Toxaphen in der Umwelt

Residue analysis of toxaphene has been difficult because of the complexity of the technical mixture consisting of a high number of compounds with very similar structure and differing chlorine content. Furthermore, the composition of toxaphene in environmental samples varies widely and is normally not related to that of the technical mixture. Therefore, quantification of single components in environmental samples was impossible. After the isolation and identification of a great number of components during the last decade, enough standards are available for the reliable quantification of toxaphene in all environmental compartments. Recently, most research has been performed on the separation of chiral components of toxaphene with a view to identifying the degradation mechanisms and distribution pathways.     

Photolytic clean-up of biological samples for gas chromatographic analysis of chlorinated paraffins

A method based on gas chromatography electron capture detection (GC-ECD) for the analysis of chlorinated paraffins (CPs) in biological samples has been investigated. The method includes photolytic destruction of halogenated aromatic compounds, such as PCBs, to eliminate some of the interferences in the analysis of CPs in environmental samples. Gel permeation chromatography was used to isolate CPs from the interfering components of Toxaphene and chlordane after the photolysis. GC-ECD gave a detection limit of 20 ng CPs/g fresh muscle tissue. The recovery of CPs from a spiked moose liver sample was estimated to 94%.     

Community strategies to improve flood risk communication in the Red River Basin, Manitoba, Canada

More than a decade after the 1997 Red River Flood, vulnerability to future flooding exists due to a lack of risk communication. This study identifies risk communication gaps and discusses the creation of strategies to enhance information-sharing, bottom-up activity and partnership development. The objectives were achieved using mixed methods, including interviews, a floodplain-wide survey, and a decision-makers' risk management workshop. The results highlight a number of external pressures exerted by regional floodplain policies and procedures that restrict risk communication and affect social vulnerability in the rural floodplain. The failures of a top-down approach to floodplain management have impacted on communities' abilities to address floodplain risks, have amplified local risks, and have decreased community cooperation in floodplain management initiatives since the 1997 'Flood of the Century'. Recommended policies promote the establishment of community standards to compensate for gaps in risk communication and the development of partnerships between floodplain communities.     

Factors influencing the implementation of a safety management system for construction sites

The objective of the study was to determine the influential safety factors that governed the success of a safety management system for construction sites. The number of incidences among construction workers and the level of awareness on matters concerning safety were also determined. The study involved a self-administered three-part questionnaire among the workers and interviews with industry experts involved in brick-laying, concreting and in related assorted trades. Part A of the questionnaire concerned personal particulars, Part B involved training and experience and Part C was based on 28 industry-accepted safety factor elements. The construction sites ranged from high rise buildings, landed houses and infrastructure renovation. The sample size was 275. From the survey it was found that the most influential safety factor was personal awareness followed closely by communication. Suggestions and recommendations on equipment design and improved work practices and procedures to improve the efficiency and productivity of construction workers were proposed. Management was urged to get their workers better informed about safety matters.     

Quantitative elimination of Flavokavines A and B from Kava Kava (<Emphasis Type="Italic">Piper methysticum</Emphasis> G. Forst) by isoelectric focused adsorptive bubble separation

Adsorptive bubble separation, though still rarely used, is a suitable method for enrichment of surface-active macromolecules such as enzymes and proteins. There is a lack of investigations with small molecules, which can also be separated from complex mixtures by this method. In this work, an aqueous extract of Kava Kava (Piper methysticum G. Forst) was used as a model system. Enrichment of undesirable Flavokavine A (7) and Flavokavine B (8) in the foam was influenced by the pH value, the amount of saponin as surface active substance, and the flow rate of the foam-forming gas. Efficiency was highest with diluted samples at pH 6.5. Under these conditions, transfer of Kavapyrone (1–6) to the foam was negligible.     

Analysis of short chain chlorinated paraffins in sediment samples from the Czech Republic by short-column GC/ECNI-MS

Top layer sediment samples from the Czech Republic were analyzed to obtain the preliminary information about contamination of the region by chlorinated paraffins. Sediment samples from three locations with different industrial discharges were taken over the period of 2 years. The analysis was performed by short-column gas chromatography-electron capture negative ion mass spectrometry (SCGC/ECNI-MS). Short chain chlorinated paraffin sediment concentrations varied between 24.00 and 45.78 ng g(-1) (dry weight, d.w.) in the Kosetice area, 16.30-180.75 ng g(-1) (dry weight) in the Zlín area and 4.58-21.57 ng g(-1) dry weight in the Beroun area. Highly chlorinated undecanes prevailed in the samples. On the basis of these results, more detailed studies should be conducted to determine the magnitude and extent of chlorinated paraffin contamination in these regions.     

Visual interpretation of satellite imagery for monitoring floods in Bangladesh

This article presents the methods and results of visual interpretation of NOAA AVHRR imagery for mapping flood areas in Bangladesh. Color composites of channels 1 and 2 for 18 August 1987 and 10, 15, and 24 September 1988 were interpreted visually for delineating flood boundaries. On such imagery flood areas appear in dark tones and are separated from land (light tones) owing to the absorption of near infrared by water and its reflectance by land and non-waterbodies. Visual interpretation was aided by the use of ground information, such as physiographic and river maps, previous flood maps, newspaper reports, and other published and unpublished documents on the 1987 and 1988 floods. Interpreted flood areas on selected images ranged from 31% to 43% of the total area of Bangladesh. Visual interpretation overestimated flood areas by 5%–10%, compared to the digitally analyzed data. The main advantage of visual analysis lies in the cost effectiveness of AVHRR photographic products, which make them more accessible than the digital image analysis of computer-compatible tapes.     

Medium-scale gasification of oil palm empty fruit bunch for power generation

Journal of Material Cycles and Waste Management - This paper focuses on the performance of oil palm empty fruit bunch (EFB) gasification using a medium-scale downdraft gasifier for power...     

Understanding of groundwater salinity using statistical modeling in a small tropical island,East Malaysia

This paper presents an understanding of groundwater salinity by identification of effective factors using chemometric methods (cluster analysis and multiple linear regressions) in Manukan Island, Sabah. Local groundwater and environmental properties were used to explore the effective factors of groundwater salinity. Cluster analysis showed salinity and chloride illustrated the highest similarities. Electrical conductivity and total dissolved solids were also grouped in the same cluster. Seawater is the only chloride source in groundwater of Manukan Island demonstrated an indication of seawater mixing in freshwater. It is an effect of upward movement of the seawater by pumping activities. Precipitation and evapotranspiration (environmental condition) with hydraulic heads were clustered together to show that they also influence salinity concentration in groundwater. Multiple linear regressions showed descending order of the factors from chloride (the largest contribution) to evapotranspiration (the smallest contribution) and illustrated the contribution to groundwater salinity in Manukan Island. The integrated results using chemometric methods have provided a way to identify the effective factors on groundwater salinity. This similar approach and resulting equation can be applied in other small tropical islands with alike hydrogeological condition and limited information available for a better understanding of its groundwater salinity.