太原市土壤六六六和滴滴涕的暴露格局及健康风险

为研究六六六(HCHs)和滴滴涕(DDTs)在太原市不同功能区土壤中的暴露格局、来源以及对周围人群的健康风险,在太原市化工区、灌区、矿区、生态区周边荒地土壤中进行采样,分析测定了土壤中HCHs和DDTs含量,根据太原市人群实际情况的暴露参数和USEPA的部分参数,对土壤HCHs和DDTs的健康风险进行评价。结果表明:1)太原市表层土壤中HCHs的平均含量大小依次为化工区>灌区>矿区>生态区;DDTs平均含量的大小依次为化工区>灌区>矿区>生态区,仅6%的HCHs和3%的DDTs和的平均残留水平均高于我国土壤质量标准一级标准,但均不超过二级标准值;2)土壤中HCHs残留主要源于历史上林丹的使用,DDTs残留则来源于历史和新污染源的共同影响;3)太原市表层土壤HCHs和DDTs致癌风险大小为化工园区>矿区>灌区>生态区。非致癌风险大小为化工区>矿区>灌区>生态区。3种暴露途径的在不同功能区的健康风险贡献率大小均为经口摄入>呼吸吸入>皮肤接触;综合来看太原市表层土壤中的HCHs和DDTs并未对人类造成非致癌风险,但有一定的致癌风险。本文的研究结果可为太原市土壤质量评价和环境污染防治提供科学指导,并对太原市人群的健康风险防治提供依据。     

垃圾渗滤液中典型内分泌干扰物质(EDCs)细胞毒性分析

垃圾渗滤液的人类健康风险评估日益受到人们重视,也成为研究热点。本文采用一种新型高级氧化技术UV-Fenton处理渗滤液,并用人体乳腺癌细胞(MCF-7)评估处理过程中渗滤液原液以及渗滤液中典型内分泌干扰物质(EDCs)的细胞毒性,对垃圾渗滤液中EDCs的细胞毒性和变化规律进行了研究。结果表明渗滤液中的邻苯二甲酸二丁酯(DBP)、双酚A(BPA)、壬基酚(NP)是产生细胞毒性的主要物质,其毒性大小为DBPBPANP。在同样的氧化降解过程中显示出不同毒性变化规律,通过GC-MS分析,结果显示UV-Fenton过程中产生了大量的中间产物,这也是引起毒性变化的主要原因。实验结果也说明垃圾渗滤液细胞毒性可以通过UV-Fenton过程有效去除。     

De novo formation of dioxins from milled model fly ash

Environmental Science and Pollution Research - Municipal solid waste incineration (MSWI) fly ash has been classified as hazardous waste and needs treatment in an environmentally safe manner....     

Distribution and controls of heavy metals and organic matter in the surface sediments of the Southern Yellow Sea,China

Environmental Science and Pollution Research - Accurate and effective determination of the source of heavy metals is essential for the treatment of marine ecological environments. This article...     

Validation of temporal and spatial consistency of facility- and speed-specific vehicle-specific power distributions for emission estimation: A case study in Beijing,China

Vehicle-specific power (VSP) has been found to be highly correlated with vehicle emissions. It is used in many studies on emission modeling such as the MOVES (Motor Vehicle Emissions Simulator) model. The existing studies develop specific VSP distributions (or OpMode distribution in MOVES) for different road types and various average speeds to represent the vehicle operating modes on road. However, it is still not clear if the facility- and speed-specific VSP distributions are consistent temporally and spatially. For instance, is it necessary to update periodically the database of the VSP distributions in the emission model? Are the VSP distributions developed in the city central business district (CBD) area applicable to its suburb area? In this context, this study examined the temporal and spatial consistency of the facility- and speed-specific VSP distributions in Beijing. The VSP distributions in different years and in different areas are developed, based on real-world vehicle activity data. The root mean square error (RMSE) is employed to quantify the difference between the VSP distributions. The maximum differences of the VSP distributions between different years and between different areas are approximately 20% of that between different road types. The analysis of the carbon dioxide (CO₂) emission factor indicates that the temporal and spatial differences of the VSP distributions have no significant impact on vehicle emission estimation, with relative error of less than 3%.

Implications: The temporal and spatial differences have no significant impact on the development of the facility- and speed-specific VSP distributions for the vehicle emission estimation. The database of the specific VSP distributions in the VSP-based emission models can maintain in terms of time. Thus, it is unnecessary to update the database regularly, and it is reliable to use the history vehicle activity data to forecast the emissions in the future. In one city, the areas with less data can still develop accurate VSP distributions based on better data from other areas.     

