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771.
Many studies on geological carbon dioxide (CO2) storage capacity neglect the influence of complex coupled processes which occur during and after the injection of CO2. Storage capacity is often overestimated since parts of the reservoirs cannot be reached by the CO2 plume due to gravity segregation and are thus not accessible for storage. This work investigates the effect of reservoir parameters like depth, temperature, absolute and relative permeability, and capillary pressure on the processes during CO2 injection and thus on estimates of effective storage capacity. The applied statistical characteristics of parameters are based on a large reservoir parameter database. Different measured relative permeability relations are considered. The methodology of estimating storage capacity is discussed. Using numerical 1D and 3D experiments, detailed time-dependent storage capacity estimates are derived. With respect to the concept developed in this work, it is possible to estimate effective CO2 storage capacity in saline aquifers. It is shown that effective CO2 mass stored in the reservoir varies by a factor of 20 for the reservoir setups considered. A high influence of the relative permeability relation on storage capacity is shown. 相似文献
772.
Model-based prediction of long-term leaching of contaminants from secondary materials in road constructions and noise protection dams 总被引:1,自引:0,他引:1
Beyer C Konrad W Rügner H Bauer S Liedl R Grathwohl P 《Waste management (New York, N.Y.)》2009,29(2):839-850
In this study, contaminant leaching from three different secondary materials (demolition waste, municipal solid waste incineration ash, and blast furnace slag) to groundwater is assessed by numerical modeling. Reactive transport simulations for a noise protection dam and a road dam (a typical German autobahn), in which secondary materials are reused as base layers, were performed to predict the breakthrough of a conservative tracer (i.e., a salt) and sorbing contaminants (e.g., PAHs like naphthalene and phenanthrene or heavy metals) at the groundwater table. The dam constructions have a composite architecture with soil covers in inclined layers and distinct contrasts in the unsaturated hydraulic properties of the used materials. Capillary barrier effects result in strong spatial variabilities of flow and transport velocities. Contaminant breakthrough curves at the groundwater table show significant tailing due to slow sorption kinetics and a wide distribution of travel times. While conservative tracer breakthrough depends primarily on subsoil hydraulic properties, equilibrium distribution coefficients and sorption kinetics represent additional controlling factors for contaminant spreading. Hence, the three secondary materials show pronounced differences in the temporal development of leached contaminant concentrations with consequences for breakthrough times and peak concentrations at the groundwater table. Significant concentration reductions due to dispersion occur only if the source concentrations decrease significantly prior to the arrival of the contaminant at the groundwater table. Biodegradation causes significant reduction of breakthrough concentrations only if flow velocities are low. 相似文献
773.
Recycling plants that size, sort and wash construction and demolition waste can produce high quality aggregate. However, they also produce up to 80ton per hour of filter cake waste containing fine (<63mum) silt particles that is classified as inert waste and normally landfilled. This research investigated the potential to form geopolymers containing silt, which would allow this problematic waste to be beneficially reused as aggregate. This would significantly improve the economic viability of recycling plants that wash wastes. Silt filter cakes have been collected from a number of aggregate washing plants operating in the UK. These were found to contain similar aluminosilicate crystalline phases. Geopolymer samples were produced using silt and silt mixed with either metakaolin or pulverised fuel ash (PFA). Silt geopolymers cured at room temperature had average 7-day compressive strengths of 18.7MPa, while partial substitution of silt by metakaolin or PFA increased average compressive strengths to 30.5 and 21.9MPa, respectively. Curing specimens for 24h at 105 degrees C resulted in a compressive strength of 39.7MPa and microstructural analysis confirmed the formation of dense materials. These strengths are in excess of those required for materials to be used as aggregate, particularly in unbound applications. The implications of this research for the management of waste silt at construction and demolition waste washing plants are discussed. 相似文献
774.
This research has applied different chemical activators to mechanically and thermally treated fine fraction (<14 mm) of incinerator bottom ash (IBA), in order to investigate the influences of chemical activators on this new pozzolanic material. IBA has been milled and thermally treated at 800 degrees C (TIBA). The TIBA produced was blended with Ca(OH)(2) and evaluated for setting time, reactivity and compressive strength after the addition of 0.0565 mole of Na(2)SO(4), K(2)SO(4), Na(2)CO(3), K(2)CO(3), NaOH, KOH and CaCl(2) into 100g of binder (TIBA+Ca(OH)(2)). The microstructures of activated IBA and hydrated samples have been characterized by X-ray diffraction (XRD) and thermogravimetry (TG) analysis. Thermal treatment is found to produce gehlenite (Ca(2)Al(2)SiO(7)), wollastonite (CaSiO(3)) and mayenite (Ca(12)Al(14)O(33)) phases. The thermally treated IBA samples are significantly more reactive than the milled IBA. The addition of Na(2)CO(3) can increase the compressive strength and calcium hydroxide consumption at 28-day curing ages. However, the addition of Na(2)SO(4), K(2)SO(4), K(2)CO(3), NaOH and KOH reduces the strength and hydration reaction. Moreover, these chemicals produce more porous samples due to increased generation of hydrogen gas. The addition of CaCl(2) has a negative effect on the hydration of TIBA samples. Calcium aluminium oxide carbonate sulphide hydrate (Ca(4)Al(2)O(6)(CO(3))(0.67)(SO(3))(0.33)(H(2)O)(11)) is the main hydration product in the samples with activated IBA, except for the sample containing CaCl(2). 相似文献
775.
