NITRATE TRANSFORMATIONS IN SOUTHERN ONTARIO STREAM SEDIMENTS1

The transformation of nitrate was investigated in diverse stream sediments from six areas of Southern Ontario, Canada. Laboratory Experiments conducted with intact 0-5 cm depth sediment cores overlain with aerated 5 mg/l nitrate-N solution reveald considerable nitrate depletion during a six-day period as a resuit of denitrification and nitrate reduction to ammonium. Nitrification and ammonification also occurred simultaneously with nitrate reduction in many stream sediments. Mixed 0-5 cm depth sediments collected from 81 stream sites were used to examine the relationship between microbial nitrate removal and sediment characteristics. Rates of nitrate-N loss from aerated 5 mg/l nitrate-N solutions overlying these sediments ranged between 11 and 171 mg/m²/day for a 24-hour incubation period. Rates of nitrate loss for the 24-hour period exhibited a significant positive correlation (r=0.72) with sediment ammonium content. Organic carbon, total nitrogen and sediment texture also had significant but weak correlations with nitrate loss.     

A SELF-VERIFYING HYBRID COMPUTER MODEL OF RIVER-BASIN HYDROLOGY1

ABSTRACT. As demands upon available water supplies increase, there is an accompanying increase in the need to assess the downstream consequences resulting from changes at specific locations within a hydrologic system. The problem is approached in this study by hybrid computer simulation of the hydrologic system. Modeling concepts are based upon the development of basic relationships which describe the various hydrologic processes. Within a system these relationships are linked by the continuity-of-mass principle. Spatial resolution is achieved by considering the modeled areas as a series of subbasins. The time increment adopted for the model is one month, so that time varying quantities are expressed in terms of mean monthly values. The model is general in nature and is applied to a particular hydrologic system through a programmed verification procedure whereby model coefficients are evaluated for the particular system. In this study the model is applied to the Bear River basin of western Wyoming, southern Idaho, and northern Utah. Comparisons between observed and computed outflow hydrographs show good agreement. The utility of the model is demonstrated by predicting the effects of various possible water resource management alternatives. The verified hybrid computer program can be digitized for application to the digital computer.     

Differences in resistance of three subtropical vegetation types to experimental trampling

Experimental trampling trials using a standardized methodology were undertaken in 10 replicate blocks in three vegetation types in an urban reserve in the subtropics of Australia. In each block different intensities of trampling (controls, 10, 25, 50, 100, 150, 200, 250, 300, 400 and 500 passes) were applied, and vegetation parameters were measured pre-trampling, immediately after trampling and 2 weeks later. A Fern understorey had low resistance to trampling intensity, with reductions in relative vegetation height and cover with as few as 10 passes. A Tussock grass understorey showed moderate resistance with reduction in height at 25 passes and cover at 50 passes. A Disturbed grassland dominated by lawn grasses had the highest resistance, with reductions in vegetation height at 100 passes, but cover was affected by as few as 10 passes. The resistance indices (number of passes required to reduce vegetation cover by 50%) of three vegetation types were 210, 360 and 860 passes, respectively. When these values were compared with those for 52 other vegetation types considerable variation was found within life forms, climatic zones and vegetation types indicating that the response of a specific community may not always be predictable.     

Estimating Evapotranspiration and Seepage for a Sinkhole Wetland From Diurnal Surface‐Water Cycles1

Abstract: This study used measured diurnal surface‐water cycles to estimate daily evapotranspiration (ET) and seepage for a seasonally flooded sinkhole wetland. Diurnal surface‐water cycles were classified into five categories based on the relationship between the surface‐water body and the surrounding ground‐water system (i.e., recharge/discharge). Only one class of diurnal cycles was found to be suitable for application of this method. This subset of diurnal cycles was used to estimate ET and seepage and the relative importance of each transfer process to the overall water budget. The method has limited utility for wetlands with erratic hydrologic regimes (e.g., wetlands in urban environments). This is due to violation of the critical assumption that the inflow/outflow rate remains constant throughout the day. For application to surface‐water systems, the method is typically applied with an assumed specific yield of 1.0. This assumption was found to be invalid for application to surface‐water systems with a noncylindrical pond geometry. An overestimation of ET by as much as 60% was found to occur under conditions of low pond stage and high water loss. The results demonstrate the high ET rates that can occur in isolated wetlands due to contrasting roughness and moisture conditions (oasis and clothesline effects). Estimated ET rates ranged from 4.1 to 18.7 mm/day during the growing season. Despite these large ET rates, seepage (recharge) was found to be the dominant water loss mechanism for the wetland.     

