Adsorption mechanism of Zn2+, Ni2+, Cd2+, and Cu2+ ions by carbon-based adsorbents: interpretation of the adsorption isotherms via physical modelling

Environmental Science and Pollution Research - A theoretical physicochemical and thermodynamic investigation of the adsorption of heavy metals Zn2+, Cd2+, Ni2+, and Cu2+on carbon-based adsorbents...     

Landfill leachate enhances fermentative hydrogen production from glucose and sugarcane processing derivatives

Fermentation can use renewable raw materials as substrate, which makes it a sustainable method to obtain H₂. This study evaluates H₂ production by a mixed culture from substrates such as glucose and derivatives from sugarcane processing (sucrose, molasses, and vinasse) combined with landfill leachate. The leachate alone was not a suitable substrate for biohydrogen production. However, leachate blended with glucose, sucrose, molasses, or vinasse increased the H₂ production rate by 2.0-, 2.8-, 4.6-, and 0.5-fold, respectively, as compared with the substrates without the leachate. Determination of metals (Cu, Cd, Pb, Hg, Ni, and Fe) at the beginning and at the end of the fermentative assays showed how they were consumed during the fermentation and demonstrated improved H₂ production. During fermentation, Cu, Fe, and Cd were the most consumed leachate metals. The best substrate combination to produce H₂ was molasses and leachate, which gave high volumetric productivity—469 ml H₂/l h. However, addition of the leachate to the substrates stimulated lactic acid formation pathways, which lowered the H₂ yield. The use of leachate combined with sugarcane processing derivatives as substrates could add value to the leachate and reduce its polluting power, generating a clean energy source from renewable raw materials.     

Water Management Decision Making in the Face of Multiple Forms of Uncertainty and Risk

In the Wasatch Range Metropolitan Area of Northern Utah, water management decision makers confront multiple forms of uncertainty and risk. Adapting to these uncertainties and risks is critical for maintaining the long‐term sustainability of the region's water supply. This study draws on interview data to assess the major challenges climatic and social changes pose to Utah's water future, as well as potential solutions. The study identifies the water management adaptation decision‐making space shaped by the interacting institutional, social, economic, political, and biophysical processes that enable and constrain sustainable water management. The study finds water managers and other water actors see challenges related to reallocating water, including equitable water transfers and stakeholder cooperation, addressing population growth, and locating additional water supplies, as more problematic than the challenges posed by climate change. Furthermore, there is significant disagreement between water actors over how to best adapt to both climatic and social changes. This study concludes with a discussion of the path dependencies that present challenges to adaptive water management decision making, as well as opportunities for the pursuit of a new water management paradigm based on soft‐path solutions. Such knowledge is useful for understanding the institutional and social adaptations needed for water management to successfully address future uncertainties and risks.     

Assessment of Presence of Heavy Metals and Other Pollution Burden Parameters and Their Effect on Water Quality in Benin City,Edo State

An assessment of the heavy metal content and biological pollution burden of an abattoir dumpsite, an automobile carwash, the Ikpoba River, and a private water borehole located near the abattoir dumpsite was conducted in Benin City in Southern Nigeria, during the rainy and dry seasons. The water samples’ pH was lower than the permissible values, with the river water displaying color and possessing a slight odor. Iron concentrations exceeded the permissible limits for drinking water at all four of the sampling stations in the study area, although not in samples collected from the control station, station 5, a public water borehole that is located some distance away. Lead values were higher than drinking water standards in the samples collected from stations 1 through 4, with some exceptions during the rainy season. Copper, nickel, arsenic, chromium, and aluminum were detected in three out of the four sampling stations located within the study area. However, these metals were detected at levels that were within regulatory limits. The detection of three metals (iron, lead, and zinc) within the study area at levels exceeding drinking water limits suggested that a complete cycle of movement of pollutants into the sampling stations had occurred. Significant biological presences were also detected, as the Ikpoba River water had a standard plate count (SPC) of 130 most probable number (MPN) and a 22 MPN presumptive coliform count (PCC) or 22 MPN. However, Escherichia coli (E. coli) confirmatory tests recorded less than 2 MPN in both seasons. The study has shown that the quality of water in the river may be compromised by effluent discharges from the dumpsite and the carwash channel. Therefore, this situation requires more stringent enforcement of local environmental laws and maintenance of safe distances between domestic and industrial waste sources and domestic or private water wells.     

Factors Affecting Flood Disasters in Small Island Developing States and Potential Adaptation Measures: The Case of Funchal City,Portugal

This work highlights the evolution of flood disasters and their impacts upon environmental and socioeconomic aspects both worldwide and in Small Island Developing States (SIDS) in particular. For our research, we reviewed the stress factors affecting flood disasters and performed surveys of two focus groups in Funchal municipality on Madeira Island (Portugal). Our research identifies the main causes of the serious impacts that flash floods can have on Funchal city. These include:

• The occupation of floodplain areas,
• Canalization of water courses,
• Erosion and transport of soil from upstream hillslopes due to deforestation, and
• Intensive precipitation of long duration.

