长江经济带重化工风险问题识别与防控建议

从流域-行业-区域/城市多级角度,系统梳理了长江经济带布局性风险、局部突发事故型风险、污染排放累积风险、有毒有害污染物潜在慢性风险等长江经济带重化工风险问题.基于长江经济带典型区域重化工现状分析及风险分析,针对流域总体及各行业/区域特征,统筹制定重化工布局与风险防控方案,实现分类分区施策.提出了园区分级动态管理、现有与...     

因子分析法在水质评价中的应用

因子分析法是主成分分析方法的推广和深化,用于研究样本中变量之间的相关关系,把原来的多个变量化为少数几个综合指标的一种多元分析方法。用该法对嘉陵江顺庆段水质进行评价,结果表明该水体受到了不同程度的有机物污染,其中NO-3-N、SS、BOD5和非离子氨所占的负荷最大,这为环境治理提供了科学的依据。     

配水管网中与有机物反应的余氯衰减动力学模型

提出一级二级反应组合动力学模型,用大量实验数据拟合模型中的参数,模拟配水管网系统中余氯衰减的水体消耗部分.该模型定量反应了温度T、初始氯浓度c₀和TOC与余氯衰减之间的复杂关系.除初始阶段外,组合模型可简化为一级反应模型;T、TOC和c₀与余氯衰减之间的关系分别可简化为指数关系、正线性关系和负线性关系.该模型较好地解释了余氯衰减在初始阶段进行相对较快这一现象.实验数据验证的结果表明:该组合模型与实验数据吻合良好,优于传统的一级反应模型.     

Cadmium accumulation in <Emphasis Type="Italic">Panax notoginseng</Emphasis>: levels,affecting factors and the non-carcinogenic health risk

Cadmium (Cd) contamination has been reported to be a problem for the safe usage of Panax notoginseng (Sanchi); thus, it is necessary to elucidate the Cd accumulation in Sanchi and to assess its associated health risk. Samples were collected from major producing areas in Yunnan, China. The average concentration of Cd in Sanchi was 0.43 mg/kg, which exceeds the standard level for herbal medicine in China (0.3 mg/kg). A stepwise regression analysis showed that zinc and the pH were the related factors that most significantly impacted Cd in Sanchi roots. The hazard quotient values were estimated as 0.0010 (men) and 0.0012 (women) for consumers taking preparations and were 0.011 (men) and 0.013 (women) for consumers taking health products, implying that there is no non-carcinogenic hazard associated with Sanchi consumption. However, a Monte Carlo simulation showed that approximately 0.80 % of male and 1.02 % of female consumers via drug consumption and 36.28 % of male and 41.87 % of female consumers via health product consumption had an exposure exceeding the acceptable daily intake (ADI) of Cd from drugs (1 % of the total oral ADI as suggested by the World Health Organization). These people should control their oral Cd intake from both Sanchi consumption and diet as a whole.     

污染浓度对多级人工湿地-塘系统处理微污染河水中COD的影响

针对微污染水水质不稳定,COD_Mn波动较大的问题,本研究构建了3套中试规模的以"前置生态氧化塘、两级水平潜流湿地和表流湿地为核心、后置沉水植物塘"为工艺的多级人工湿地-塘组合系统（处理水量230 L·d^-1,分别命名为S1、S2和S3）.在3种进水浓度条件下（原水、稀释2倍和稀释1.3倍后的水体,分别作为S1、S2和S3系统的进水）,考察了3套湿地-塘系统各单元对实际微污染河水中COD_Mn的处理效果,并采用高通量测序等方法解析了S1系统湿地单元微生物群落分布特征.研究结果表明,3套系统的平均出水COD较进水有着非显著的升高,从升高的程度来看,S2>S3>S1.污染浓度相对最高、运行时间最长的S1系统对COD有着更好的净化效果.相较于S2系统,S3系统更高的进水浓度有利于COD去除.S1和S2系统的二级水平潜流湿地较其他单元有着较好的COD去除作用,平均去除率分别为18.60%和26.52%.S3系统的表流湿地较其他单元有着较好的COD去除作用,平均去除率为8.92%.微生物群落分析结果表明,S1系统的一级、二级水平潜流湿地中细菌丰度和多样性沿程提高,两个单元所富集的相同优势菌群包括α-变形菌纲、γ-变形菌纲和拟杆菌纲,与COD降解有关的菌属分别包括unclassified_f__Burkholderiaceae、unclassified_c__Alphaproteobacteria、norank_f__Blastocatellaceae和norank_f__Saprospiraceae、红细菌属.表流湿地中细菌丰富度进一步升高,但生物多样性有所减少,其中蓝菌属和norank_c__Actinobacteria可能与表流湿地出水COD升高有关.本研究为大型河口湿地-塘复合生态系统处理微污染地表水时工作重心由浓度削减向污染物释放控制的转移提供了宝贵的工程经验.     

褐色土地利益相关者的环境冲突及其解决途径初探

随着中国城市化进程的不断加快,城市土地资源日益稀缺,褐色土地的再开发戊为城市土地资源可持续利用的重要手段。在褐色土地开发过程中难免会涉及政府、企业、居民、工业企业、开发商、金融机构、媒体等多方利益相关主体,并引发错综复杂的利益纠纷与冲突。在倡导构建和谐社会的今天,对褐色土地利益相关者间的相互关系、环境冲突及其解决办法的研究也就具有重要的现实意义。     

关于环保信息系统分级建设

本文归纳了多年来环保信息系统建设的四种模式,并对它们的特点、适用条件及优劣比对作了论述。     

沘江兰坪段生态健康评价指标体系研究

河流是人类文明的发源地。它为人类提供了多样的生态服务,但随着工业文明的发展,大量废水和污染物的排入,河流生态健康受到了严重影响。本文以沘江兰坪段为例,根据整体性原则、层次性原则、可操作性原则和定性与定量结合的原则,参考国内外河流生态健康评价的指标体系,结合沘江具体情况对河流生态健康的评价指标体系进行了探讨。     

基于突变级数法的滑坡稳定性评价

基于突变级数法,建立了滑坡稳定性评价和预测模型。在相关研究的基础上,建立了滑坡稳定性评价指标的递阶层次结构,以滑带强度、滑面特征、滑坡外形特征及其近期活动等4个内部影响因素,以及暴雨作用、河流作用、滑坡后缘加载、人工活动和地震作用等5个外部影响因素,作为滑坡稳定性识别的判别因子;以22组典型滑坡工程案例作为训练样本,建立了滑坡稳定性评价模型和突变级数判据;然后利用6组典型滑坡工程实际案例作为测试样本,检验了模型的可行性和可靠性。研究表明,突变级数法对滑坡稳定性的识别结果与实际情况吻合,并与系统加权聚类分析法、判别分析法等的识别结果一致。     

A 1-dodecanethiol-based phase transfer protocol for the highly efficient extraction of noble metal ions from aqueous phase

A 1-dodecanethiol-based phase-transfer protocol is developed for the extraction of noble metal ions from aqueous solution to a hydrocarbon phase, which calls for first mixing the aqueous metal ion solution with an ethanolic solution of 1-dodecanethiol, and then extracting the coordination compounds formed between noble metal ions and1-dodecanethiol into a non-polar organic solvent. A number of characterization techniques,including inductively coupled plasma atomic emission spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis demonstrate that this protocol could be applied to extract a wide variety of noble metal ions from water to dichloromethane with an efficiency of 96%, and has high selectivity for the separation of the noble metal ions from other transition metals. It is therefore an attractive alternative for the extraction of noble metals from water, soil, or waste printed circuit boards.