Potential use of oil shale for direct production of power in Jordan

Up until the present, Jordan has relied almost exclusively on imported petroleum for its primary energy requirements. Encouraged by emerging technologies and recent fossil fuel discoveries, Jordanians are seriously examining exploitation of their own indigenous energy resources to meet projected mid- and long-term power requirements. The most prominent of the known resources is oil shale. This report addresses the oil shale-for-power-production option in Jordan. Under consideration are 20 MW and 50 MW demonstration units and a 400 MW commercial-scale plant. The report focuses on three areas: (i) the engineering feasibility of using Jordan's oil shale in a circulating fluidized bed combustion (CFBC) boiler; (ii) environmental aspects of the proposed oil shale-for-power plants(s); and (iii) the economic feasibility of the proposed plant(s). The results could be useful for other low- to middle-income countries considering oil shale as an option for power production.     

Indigenous community-based fisheries in Australia

The commercial sea cucumber species known as Sandfish (Holothuria scabra) occurs intertidally and subtidally in the Northern Territory of Australia, on or adjacent to Aboriginal land. A 4-yr program of community-based fisheries research with Aboriginal Australians was implemented to assess the viability of indigenous Australians' involvement in the wild-stock fishery. The research involved extensive and intensive indigenous participation, unusual in Australian biophysical sciences research, during field survey and habitat mapping, complemented by commercial catch data modelling and discussion of its implications. Field surveys produced Sandfish distribution and site-specific density, and revealed some areas that were not commercially fished. Catch data modelling results suggested that no additional effort could be sustained, however commercial fishers increased their effort, expanding their operations into the newly mapped areas. These actions effectively precluded indigenous peoples' aspirations of entry into the commercial fishery. The efficacy and outcomes of participatory program design with indigenous Australians need critique in the absence of the political will and statutory backing to provide equitable access to resources.     

Facilities and Techniques for Maintaining a Controlled Fluoride Environment in Vegetation Studies

The principle of fabric filtration has only recently been accepted for fossil fuel fired boiler particulate emissions control. Information on design criteria is, therefore, limited. The paper provides data on the few installations where baghouses have been installed and successfully operated. The general conclusion is that a strong relationship exists between air to cloth ratio and bag life.     

Dissipation,half-lives,and mass spectrometric identification of endosulfan isomers and the sulfate metabolite on three field-grown vegetables

Endosulfan 3 EC, a mixture of α- and β-stereo isomers, was sprayed on field-grown pepper, melon, and sweet potato plants at the recommended rate of 0.44 kg A.I. acre^?1. Plant tissue samples (leaves, fruits, or edible roots) were collected 1 h to 30 days following spraying and analyzed for endosulfan isomers (α- and β-isomers). Analysis of samples was accomplished using a gas chromatograph (GC) equipped with a mass detector in total ion mode. The results indicated the formation of endosulfan sulfate as the major metabolite of endosulfan sulfite and the relatively higher persistence of the β-isomers as compared to the α-isomer. The initial total residues (α- and β-isomers plus endosulfan sulfate) were higher on leaves than on fruits. On pepper and melon fruits, the α-isomer, which is the more toxic to mammals, dissipated faster (T_1/2 = 1.22 and 0.95 d, respectively) than the less toxic β-isomer (T_1/2 = 3.0 and 2.5 d, respectively). These results confirm the greater loss of the α-isomer compared to the β-isomer, which can ultimately impact endosulfan dissipation in the environment. Additionally, the higher initial residues of endosulfan on pepper and sweet potato leaves should be considered of great importance for timing field operations and the safe entry of harvesters due to the high mammalian toxicity of endosulfan.     

Vegetation: A Sink for Atmospheric Pollutants

The possibility of vegetation being an important sink for gaseous air pollutants was investigated. Plant pollutant uptake measurements were made utilizing a typical vegetation canopy and chambers that were designed specifically for gaseous exchange studies. The data indicate that an alfalfa canopy removed gases from the atmosphere in the following order: hydrogen fluoride (HF) > sulfur dioxide (SO₂) > chlorine (Cl₂) > nitrogen dioxide (NO₂) > ozone (O₃) > peroxyacetyl nitrate (PAN) > nitric oxide (NO) > carbon monoxide (CO). The absorption rate of NO was low, and no absorption of CO could be detected with the methods used. In the typical ambient concentration range uptake increased linearly with increasing concentration except for O₃ and Cl₂ which caused partial stomatal closure at the higher concentrations. Wind velocity above the plants, height of the canopy, and light intensity were shown to affect the pollutant removal rate. A relationship between the absorption rate and solubility of the pollutant in water was also shown. It was concluded that vegetation may be an important sink for many gaseous air pollutants.