with the ammonia concentrations. Therefore, a feed-forward control strategy, based on the chlorine/ammonia weight ratio (Cl/N), is proposed in this paper, to control the chlorine doses for a continuous wastewater chlorination experiment in a laboratory-scale reactor. The result of this continuous wastewater chlorination experiment has shown that the pH-ORP titration was able to precisely determine the variations of ammonia concentrations in the chlorination influent. Under this control strategy, effective and stable disinfection efficiencies in terms of total coliform count were obtained.     

Bronchial dosimeters for radon progeny for Chinese males and females

Bronchial dosimeters have been designed for adult Chinese males and females for home and mine exposures, which can give the bronchial doses from radon progeny by direct measurements. The bronchial dosimeter for home exposures consists of five 400-mesh wire screens. With a sampling face velocity of 3.3 cm s(-1) for Chinese males and 2.7 cm s(-1) for Chinese females, the deposition pattern on the wire screens were found to satisfactorily match the variation of the dose conversion coefficients (in units of mSv WLM(-1)) with the size of radon progeny from 1 to 1000 nm. The bronchial dosimeter for mine exposures consists of four 250-mesh wire screens. With a sampling face velocity of 3.3 cm s(-1), the deposition pattern on the wire screens were found to satisfactorily match the variation of the dose conversion coefficients for both Chinese males and females. In this way, the bronchial dosimeters directly give the bronchial doses from the alpha counts recorded on the wire-screens.     

Simulating interactive effects of symbiotic nitrogen fixation, carbon dioxide elevation, and climatic change on legume growth

The underlying mechanisms of interaction between the symbiotic nitrogen-fixation process and main physiological processes, such as assimilation, nutrient allocation, and structural growth, as well as effects of nitrogen fixation on plant responses to global change, are important and still open to more investigation. Appropriate models have not been adequately developed. A dynamic ecophysiological model was developed in this study for a legume plant [Glycine max (L.) Merr.] growing in northern China. The model synthesized symbiotic nitrogen fixation and the main physiological processes under variable atmospheric CO2 concentration and climatic conditions, and emphasized the interactive effects of these processes on seasonal biomass dynamics of the plant. Experimental measurements of ecophysiological quantities obtained in a CO2 enrichment experiment on soybean plants, were used to parameterize and validate the model. The results indicated that the model simulated the experiments with reasonable accuracy. The R2 values between simulations and observations are 0.94, 0.95, and 0.86 for total biomass, green biomass, and nodule biomass, respectively. The simulations for various combinations of atmospheric CO2 concentration, precipitation, and temperature, with or without nitrogen fixation, showed that increasing atmospheric CO2 concentration, precipitation, and efficiency of nitrogen fixation all have positive effects on biomass accumulation. On the other hand, an increased temperature induced lower rates of biomass accumulation under semi-arid conditions. In general, factors with positive effects on plant growth tended to promote each other in the simulation range, except the relationship between CO2 concentration and climatic factors. Because of the enhanced water use efficiency with a higher CO2 concentration, more significant effects of CO2 concentration were associated with a worse (dryer and warmer in this study) climate.     

Cadmium(II) removal from aqueous solutions by pre-treated biomass of marine alga Padina sp

In this study, the adsorption properties of a pre-treated biomass from marine alga Padina sp., a biomass collected from Surin Island, Thailand, for removal of cadmium(II) ions from aqueous solutions was investigated. Batch and column experiments were conducted to determine the adsorption properties of the modified biomass. At a pH of 5, the maximum removal capacity of the biomass is 0.53 mmol/g. The kinetics of cadmium(II) adsorption were fast with 90% of adsorption taking place within 35 min. This study demonstrated that the pre-treated biomass of Padina sp. could be used as an efficient biosorbent for the treatment of cadmium(II)-bearing wastewater streams.     

