Effect on herbicide adsorption of organic forestry waste products used for soil remediation

Organic soil amendments can be useful for improving degraded soil, but this increase in organic matter (OM) may influence adsorption of herbicides subsequently applied to the treated soil, even though the particle size of amendments and their nature differ from typical soil OM. In this study, a batch equilibrium method was used to measure adsorption of five herbicides following application to two organic media, wood pulp and sawdust, comparing these with two cropping soils. Herbicide adsorption, quantified by distribution coefficients (k_d), was much higher in the two organic media than in the cropping soils. The increases in adsorption were strongly correlated to the percentage of organic carbon. When the k_d was normalized to adsorption coefficients corrected for OM content (k_oc), variation in results between the media was greatly reduced, indicating that OM is an important factor influencing adsorption in these media. The results of this study suggest that herbicides will be less effective when applied to soils in which sawdust and wood pulp have been added. Using organic amendments to remediate soil will increase adsorption of pesticides, reducing their bio-availability and efficacy, but also reducing their tendency to leach into root zones of deep-rooted crops and into groundwater.     

Fingerprinting and Groundwater Model Application to Evaluate Hydraulic Barrier Efficiency (Italy)

Remediation actions at contaminated sites are based on multiple numerical model scenarios considering different parameter distributions, source positions and contaminant transport paths. In some cases the excess of scenarios is due to uncertainties in the conceptual model as a result of the spread of contamination through heterogeneities in the physical system. Reduction of project hypotheses and conceptual model uncertainty is therefore needed. This result can be achieved by coupling hydrogeological investigations with environmental forensic techniques, better localization of the source and understanding of contamination history. In this respect, in the present study, compositional fingerprinting and groundwater flow modeling were applied to a former oil storage facility where, even though a hydraulic barrier had been built to stop the hydrocarbon plume, the presence of some hydrocarbons was still found in downgradient monitoring wells. The final aim was to evaluate the efficacy of the hydraulic barrier and identify of the source of pollution. Fingerprinting results indicated pollution with a gasoline-diesel mixture much altered by water washing and/or biodegradation. Comparison of seven groundwater samples collected in wells and monitoring wells was performed by analyzing the volatile fraction (BTEX) and the total ion chromatogram (TIC), focusing attention on: n-alkanes (m/z 85), alkylcyclohexanes (m/z 83), isoprenoids (m/z 113), C4-alkylbenzenes (m/z 134), C3-C6 alkylbenzenes and polycyclic aromatic hydrocarbons (PAHs). The most probable scenario was then identified by combining the results of fingerprinting with different contaminant paths obtained using the numerical model.     

Comparison of understorey bird species in relation to edge–interior gradient in an isolated tropical rainforest of Malaysia

Forest fragmentation results in a loss of forest interior and an increase in edge habitat. As a result, these changes may affect the bird species distribution and composition. We studied how understorey bird community composition and habitat variables changed along an edge-to-interior gradient in a fragmented lowland rainforest in Peninsular Malaysia. Birds and environmental variables were recorded at each of the 93 sampling points distributed along the 14 parallel transects that were systematically placed across the gradient of distance from the forest edge to the forest interior. Species composition was different along the edge–interior gradient, although only a few species were strictly confined to either edge or interior habitat. Based on bird–habitat associations along the edge–interior gradient, some of these edge-preferred species occurred in high numbers at the matrix surrounding the patch. In contrast, the interior-specialist group, mainly terrestrial insectivores, avoided the forest edge and was positively associated with humidity, canopy cover, the number of dead trees, percentage of litter cover, and depth of the litter layer. Species endemic to the Sunda subregion were more abundant in the interior of the forest. From a conservation perspective, forest remnants in the lowlands of Peninsular Malaysia that have a deep leaf litter layer, dense canopy cover, high number of dead trees, and high relative humidity are able to support understorey bird species that are sensitive to edge effects. The forest has important conservation value even though it is fragmented and isolated.     

