The disposal of radioactive ferric floc

An iron hydroxide floc is used as treatment for adsorbing low amounts of actinides during nuclear fuel re-processing. This waste is cemented only after pre-treatment with Ca(OH)(2). Characterisation of all simulant material has been undertaken using XRD, TGA and SEM/EDS. The floc is a moderately alkaline colloidal slurry containing approximately 15wt% solids, with the main particulate being an amorphous hydrated iron oxide. The main phase formed during pre-treatment appears to be an X-ray amorphous hydrated calcium-ferrate phase. Embedded within this are small amounts of crystalline Ca(OH)(2), calcite, Fe(6)(OH)(12)(CO(3)), Ca(6)Fe(2)(SO(4))(3)(OH)(12).26H(2)O and Ca(3)B(2)O(6), and can form depending on concentrations of Ca(OH)(2) and time. Apart from Ca(OH)(2) and calcite, none of the crystalline phases detected during pre-treatment are detected when the floc is encapsulated in an OPC/PFA composite cement hydrated for 90 days. The main crystalline phase detected in the hardened wasteform is a solid solution hydrogarnet, Ca(3)AlFe(SiO(4))(OH)(8), known as C(3)(A,F)SH(4) in cement chemistry nomenclature.     

Analysis of macroinvertebrate assemblages in relation to environmental gradients among lotic habitats of California's Central Valley

We assessed relationships between environmental characteristicsand macroinvertebrate assemblages in lotic habitats of California's Central Valley with community metric and multivariate statistical approaches. Using canonical ordinationanalyses, we contrasted results when assemblage structure was assessed with macroinvertebrate metrics, as suggested for use inindices of biotic integrity, or with genera abundances. Our objectives were to identify metrics or taxa diagnostic of loticenvironmental stressors and compare the capacity of theseapproaches to detect stressors in order to suggest how they mightbe used to diagnose stressors. For macroinvertebrate metrics,redundancy analysis (RDA) extracted three axes correlated withchannel morphology and substrates. For genera abundances, canonical correspondence analysis (CCA) extracted two axescorrelated with soluble salts and with channel morphology andsubstrates but did not separate these gradients onto differentaxes. Cluster analyses identified five RDA and five CCA sitegroups, which exhibited differences for environmental variables,metrics, or genera abundances, and agreement between the analysesin partitioning of sites was greater than if sites were partitioned randomly. These approaches differ in their abilityto detect environmental stressors, because they measure differentaspects of assemblages and would be complementary in design ofnew metrics diagnostic of stressors.     

Injury Severity Score alone predicts mortality when compared to EMS scene time and transport time for motor vehicle trauma patients who arrive alive to hospital

ABSTRACT

Objective: This study aims to identify the association, if any, between prehospital scene time, prehospital transport time, and Injury Severity Score (ISS) with in-hospital mortality.

Methods: A retrospective analysis was performed on patients at least 18 years of age who arrived to the hospital alive via emergency medical services (EMS) after a motor vehicle collision (MVC) between 1992 and 2016. These patients were divided into groups based on minutes spent at the scene and in transport. The ISS of the in-hospital mortalities, as well as the entire patient sample for each time frame, was collected. Patients without documented scene time, transport time, or ISS were excluded.

Results: Four thousand one hundred ninety-four patients were captured when analyzing scene time, though only 3,980 met inclusion criteria. In addition, 4,177 patients were captured when analyzing transport time, though only 3,979 met inclusion criteria. Scene time and transport time were not statistically significant predictors of in-hospital mortality (P = .31 and P = .458, respectively). ISS was found to be a statistically significant predictor of in-hospital mortality (P < .001).

Conclusions: ISS predicts mortality independent of scene time or transport time for patients who arrive to the hospital alive following an MVC at Guthrie Robert Packer Hospital. Limitations of our study include inability to capture prehospital deaths and inability to correlate ISS with prehospital injury severity scores.     

What are the implications of sea-level rise for a 1.5, 2 and 3 °C rise in global mean temperatures in the Ganges-Brahmaputra-Meghna and other vulnerable deltas?

Even if climate change mitigation is successful, sea levels will keep rising. With subsidence, relative sea-level rise represents a long-term threat to low-lying deltas. A large part of coastal Bangladesh was analysed using the Delta Dynamic Integrated Emulator Model to determine changes in flood depth, area and population affected given sea-level rise equivalent to global mean temperature rises of 1.5, 2.0 and 3.0 °C with respect to pre-industrial for three ensemble members of a modified A1B scenario. Annual climate variability today (with approximately 1.0 °C of warming) is potentially more important, in terms of coastal impacts, than an additional 0.5 °C warming. In coastal Bangladesh, the average depth of flooding in protected areas is projected to double to between 0.07 and 0.09 m when temperatures are projected at 3.0 °C compared with 1.5 °C. In unprotected areas, the depth of flooding is projected to increase by approximately 50% to 0.21–0.27 m, whilst the average area inundated increases 2.5 times (from 5 to 13% of the region) in the same temperature frame. The greatest area of land flooded is projected in the central and north-east regions. In contrast, lower flood depths, less land area flooded and fewer people are projected in the poldered west of the region. Over multi-centennial timescales, climate change mitigation and controlled sedimentation to maintain relative delta height are key to a delta’s survival. With slow rates of sea-level rise, adaptation remains possible, but further support is required. Monitoring of sea-level rise and subsidence in deltas is recommended, together with improved datasets of elevation.