     

Benchmarking Optical/Thermal Satellite Imagery for Estimating Evapotranspiration and Soil Moisture in Decision Support Tools

Generally, one expects evapotranspiration (ET) maps derived from optical/thermal Landsat and MODIS satellite imagery to improve decision support tools and lead to superior decisions regarding water resources management. However, there is lack of supportive evidence to accept or reject this expectation. We “benchmark” three existing hydrologic decision support tools with the following benchmarks: annual ET for the ET Toolbox developed by the United States Bureau of Reclamation, predicted rainfall‐runoff hydrographs for the Gridded Surface/Subsurface Hydrologic Analysis model developed by the U.S. Army Corps of Engineers, and the average annual groundwater recharge for the Distributed Parameter Watershed Model used by Daniel B. Stephens & Associates. The conclusion of this benchmark study is that the use of NASA/USGS optical/thermal satellite imagery can considerably improve hydrologic decision support tools compared to their traditional implementations. The benefits of improved decision making, resulting from more accurate results of hydrologic support systems using optical/thermal satellite imagery, should substantially exceed the costs for acquiring such imagery and implementing the remote sensing algorithms. In fact, the value of reduced error in estimating average annual groundwater recharge in the San Gabriel Mountains, California alone, in terms of value of water, may be as large as $1 billion, more than sufficient to pay for one new Landsat satellite.     

Developing Effective Decision Support for the Application of “Gentle” Remediation Options: The GREENLAND Project

Gentle remediation options (GRO) are risk management strategies/technologies that result in a net gain (or at least no gross reduction) in soil function as well as risk management. They encompass a number of technologies, including the use of plant (phyto‐), fungi (myco‐), and/or bacteria‐based methods, with or without chemical soil additives or amendments, for reducing contaminant transfer to local receptors by in situ stabilization, or extraction, transformation, or degradation of contaminants. Despite offering strong benefits in terms of risk management, deployment costs, and sustainability for a range of site problems, the application of GRO as practical on‐site remedial solutions is still in its relative infancy, particularly for metal(loid)‐contaminated sites. A key barrier to wider adoption of GRO relates to general uncertainties and lack of stakeholder confidence in (and indeed knowledge of) the feasibility or reliability of GRO as practical risk management solutions. The GREENLAND project has therefore developed a simple and transparent decision support framework for promoting the appropriate use of gentle remediation options and encouraging participation of stakeholders, supplemented by a set of specific design aids for use when GRO appear to be a viable option. The framework is presented as a three phased model or Decision Support Tool (DST), in the form of a Microsoft Excel‐based workbook, designed to inform decision‐making and options appraisal during the selection of remedial approaches for contaminated sites. The DST acts as a simple decision support and stakeholder engagement tool for the application of GRO, providing a context for GRO application (particularly where soft end‐use of remediated land is envisaged), quick reference tables (including an economic cost calculator), and supporting information and technical guidance drawing on practical examples of effective GRO application at trace metal(loid) contaminated sites across Europe. This article introduces the decision support framework. ©2015 Wiley Periodicals, Inc.     

BR-319: Brazil’s Manaus-Porto Velho Highway and the Potential Impact of Linking the Arc of Deforestation to Central Amazonia

Brazil’s BR-319 Highway linked Manaus, in the state of Amazonas, to Porto Velho, Rondônia, until it became impassable in 1988. Now it is proposed for reconstruction and paving, which would facilitate migration from the “Arc of Deforestation” in the southern part of the Amazon region to new frontiers farther north. The purpose of the highway, which is to facilitate transport to São Paulo of products from factories in the Manaus Free Trade Zone, would be better served by sending the containers by ship to the port of Santos. The lack of a land connection to Manaus currently represents a significant barrier to migration to central and northern Amazonia. Discourse regarding the highway systematically overestimates the highway’s benefits and underestimates its impacts. A variety of changes would be needed prior to paving the highway if these potential impacts are to be attenuated. These include zoning, reserve creation, and increased governance in various forms, including deforestation licensing and control programs. More fundamental changes are also needed, especially the abandonment of the long-standing tradition in Brazil of granting squatters’ rights to those who invade public land. Organizing Amazonian occupation in such a way that road construction and improvement cease to lead to explosive and uncontrolled deforestation should be a prerequisite for approval of the BR-319 and other road projects for which major impacts are expected. These projects could provide the impetus that is needed to achieve the transition away from appropriation of public land by both small squatters and by grileiros (large-scale illegal claimants). A delay in reconstructing the highway is advisable until appropriate changes can be effected.     

“Modern agriculture” transfers many pesticides to watercourses: a case study of a representative rural catchment of southern Brazil

Environmental Science and Pollution Research - The total cultivated area in Brazil reached to 62 million ha in 2018, with the predominance of genetically modified soybean and corn (36 and 17...     

Carbon stocks and losses to deforestation in protected areas in Brazilian Amazonia

Regional Environmental Change - By 2014 approximately 2.2 million km2 (~43%) of Brazil’s Legal Amazonia region had been incorporated into an extensive network of 718 protected areas, which...