Heavy metal release from different ashes during serial batch tests using water and acid

Most ashes contain a significant amount of heavy metals and when released from disposed or used ash materials, they can form a major environmental concern for underground waters. The use of water extracts to assess the easily mobilisable content of heavy metals may not provide an appropriate measure. This study describes the patterns of heavy metal release from ash materials in context with results from the German standard extraction method DIN-S4 (DIN 38 414 S4). Samples of four different ashes (municipal solid waste incineration ash, wood ash, brown coal ash and hard coal ash) were subjected to a number of serial batch tests with liquid renewal, some of which involved the addition of acid to neutralize carbonates and oxides. Release of heavy metals showed different patterns depending on the element, the type of material, the method of extraction and the type of the extractant used. Only a small fraction of the total heavy metal contents occurred as water soluble salts; of special significance was the amount of Cr released from the wood ash. The reaction time (1, 24 or 72 h between each extraction step with water) had only a small effect on the release of heavy metals. However, the release of most of the heavy metals was governed by the dissolution processes following proton inputs, indicating that pH-dependent tests such as CEN TC 292 or others are required to estimate long-term effects of heavy metal releases from ashes. Based on the chemical characteristics of ash materials in terms of their form and solubility of heavy metals, recommendations were made on the disposal or use of the four ash materials.     

Technology use and psychosocial factors in the self-reporting of musculoskeletal disorder symptoms in call center workers

PROBLEM: Evidence exists to suggest that working with computer terminals and keyboards is associated with the development and exacerbation of a range of musculoskeletal disorders (MSDs). Research has suggested that psychosocial factors may be of more importance than computer use factors in the development of MSDs in the computing workplace. METHOD: A questionnaire-based study was undertaken to test this hypothesis in a sample of 67 call center workers. A Spearman's rho was performed on the data, as well as chi(2) tests on the individual variables. RESULTS: It was found that overall, computer use factors were significantly associated with self-reporting of MSD symptoms, whereas psychosocial factors had no such association. However, certain individual psychosocial factors emerged as having a significant association with MSD symptoms. DISCUSSION: The findings suggest that specific areas of call center work have associations with poor worker health and possible long-term MSD problems. These areas appear to be workload and particular management-worker relations, rather than computer use. SUMMARY: This suggests that the relationship among computer use, psychosocial factors, and MSD is a complex area that would benefit from more research. IMPACT ON INDUSTRY: This study raises issues about the importance of psychosocial and organizational factors and employee welfare in the call center working environment.     

Trace elements and organochlorines in surf scoters from San Francisco Bay, 1985

Surf scoters (Melanitta perspicillata) were collected from 6 locations in San Francisco Bay during January and March 1985. Overall, mean concentrations of cadmium and zinc were higher in livers of scoters from the southern region of the Bay, whereas mean iron and lead were higher in those from the northern Bay region. Mean concentrations of arsenic, copper, lead, zinc, aluminum (January only) and iron (January) also differed among individual locations. Mean concentrations of copper and zinc increased, arsenic decreased, and cadmium remained the same between January and March. Selenium and mercury concentrations in scoter livers were not significantly correlated (P>0.05), but cadmium concentrations in livers and kidneys were positively correlated (P<0.0001), and body weight was negatively related to mercury concentration in the liver (P<0.05). Body weight differed among locations but not between January and March. Body weight was correlated with lipid content (P<0.0001). DDE and PCBs were each detected in 34 of 36 scoter carcasses. DDE increased significantly between January and March at Richmond Harbor, but BCBs did not differ between January and March at the 3 locations that could be tested.     

What is this thing called a safety regulation?

Regulation is generally perceived as an important way to achieve safety. Controversy about enforcing, amending, reforming, reducing, improving, and evaluating safety regulations abounds. Questions about the need for, validity, and effectiveness of safety regulations also continue. This paper explores the nature of a safety regulation, what can be expected of a safety regulation in view of its nature, and what this means to persons affected by safety regulation. The role of regulation in safe task performance is reviewed. Consequences of these findings on regulation promulgation, employee training, and regulatory enforcement programs are discussed. Steps to enhance the effectiveness of safety regulations are suggested.     