钻井环境污染源头控制技术综述

通过对国内外石油行业的钻井环境污染源头控制技术的简单综述,分析了钻井工艺可采用小孔径钻井、连续软管工艺、新型固控设施等的技术特点,对选择合适的钻井液以及应用环保型钻井液来减轻污染方面进行了探讨。并展望了我国石油行业钻井环境污染源头控制技术的发展。     

山东省水环境自动监测监控系统数据的应用设计和使用方法

山东省水环境自动监测监控子系统的主要功能是将全省水质自动站数据利用计算机网络、数据仓库等技术导入到环境监测数据仓库中，实现全省水环境自动监测的统一监控和监测信息的自动管理和发布。本文简单介绍了系统担制中心端监测数据统计应用部分的功能设计和实现方法。     

山东省城市空气自动监测监控系统数据的应用设计和使用方法

山东省城市空气自动监测监控系统的主要功能是将全省城市自动监测站数据利用计算机网络、数据仓库等技术导入到环境监测数据仓库中，实现全省城市空气质量自动监测的统一监控和监测信息的自动管理和发布。本文简单介绍了系统控制中心端监测数据统计应用部分的功能设计和实现方法。     

Fire and explosion risk assessment for large-scale oil export terminal

Now in Russian Federation and other countries large-scale oil terminals (volume of one tank exceeds 100 000 m³, total volume of tanks exceeds 300 000 m³) are designed and constructed. Therefore fire safety of such objects becomes a very important task, solution of which is hardly possible without detail fire risk assessment. This study is aimed to a solution of this problem. Potential, individual and social risks were calculated. The potential risk was defined as a frequency of occurrence of hazardous factors of fires and explosions in a given point of space (the so-called risk contours). The individual risk was defined as a frequency of injuring a given person by hazardous factors of fires and explosions. Time of presence of this person in hazardous zones (near the hazardous installation) is taken into account during calculations of the individual risk. Social risk was defined as a dependence of frequency of injuring a given number of people by hazardous factors of fires and explosions on this number. In practice the social risk is usually determined on injuring not less than 10 people.

The oil terminal under consideration includes the following main parts: crude oil storage consisting of three tanks of volume 100 000 m³ each, input crude oil pipeline of diameter 0.6 m, crude oil pumps, output crude oil pipeline of diameter 0.8 m, auxiliary buildings and facilities. The following main scenarios of tank fires have been considered: rim seal fire, pool fire on a surface of a floating roof, pool fire on a total cross-section surface of the tank, pool fire in a dyke, explosions in closed or semiclosed volumes. Fires and explosions in other parts of the terminal are also taken into account. Effects of escalation of accidents are considered.

Risk contours have been calculated both for the territory of the terminal and for the neighbouring space. The potential risk for the storage zone is near 10⁻⁴–10⁻⁵ year⁻¹, and at a distance 500 m from the terminal the potential risk values do not exceed 10⁻⁶ year⁻¹. The values of the individual risk for various categories of workers are in the range of 10⁻⁵–10⁻⁶ year⁻¹. Because of low number of the workers on the terminal and large distances to towns and villages the social risk value is negligible. These risk values are consistent with practice of the best oil companies, and fire hazard level of the terminal can be accepted as tolerable.     

Comparison of different liquid anaerobic digestion effluents as inocula and nitrogen sources for solid-state batch anaerobic digestion of corn stover

Effluents from three liquid anaerobic digesters, fed with municipal sewage sludge, food waste, or dairy waste, were evaluated as inocula and nitrogen sources for solid-state batch anaerobic digestion of corn stover in mesophilic reactors. Three feedstock-to-effluent (F/E) ratios (i.e., 2, 4, and 6) were tested for each effluent. At an F/E ratio of 2, the reactor inoculated by dairy waste effluent achieved the highest methane yield of 238.5 L/kgVS_feed, while at an F/E ratio of 4, the reactor inoculated by food waste effluent achieved the highest methane yield of 199.6 L/kgVS_feed. The microbial population and chemical composition of the three effluents were substantially different. Food waste effluent had the largest population of acetoclastic methanogens, while dairy waste effluent had the largest populations of cellulolytic and xylanolytic bacteria. Dairy waste also had the highest C/N ratio of 8.5 and the highest alkalinity of 19.3 g CaCO₃/kg. The performance of solid-state batch anaerobic digestion reactors was closely related to the microbial status in the liquid anaerobic digestion effluents.     

基于CFD分析的呼吸防护面具罩体设计

分析呼吸防护面具研究领域在呼吸阻力方面的研究情况,提出基于计算流体力学分析的呼吸防护面具罩体设计方案,在设计过程中添加以计算流体力学分析为手段的有限元模拟仿真模块。通过ANSYS产品ICEM CFD与CFX对设计模型进行网格划分与流体分析,根据仿真结果对初步设计的模型进行结构优化再设计。