Comparison of palladium and platinum in environmental matrices: Palladium pollution by automobile emissions?

A new type of automobile catalyst based on an active Pd/Rh-layer is presently being introduced into the European market. Accordingly, in order to establish baseline information, this work attempts to assess the magnitude of Pd emissions by automobile catalysts to date. Thus, a survey is presented on Pd and Pt levels detected in polluted environmental matrices (grass, soil, dust, sludges) as available from the literature. Additionally, Pd data measured by selective preconcentration/GF-AAS-detection in polluted grass, in a time series of sewage sludge ashes back to 1972, in dust, as well as in urban rain are presented. Since the data basis from the literature is partly inconsistent, the possible impact of different analytical attempts on the data is discussed. The relationship between Pt and Pd concentration from most of the results is between 5 and 10 (Pt/Pd). However, relations down to 0.04 are also reported, thus implying anthropogenic Pd input from additional sources.     

Platinum emission rate of automobiles with catalytic converters

Inconsistent data presently available on the platinum emission rate of cars in Germany equipped with catalytic converters are evaluated. Automobile sources of Pt other than autocatalysts are quantified and found to be 1–6 orders of magnitudes lower than the Pt emissions attributed to catalytic converters. A transfer of emission rates derived from test stand experiments to more realistic street conditions reaches 0.8 μg Pt/km. In this manner, data from test stand experiments and from environmental investigations meet in the range of 0.5–0.8 μg Pt/km.     

Innovation and diffusion of clean/green technology: Can patent commons help?

This paper explores the characteristics of 238 patents on 90 inventions contributed by major multinational innovators to the “Eco-Patent Commons”, which provides royalty-free access to third parties to patented innovations on green technologies. We compare the pledged patents to other patents in the same technologies or held by the same multinationals to investigate the motives of the contributing firms as well as the potential for such commons to encourage innovation and diffusion of climate change related technologies. We find pledged patents to protect environmentally friendly technologies and to be of similar value as the average patent in a pledging firm's patent portfolio but of lower value than other patents in their class. Our analysis of the impact of the patent commons on diffusion of patented technologies suggests that making patents accessible royalty-free did not result in any significant increase in diffusion as measured by citing patents. This study, therefore, indirectly provides evidence on the role of patents in the development and diffusion of green technologies.