An analysis of occupational stair accident patterns

This report describes an analysis of existing occupational injury data concerning stairway-related falls. Injury data based on reports obtained from the Ohio and California workers' compensation agencies were analyzed to identify common stair injury patterns. Frequency tabulations are provided for the following factors: (a) location (indoors vs. outdoors, on vs. off employer's premises, site category); (b) task (ascending vs. descending, body movement on the stair, task being attempted); and (c) events (precipitating actions and conditions). One of the most outstanding findings is that 92 % of the injuries occurred when the worker was descending the stair, i.e., 636 of the 688 cases in which direction of travel was indicated. Additionally, injury records from the New York and Ohio workers' compensation agencies were used to rank industries in terms of combined frequency and severity rates of stairway-related injuries.     

Planning for environmental project implementation and development: as exemplified by the songklha lake basin planning study,Thailand

Summary This paper describes use of the economic-cumenvironmental regional development planning process (as differentiated from regional economic planning and regional environmental planning) for its first application in the Asia-Pacific region, for The Songkhla Lake Basin Planning Study, in southern Thailand. The study project was carried out, with Asian Development Bank (ADB) loan financing, as a joint venture of the national economic and national environmental planning agencies. Because of its pioneering nature, in both technical and institutional aspects, numerous lessons were learned from the project. These are described, and yield guidelines valuable for future studies of this type.Dr Harvey F. Ludwig, Chairman of Seatec International Consulting Engineers in Bangkok, has a unique record of distinguished experience in environmental engineering. This includes, in addition to his present role, experience as a professor at the University of California at Berkeley, in research (four USA national awards), in government (as Assistant Chief Engineer of the US Public Health Service Engineering Group, the predecessor to USEPA), and with numerous international assistance agencies including the World Bank, ADB, and many UN affiliates. Dr Ludwig moved to live in Bangkok in 1973 and has since been a continuing adviser to the National Environment Board of Thailand and to the Institutes of Water Resources Research of Indonesia. He is the author/coauthor of some 160 professional publications and the senior author of a textbook onEnvironmental Technology in Developing Countries, now being printed by CRC Press of Boca Raton, Florida. His work record includes projects in more than 30 Developing countries.     

COAL ASH BASIN EFFECTS (PARTICULATES,METALS, ACIDIC pH) UPON AQUATIC BIOTA: AN EIGHT-YEAR EVALUATION1

ABSTRACT Coal ash effluent effects including particulates, acidic pH excursions, elemental concentrations and bioconcentration in selected organisms have been studied as changes in water quality and densities of benthic macroinvertebrate and mosquitofish (Gambusia affinis) populations in a swamp drainage system over an eight-year period. Three changes in the ash basin settling system were made between mid- 1973 and January 1982. Initial density of the aquatic biota was altered severely by heavy ash siltation, followed by acidic pH excursions and perhaps overall by elemental concentrations and bioaccumulation. Heavy ash siltation, followed by acidic Ph excursions (mean of 5.5, extreme of 3.5) after the addition of fly ash to the original settling basin system, had the most profound effect on biota. Dipterans (chironomids) and some odonates (Plathemis lydia and Libellula spp.) were resistant to heavy ash siltation, while mosquitofish, which showed no discernible responses to ash siltation, were absent at acidic pH, along with the few previously surviving invertebrate populations. Elemental concentrations of arsenic, cadmium, chromium, copper, selenium, and zinc did not appear to limit aquatic flora and fauna on a short-term, acute basis. Long, chronic elemental exposures may have been instrumental in retarding the recovery of all forms of aquatic life in the receiving system. Elemental concentrations (except for arsenic and selenium) in the receiving system were generally one to two orders of magnitude higher than the Water Quality Criteria set by the U.S. Environmental Protection Agency (1980) for protection of aquatic life for the minimum and 24-hour mean values. From collective elemental exposures in the receiving system, bioconcentration factors in macrophytes, invertebrates and fish were generally lower than those reported in the literature for laboratory, single elemental concentrations. By 1978, when the new settling basin systems were operating effectively, invertebrate populations were largely recovered, and mosquitofish populations recovered within one year afterward.