Particle fluxes above forests: observations, methodological considerations and method comparisons

This paper reports a study designed to test, evaluate and compare micro-meteorological methods for determining the particle number flux above forest canopies. Half-hour average particle number fluxes above a representative broad-leaved forest in Denmark derived using eddy covariance range from -7x10(7) m(-2) s(-1) (1st percentile) to 5x10(7) m(-2) s(-1) (99th percentile), and have a median value of -1.6x10(6) m(-2) s(-1). The statistical uncertainties associated with the particle number flux estimates are larger than those for momentum fluxes and imply that in this data set approximately half of the particle number fluxes are not statistically different to zero. Particle number fluxes from relaxed eddy accumulation (REA) and eddy covariance are highly correlated and of almost identical magnitude. Flux estimates from the co-spectral and dissipation methods are also correlated with those from eddy covariance but exhibit higher absolute magnitude of fluxes.     

An assessment of the optimal scale for monitoring of MODIS and FIA NPP across the eastern USA

Robust monitoring of carbon sequestration by forests requires the use of multiple data sources analyzed at a common scale. To that end, model-based Moderate Resolution Imaging Spectroradiometer (MODIS) and field-based Forest Inventory and Analysis (FIA) data of net primary productivity (NPP) were compared at increasing levels of spatial aggregation across the eastern USA. A total of 52,167 FIA plots and colocated MODIS forest cover NPP pixels were analyzed using a hexagonal tiling system. A protocol was developed to assess the optimal scale as an optimal size of landscape patches at which to map spatially explicit estimates of MODIS and FIA NPP. The optimal mapping resolution (hereafter referred to as optimal scale) is determined using spatially scaled z-statistics as the tradeoff between increased spatial agreement as measured by Pearson’s correlation coefficient and decreased details of coverage as measured by the number of hexagons. Spatial sensitivity was also assessed using land cover assessment and forest homogeneity using spatially scaled z-statistics. Pearson correlations indicate that MODIS and FIA NPP are most highly correlated when using large hexagons, while z-statistics indicate an optimal scale at an intermediate hexagon size of 390 km². This optimal scale had more spatial detail than was obtained for larger hexagons and greater spatial agreement than was obtained for smaller hexagons. The z-statistics for land cover assessment and forest homogeneity also indicated an optimal scale of 390 km².     

Mind the gap in SEA: An institutional perspective on why assessment of synergies amongst climate change mitigation, adaptation and other policy areas are missing

This article takes its point of departure in two approaches to integrating climate change into Strategic Environmental Assessment (SEA): Mitigation and adaptation, and in the fact that these, as well as the synergies between them and other policy areas, are needed as part of an integrated assessment and policy response. First, the article makes a review of how positive and negative synergies between a) climate change mitigation and adaptation and b) climate change and other environmental concerns are integrated into Danish SEA practice. Then, the article discusses the implications of not addressing synergies. Finally, the article explores institutional explanations as to why synergies are not addressed in SEA practice. A document analysis of 149 Danish SEA reports shows that only one report comprises the assessment of synergies between mitigation and adaptation, whilst 9,4% of the reports assess the synergies between climate change and other environmental concerns. The consequences of separation are both the risk of trade-offs and missed opportunities for enhancing positive synergies. In order to propose explanations for the lacking integration, the institutional background is analysed and discussed, mainly based on Scott's theory of institutions. The institutional analysis highlights a regulatory element, since the assessment of climate change synergies is underpinned by legislation, but not by guidance. This means that great focus is on normative elements such as the local interpretation of legislation and of climate change mitigation and adaptation. The analysis also focuses on how the fragmentation of the organisation in which climate change and SEA are embedded has bearings on both normative and cultural-cognitive elements. This makes the assessment of synergies challenging. The evidence gathered and presented in the article points to a need for developing the SEA process and methodology in Denmark with the aim to include climate change in the assessments in a more systematic and integrated manner.     

Supporting Diverse Data Providers in the Open Water Data Initiative: Communicating Water Data Quality and Fitness of Use

Shared, trusted, timely data are essential elements for the cooperation needed to optimize economic, ecologic, and public safety concerns related to water. The Open Water Data Initiative (OWDI) will provide a fully scalable platform that can support a wide variety of data from many diverse providers. Many of these will be larger, well‐established, and trusted agencies with a history of providing well‐documented, standardized, and archive‐ready products. However, some potential partners may be smaller, distributed, and relatively unknown or untested as data providers. The data these partners will provide are valuable and can be used to fill in many data gaps, but can also be variable in quality or supplied in nonstandardized formats. They may also reflect the smaller partners' variable budgets and missions, be intermittent, or of unknown provenance. A challenge for the OWDI will be to convey the quality and the contextual “fitness” of data from providers other than the most trusted brands. This article reviews past and current methods for documenting data quality. Three case studies are provided that describe processes and pathways for effective data‐sharing and publication initiatives. They also illustrate how partners may work together to find a metadata reporting threshold that encourages participation while maintaining high data integrity. And lastly, potential governance is proposed that may assist smaller partners with short‐ and long‐term participation in the OWDI.     