Remediation of DDTs contaminated soil in a novel Fenton-like system with zero-valent iron

Application of a novel Fenton-like system with zero-valent iron, EDTA and Air (ZVI/EDTA/Air) was investigated to degrade dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethane, and dichlorodiphenyldichloroethylene (DDE) in the actual contaminated soil from an organochlorine pesticide site. It was found DDTs in the soil were effectively degraded by the system at room temperature, ambient atmosphere pressure and near neutral pH. The dosages of EDTA and ZVI were the dominant factors influencing the removal of contaminants. An increase of EDTA from 0.05 to 0.2 mM and ZVI from 1 to 5 g L^?1 improved the removal of the contaminants significantly. However, excessive amount of EDTA led to a negative effect on the degradation process. Meanwhile, EDTA was simultaneously degraded so as to avoid the secondary pollution risk on soil remediation. Only a small amount of 4,4′-DDE and 2,2-bis(4-chlorophenyl)-1-chloroethylene (4,4′-DDMU) generated as the intermediates of DDT degradation during the process. Our investigation suggests that the Fenton-like system is a promising alternative for remediation of organochlorine pesticides contaminated soils.     

Fingerprinting of High Boiling Hydrocarbon Fuels,Asphalts and Lubricants

Fingerprinting of hydrocarbon products requires high resolution differentiation of individual hydrocarbon compounds in any mixture. This requires the applications of various measuring techniques. In this paper, we have chosen the heavy hydrocarbons in fuels, lubricants and paving material as examples to discuss the methods for chemical characterization and differentiation. In the category most frequently termed "semi-volatile hydrocarbons" with boiling points from about 500°F to 1200°F or higher, there are several families of hydrocarbons, both natural and refined that are not easily distinguished by conventional EPA tests. Among the groups which we will use as examples are asphalts, hydraulic fluid, transmission oil, motor lubricating oils, heating oils, crude oil and coal. These hydrocarbon families are best studied using combined gas chromatography-mass spectrometry in full scan mode and characterizing various homologous series of hydrocarbons at known fragment ions. The hydrocarbon series providing the best information are: (1) N -alkanes; (2) iso-alkanes; (3) steranes; (4) terpanes; (5) polynuclear aromatic hydrocarbons; (6) aromatic steranes; and (7) specific polycyclic compounds.     

湿法净化黑烟中添加剂对炭黑沉降性能的影响

湿法净化黑烟中炭黑颗粒物的关键在于降低吸收液的表面张力并以高性能絮凝剂使其从溶液中絮凝、沉降以利于分离。选用十六烷基三甲基溴化胺(CTAB)为主要表面活性剂,使之与十二烷基苯磺酸钠(SDBS)和月桂醇聚氧乙烯(9)醚(AEO-9)进行复配实验,研究了复配液的表面张力,再向最低表面张力的复配表面活性剂溶液中投加絮凝剂聚合氯化铝(PAC)和聚丙烯酰胺(PAM),探讨絮凝剂的添加对黑烟颗粒沉降和絮凝的影响.实验结果表明:同时添加表面活性剂CTAB,SDBS和PAC,并使之浓度分别为0.5 mmol/L,0.4 mmol/L和200 mg/L时,炭黑颗粒的沉降效果最好,沉降率高达94%,且絮凝体较大,沉降时间仅为2 min。     

一种新型活性半焦吸附剂的制备及其表面特征分析

对一种原料半焦进行粉碎、筛分,取其中10～20目的颗粒;用去离子水冲洗后高温下烘干至恒重;依次进行HNO3活化、KOH活化和加压水热化学活化,制备出活性半焦吸附剂。经实验证明,该活性半焦吸附剂对甲苯的吸附等温线符合Langmuir模型,其甲苯吸附容量可达207 mg/g,穿透时间由80 min延长至235 min。该活性半焦吸附剂的比表面积为555.56 m2/g,碘值为811.38 mg/g,表面酸碱总量为0.8649 mmol/g,并通过SEM扫描进行了表面微观形态分析。数据表明,经改性后制备出的新型活性半焦对甲苯的去除率明显增加,其表面物化性质也有明显改变,是一种优良的有机废气吸附剂。     

羧酸盐型双子表面活性剂的合成及性能研究

以月桂酰氯、乙二胺与丁二酸酐为原料合成了一种羧酸盐型双子(gemini)表面活性剂。采用IR、1 HNMR对中间产物和目标产物进行结构表征,并考察了合成所得羧酸盐型gemini表面活性剂的表面活性。结果表明:合成产物即为目标产物。合成产物的临界胶束浓度为0.027mmol/L,比普通单链表面活性剂低2～3个数量级,表面张力最低可降至29.5mN/m。