     

Climate Change and Energy Technologies in Undergraduate Introductory Science Textbooks

Global climate change and the implementation of energy technologies are among the most pressing issues facing society and the environment today. Related educational content spans the science disciplines. Through an analysis of introductory-level university textbooks from four major US publishers in Biology, Chemistry, and Physics, this study presents trends in terminology and content. As the defining terms, “global warming” and “climate change” are used nearly equally. However, the first location of a working definition for climate change appears earlier. Energy technologies, climate change, and related environmental issues are found, on average, on ≤4% of textbook pages, and variation is large among individual textbooks. Discipline-based trends exist, especially for the energy technologies presented. Addressed separately as a non-renewable, non-fossil fuel, nuclear energy is found on ≤1% of textbook pages and unfavorably represented. The discussion within these science disciplines has implications on introductory-level education, public perception of science, and informed citizenship.     

Development and Integration of Quantitative Real-Time PCR Methods for Detection of Mitochondrial DNA and Methanobrevibacter smithii nifH Gene as Novel Microbial Source Tracking Tools

A novel microbial source tracking (MST) method based on the detection of human and non-human markers was developed and applied to track the origin of fecal pollution in water systems. Mitochondrial DNA sequences were used to develop new quantitative real-time polymerase chain reaction (qPCR) assays for dog, poultry, and gull. The targets were included as part of a toolbox including human, cow, pig, and sheep assays. A primer and probe set for the detection of the human-specific nifH gene of Methanobrevibacter smithii was also designed as an indicator of human fecal contamination. The assays were tested for specificity and applied to fecal-spiked surface waters and environmental samples collected from two river catchments impacted by sources of human and non-human fecal contamination. The MST methods described were applicable to both spiked waters and environmental samples, and using the two approaches the origin of fecal pollution could be successfully determined in mixed source fecally polluted waters.     

A small subsurface ion mobility spectrometer sensor for detecting environmental soil-gas contaminants

A small subsurface ion mobility spectrometer (SS-IMS) was constructed and tested with several environmental contaminants to determine its potential for monitoring gaseous volatile organic compounds in the vadose zone. Trichloroethylene (TCE) and tetrachloroethylene (PCE) were detected and separated in IMS for the first time. Detection limits as low as 1 part per billion volume-to-volume (ppb(v)) were observed. Reduced mobility (K(0)) values were reported for 11 environmental contaminants. These data demonstrated the potential of ion mobility spectrometry as a viable technology for detecting and separating environmental soil-gas contaminants in the field, which may lead to a practical and simple approach for long-term monitoring of contaminated soils.     

The sensitive and selective determination of aluminium by spectrofluorimetric detection after complexation with N-o-vanillidine-2-amino-p-cresol

A simple, easy to use and selective spectrofluorimetric method for the determination of trace levels of aluminium has been developed. A new Schiff base, N-o-vanillidine-2-amino-p-cresol (OVAC), has been synthesized and its fluorescence activity with aluminium investigated. Based on this chelation reaction, a spectrofluorimetric method has been developed for the determination of aluminium in samples buffered at pH 4.0 using acetic acid-sodium acetate. The chelation reaction between Al(iii) and N-o-vanillidine-2-amino-p-cresol was very fast, requiring only 20 min at room temperature to complex completely. The excitation and emission wavelengths were 423.0 and 553.0 nm, respectively, at which the OVAC-Al complex gave the maximum fluorescence intensity at pH 4.0 in a 50% ethanol-50% water medium. The interference from fluoride ions was minimized by the addition of Be(2+). Other ions were found not to interfere at the concentrations likely to be found in natural waters. Under these conditions, the calibration plot was linear up to 1000 microg L(-1) (r = 0.999). The limit of detection (3sigma) for the determination of Al(iii) was 0.19 microg L(-1) and the precision for multiple determinations of 3 ng mL(-1) Al(iii) prepared in ultra-pure water was found to be 0.29% (n = 16). The Schiff base ligand could be used to determine ultra-trace aluminium from natural waters. Analysis of environmental certified reference materials showed good agreement with the certified values. The procedure was found to be equally applicable to both fresh water and saline solutions (including sea water) using either normal external calibration or the standard additions method.     

Determination of fecal contamination indicator sterols in an Australian water supply system

This paper reports a reconnaissance survey of the concentrations of sterol compounds (as indicators of fecal contamination) in a large water supply system in southeast Australia comprising a network of rivers, channels, and drains. Levels of coprostanol and cholestanol were determined in surface water and bottom sediment using gas chromatography–mass spectrometry analysis across 17 strategic sampling sites and over 12 months. Clear differences in the levels of fecal contamination were observed among sites. Four sites routinely contained high levels of the fecal indicator sterols indicated from surface water and sediment sample analysis. Coprostanol concentrations at each location varied from 0 ng/L at the reference site to 11,327 ng/L in a surface water sample of a drain directly downstream of a knackery. The majority of the sites contained coprostanol in the range of 500 to 800 ng/L. Since no fecal-associated sterol compounds were detected at the external reference sites, these were assumed to be free from fecal contamination. Sewage water discharge and/or substantial water runoff maybe the principal factors contributing to fecal contamination of the supply drains and channels.     

Facilities and Techniques for Maintaining a Controlled Fluoride Environment in Vegetation Studies

The principle of fabric filtration has only recently been accepted for fossil fuel fired boiler particulate emissions control. Information on design criteria is, therefore, limited. The paper provides data on the few installations where baghouses have been installed and successfully operated. The general conclusion is that a strong relationship exists between air to cloth ratio and bag life.