Degradation of the herbicide dichlobenil and its metabolite BAM in soils and subsurface sediments

The worldwide used herbicide dichlobenil (2,6-dichlorobenzonitrile) has resulted in widespread presence of its metabolite 2,6-dichlorobenzamide (BAM) in surface water and groundwater. To evaluate the potential for natural attenuation of this BAM pollution in groundwater, we studied the degradation of BAM and dichlobenil in 16 samples of clayey till, unconsolidated sand and limestone, including sediments from both oxidized and reduced conditions. The degradation of dichlobenil occurred primarily in the upper few meters below surface, although dichlobenil was strongly sorbed to these sediments. However, the degradation of dichlobenil to BAM could not be correlated to either sorption, water chemistry, composition of soils or sediments. Degradation of dichlobenil to BAM was limited (<2% degraded) in the deeper unsaturated zones, and no degradation was observed in aquifer sediments. This illustrates, that dichlobenil transported to aquifers does not contribute to the BAM-contamination in aquifers. A small, but significant degradation of BAM was observed in the upper part of the unsaturated zones in sandy sediments, but no degradation was observed in the clayey till sediment or in the deeper unsaturated zones. The insignificant degradation of BAM in aquifer systems shows that BAM pollution detected in aquifers will appear for a long time; and consequently the potential for natural attenuation of BAM in aquifer systems is limited.     

Hydrocarbon emission fingerprints from contemporary vehicle/engine technologies with conventional and new fuels

The present paper presents results from the analysis of 29 individual C₂–C₉ hydrocarbons (HCs) specified in the European Commission Ozone Directive. The 29 HCs are measured in exhaust from common, contemporary vehicle/engine/fuel technologies for which very little or no data is available in the literature. The obtained HC emission fingerprints are compared with fingerprints deriving from technologies that are being phased out in Europe. Based on the total of 138 emission tests, thirteen type-specific fingerprints are extracted (Mean ± SD percentage contributions from individual HCs to the total mass of the 29 HCs), essential for receptor modelling source apportionment. The different types represent exhaust from Euro3 and Euro4 light-duty (LD) diesel and petrol-vehicles, Euro3 heavy-duty (HD) diesel exhaust, and exhaust from 2-stroke preEuro, Euro1 and Euro2 mopeds. The fuels comprise liquefied petroleum gas, petrol/ethanol blends (0–85% ethanol), and mineral diesel in various blends (0–100%) with fatty acid methyl esters, rapeseed methyl esters palm oil methyl esters, soybean oil methyl or sunflower oil methyl esters. Type-specific tracer compounds (markers) are identified for the various vehicle/engine/fuel technologies.An important finding is an insignificant effect on the HC fingerprints of varying the test driving cycle, indicating that combining HC fingerprints from different emission studies for receptor modelling purposes would be a robust approach.The obtained results are discussed in the context of atmospheric ozone formation and health implications from emissions (mg km^?1 for LD and mopeds and mg kW h^?1 for HD, all normalised to fuel consumption: mg dm^?3 fuel) of the harmful HCs, benzene and 1,3-butadiene.Another important finding is a strong linear correlation of the regulated “total” hydrocarbon emissions (tot-HC) with the ozone formation potential of the 29 HCs (ΣPO₃ = (1.66 ± 0.04) × tot-RH; r² = 0.93). Tot-HC is routinely monitored in emission control laboratories, whereas C₂–C₉ are not. The revealed strong correlations broadens the usability of data from vehicle emission control laboratories and facilitates the comparison of the ozone formation potential of HCs in exhaust from of old and new vehicle/engine/fuel technologies.     

An Air Quality Data Analysis System for Interrelating Effects,Standards, and Needed Source Reductions: Part 13— Applying the EPA Proposed Guidelines for Carcinogen Risk Assessment to a Set of Asbestos Lung Cancer Mortality Data

Abstract

The Clean Air Act Amendments of 1990 (CAAA-90) list 189 hazardous air pollutants (HAPs) for which “safe” ambient concentrations are to be determined. The primary purpose of this paper is to develop two mathematical models, lognormal and logarithmic, that effectively express excess lung cancer mortality as a function of asbestos concentration for an example set of data and also to suggest using these two models for additional HAPs. The secondary purpose of this paper is to calculate a “safe” asbestos concentration by first assuming a default linear extrapolation (to one excess death per million people, as specified for carcinogenic HAPs). The resulting “safe” concentration is an impossible-to-achieve 1/1000 of present background asbestos concentrations. A letter to the editor and a response in this Journal issue use additional asbestos data that suggest that the “safe” concentration should be about 730 times higher than first calculated here and that a default nonlinear extrapolation should be used instead, with the “safe” concentration proportional to the desired mortality level raised to the 0.39 power. These results suggest that the most important problem in setting a “safe” concentration for each carcinogenic HAP is to determine the correct nonlinear extrapolation to use for each HAP.     

Moving Bed Adsorption System for Control of VOCs from an Aircraft Painting Facility

An activated carbon moving bed system (10 to 100 acf m air flow) was tested for controlling VOC emissions from a commercial aircraft painting facility. The cross-flow moving adsorbent bed showed a VOC collection efficiency in the 77.1 to 99.6 percent range over a superficial gas velocity range of 27 to 185 ft/min (0.14-0.94 m/sec). The collection efficiencies were neither affected by a change in carbon flow rates from 5 to 8 Ib/hr (2.3 to 3.6 kg/hr) nor by a change in the gas superficial velocity from 27 to 185 ft/min. The VOC concentration in the emission stream from the painting hangar was found to vary by at least a factor of 20 (from 0.18 to 15 ppm) both over the five month period (during which the 15 system tests of about three hours each were conducted) and within a single eight hour work shift.     

The Radial Distribution of Sulfur Dioxide Source Strength and Concentration in Nashville

This progress report describes the National Air Pollution Technical Information Center currently under development in the Division of Air Pollution, Public Health Service. It briefly reviews the report "Science, Government, and Information" (Weinberg Report) and the White House delegation of responsibility to the Department of Health, Education, and Welfare for handling air pollution technical information.