Effect of different biochars amendment on soil biological indicators in a calcareous soil

Environmental Science and Pollution Research - Previous studies suggest that biochar has potential to benefit soil when used as an amendment, but only few studies have investigated how the...     

Should we Leave Nature Unattended or Assist through Enrichment to Foster Climate Change Mitigation? Exclosure Management in the Highlands of Ethiopia

Environmental Management - In order to foster the potential of exclosures to sequester carbon, it is understood that they are increasingly assisted through enrichment planting. To study the impact...     

The conceptual framework to determine interrelations and interactions for holistic Water,Energy, and Food Nexus

Environment, Development and Sustainability - Several models with a variety of concepts and approaches have been proposed to address different aspects of the Water-Energy-Food (WEF) nexus system....     

Sonocatalytic degradation of tetracycline antibiotic in aqueous solution by sonocatalysis

Tetracycline (TC), one of the most common antibiotics, is often poorly bio-degraded in conventional wastewater treatment plants. In this study, the sonocatalytic degradation of TC was investigated using TiO₂ nano-particles as catalyst. The effect of pH, initial TC concentrations, reaction times, and H₂O₂ concentrations were evaluated. The efficacy of ultrasonic irradiation alone in the removal of this pollutant was negligible but removal efficiency increased upon addition of TiO₂ up to 250 mg L^?1; increase of pH and initial TC concentration attenuated TC degradation. Addition of H₂O₂ raised the removal efficiency so that complete removal of TC was achieved within 75 min.     

Geochemical fractions and phytoavailability of Zinc in a contaminated calcareous soil affected by biotic and abiotic amendments

Many studies have conducted to determine the best management practice to reduce the mobility and phytoavailability of the trace metals in contaminated soils. In this study, geochemical speciation and phytoavailability of Zn for sunflower were studied after application of nanoparticles (SiO₂ and zeolite, with an application rate of 200 mg kg^?1) and bacteria [Bacillus safensis FO-036b(T) and Pseudomonas fluorescens p.f.169] to a calcareous heavily contaminated soil. Results showed that the biotic and abiotic treatments significantly reduced the Zn concentration in the aboveground to non-toxicity levels compared to the control treatment, and the nanoparticle treatments were more effective than the bacteria and control treatments. The concentration of CaCl₂-extractable Zn in the treated soils was significantly lower than those of the control treatment. The results of sequential extraction showed that the maximum portion of total Zn belonged to the fraction associated with iron and manganese oxides. On the contrary, the minimum percent belonged to the exchangeable and water-soluble Zn (F₁). From the environmental point of view, the fraction associated with iron and manganese oxides is less bioavailable than the F₁ and carbonated fractions. On the basis of plant growth promotion, simultaneous application of the biotic and abiotic treatments significantly increased the aboveground dry biomass yield and also significantly reduced the CaCl₂-extractable form, uptake by aboveground and translocation factor of Zn compared to the control treatment. Therefore, it might be suggested as an efficient strategy to promote the plant growth and reduce the mobile and available forms of toxic metals in calcareous heavily contaminated soils.     

COST EFFECTIVE OPERATION OF URBAN WATER SUPPLY SYSTEM USING DYNAMIC PROGRAMMING1

ABSTRACT: Efficient operation of a city water supply system is an important goal of all municipalities. Efficient operation should result in minimum operation cost through reduction in total energy use and/ or reduction in on-peak energy consumption. An optimization model was designed for operating the water supply systems of cities using groundwater. The Newton-Raphson pipe network was used for network analysis and a dynamic programming optimization algorithm was used for determining a schedule for pump operation in the pipe network system. The model is most suitable for use in small cities with up to 45,000 in population, but with large-scale disintegration techniques may also be used for larger cities. The savings in operation costs are a function of energy cost and energy use pattern and water use pattern in the area.     

Molecular and serological study on congenital toxoplasmosis in newborn of Shiraz,Southern Iran

Environmental Science and Pollution Research - Toxoplasmosis is a zoonotic disease caused by an obligatory intracellular parasite, Toxoplasma gondii. The congenital form of the disease is a...