PM2.5 samples were collected by a three-stage cascade impactor at two kinds of Chinese restaurants to characterize fine organic particulate matter from Chinese cooking sources. Major individual organic compounds have been quantified by GC/MS, including series of alkanes, n-alkanoic acids, n-alkanals, alkan-2-0nes and PAHs.Alkanes and ketones make up a significant fraction of particle-phase organic compounds, ranging from C11 to C26,and (C9 to C19, respectively. In addition, other organic compound classes have been identified, such as alkanols,esters, furans, lactones, amides, and nitriles. The mass concentrations of fine particles, alkanes, n-alkanoic acids and PAHs in air emitted from the Uigur style cooking are hundreds times higher than ambient PM2.5in Beijing. 相似文献
Ecological indicators have widespread appeal to scientists, environmental managers, and the general public. Remote sensing is unique in its capability to record variety of spatio-temporal information on land surface with complete coverage, especially with regard to larger spatial scales, which has been proven to be an effective data source to create indicators to rapidly identify regional eco-environment. In this paper, a new index, remote sensing based ecological index (RSEI) based on the pressure-state-response (PSR) framework, was applied to assess regional ecological changes in Fuzhou City of Fujian Province, southeastern China, using Landsat ETM+/OLI/TIRS images. Taking the advantages of being totally free of artificial interference in the calculation using principal components analysis (PCA) to assign weights of each variable, the RSEI can assess the regional ecological status more objectively and easily. The effectivity of the new index was validated by four approaches, including point-based, classification-based, correlation-based, and urban-rural-gradient-based comparisons. The case study showed that Fuzhou has witnessed ecological improvement during the study period, with the value of RSEI increasing from 0.663 in 2000 to 0.675 in 2016. Spatial variation analysis showed that the poor level of RSEI distributed mostly in the central urban areas, and the ecological degradation was attributed to the fast expansion of the built-up area, characterized by increasing greatly in the value of the normalized differential built up and soil index (NDBSI) in such areas.
Strategies are needed to increase the sustainability of phosphorus (P) fertiliser management in agriculture. This paper reports on the potential of pyrolysis treatment to recycle P from renewable materials previously regarded as wastes. The study used K-edge X-ray absorption near-edge structure (XANES) spectroscopy to examine chemical forms of P in the waste feedstock materials and corresponding biochars (pyrolysis at 480–500 °C) of four ligno-cellulosic, plant-based residues and five relatively P-rich livestock and water-treatment by-products, to acquire information on changes in potential P fertiliser value. Pyrolysis enriched P in the biochars by factors of 1.3–4.3, thus offering wide-ranging P fertiliser potential. XANES spectroscopy revealed hydroxyapatite (HAP) as one of the dominant chemical P compounds in the feedstocks, ranging from 14% (rice husks) to 98% (animal bone) of total P. For most materials, pyrolysis increased the proportion of HAP, and pyrophosphates were generated in several cases. These alterations possibly lead to diversity in the P solubility characteristics of the biochars if used as soil amendments; this is an important property of environmentally sound P fertilisers. 相似文献