Pollution and health risks generated by improper solid waste management are important issues concerning environmental management in developing countries. In most cities, the use of open dumps is common for the disposal of wastes, resulting in soil and water resource contamination by leachate in addition to odors and fires. Solid waste management infrastructure and services in developing countries are far from achieving basic standards in terms of hygiene and efficient collection and disposal. This paper presents an overview of current municipal solid waste management in Rasht city, Gilan Province, Iran, and provides recommendations for system improvement. The collected data of different MSW functional elements were based on data from questionnaires, visual observations of the authors, available reports and several interviews and meetings with responsible persons. Due to an increase in population and changes in lifestyle, the quantity and quality of MSW in Rasht city has changed. Lack of resources, infrastructure, suitable planning, leadership, and public awareness are the main challenges of MSW management of Rasht city. However, the present situation of solid waste management in this city, which generates more than 400tons/d, has been improved since the establishment of an organization responsible only for solid waste management. Source separation of wastes and construction of a composting plant are the two main activities of the Rasht Municipality in recent years. 相似文献
776.
K. Rajakumar V. Sarasvathy A. Thamarai Chelvan R. Chitra C. T. Vijayakumar 《Journal of Polymers and the Environment》2009,17(3):191-202
Polypropylene (PP) has achieved a dominating position and hence, their consumption increases thereby littering, which lead
to environmental pollution. Photodegradation seems to be a better choice because of naturally available sunlight as energy
source for degradation. The present work involves the study of the variation of degradation behavior of PP film during tropical
summer and winter seasons. The photodegradation is followed by Fourier transform infrared (FTIR) spectroscopic technique.
Various indices like hydroxyl, carbonyl, vinylidene, lactones, ester, carboxylic acid and crystallinity are calculated and
these values increased after a brief induction period. The variation in the mechanical properties like tensile strength and
elongation at break percentages are determined. The scanning electron microscopic (SEM) images of weathered PP showed surface
cracks when carbonyl index value increases sharply and the mechanical properties show a sudden decrease. Attempted life time
prediction using mathematical models showed that the carbonyl growth is more affected by ultraviolet (UV) and cumulative total
solar radiation for PP weathered during summer. The loss in tensile strength of PP weathered during summer is more dependent
on the average temperature and the UV portion of the total solar radiation whereas, intensity of UV radiation has profound
effect on the tensile strength of PP weathered during winter. 相似文献
777.
Richard Roth Paul R. Marques Robert B. VoasAuthor vitae 《Journal of Safety Research》2009,40(6):437-441
Introduction
The effectiveness of ignition interlocks at reducing drunk driving has been limited by the ability of driving-while-intoxicated (DWI) offenders to avoid court orders to install the devices.Methods
In a pilot program in New Mexico, four Santa Fe County judges imposed home confinement (via electronic monitoring bracelets) on offenders who claimed to have no car or no intention to drive. Interlock installation rates for Santa Fe County were compared with all other counties in New Mexico over a 2-year program and 2-year post-program period.Results
During the two program years, 70% of the drivers convicted of DWI in Santa Fe County installed interlocks, compared to only 17% in the other counties, but when the program was terminated, the Santa Fe installation rate fell by 18.8 percentage points.Summary
Mandating the alternative sanction of house arrest led to the highest reported interlock installation rate for DWI offenders.Impact on Industry
Impaired driving is a substantial expense to employers, particularly when it bars driving that interferes with employment. Interlocks provide a method of protecting the public while permitting the offender to drive sober. This study was directed at increasing interlock use by DWI offenders. 相似文献778.
A value of statistical life (VSL) is used in cost-benefit analysis (CBA) as a monetary measure of the benefits to people from small risk reductions that arise from safety projects. Despite its widespread use in a number of countries, the concept of a VSL remains controversial, not least because it implies acceptance of the underlying ethical assumptions of CBA together with the idea that ‘social welfare’ can be measured and aggregated in some manner. In addition, to comply with theory, variable VSLs for different groups within society would be advocated. However, without fail, empirically, it is the case that those countries that employ a willingness to pay based approach to cost-benefit analysis of a safety project appraisal tend to use a single value for that accident context that is independent of the per capita income level, or indeed other personal characteristics, of the sub-group in society to which the safety improvement will actually apply. This article presents a straightforward, but theoretically justified adaptation to the calculation of a VSL which allows empirical practice by policymakers i.e. the application of a “common” VSL for any particular hazard within a given society, to be compatible with a CBA decision making approach. 相似文献
779.
Mario C.R. Vidal Paulo V.R. Carvalho Marcello S. Santos Isaac J.L. dos Santos 《Journal of Loss Prevention in the Process Industries》2009,22(4):516-527
This article aims to describe the characteristics of collective working situations in complex systems – especially those in nuclear power plants – related to common forms of cooperation, in order to improve systems resilience. In addition, we will try to detail some aspects of collective working situations, emphasizing the differences between various forms of control. The similarities between work activities (multi-addressed messages, linkage to regulation, central and peripheral information) are nonetheless exposed. We conclude by proposing a contribution to support systems design, thus facilitating cooperation in teamwork activities. 相似文献
780.
After three decades of sustained continuous improvement of mine safety performances in the US, mine disasters in 2006 and 2007 compromised an excellent record and presented new challenges and vulnerabilities for the underground coal mining industry. In the aftermath of the incidents, formal investigations and new scrutiny of mine safety by the US Congress and expert study groups followed. The US Congress passed the Mine Improvement and New Emergency Response Act of 2006 (MINER Act), which mandated new laws to address the issues, including those related to mine fires and explosions from which miners must be protected. The National Mining Association-sponsored Mine Safety Technology and Training Commission report highlighted the role of risk analysis and management in identifying and controlling major hazards, such as fires and explosions. In this paper an approach is given for analyzing the risks for fires and explosions based on the Mine Safety and Health Administration citation database. Using 2006 citation data and focusing on subsystem failures, the methodology is applied to a database for a pilot sample of underground coal mines stratified by mine size and state. 相似文献