Ultraviolet irradiation of municipal wastewater: Evaluation of effects on organic constituents

A comparison of chromatograms derived from the UV-absorbing and oxidizable constituents present in primary and secondary municipal wastewater effluents indicates that exposure to UV irradiation at disinfection levels results in only slight chemical changes. The most pronounced chemical effects to nonvolatile organic constituents in wastewater effluents have been observed at irradiation levels in excess of those necessary for disinfection. Aliquots of effluents before and after exposure to varying levels of UV irradiation were concentrated by lyophilization prior to liquid chromatographic (LC) analysis. Anion-exchange chromatographic techniques utilizing a modified ultraviolet detector coupled in series with a cerate oxidative monitor provided excellent resolution and sensitivity in the determination of chemical changes occurring in the effluents as a result of exposure to different irradiation levels. The total coliform counts for each irradiated effluent were determined by the membrane-filter technique to evaluate the effectiveness of UV irradiation as a disinfection process for municipal wastewaters. Changes in biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic carbon (TOC), and total Kjeldahl nitrogen (TKN) at different levels of exposure to UV irradiation are presented. The results of these determinations and the gas chromatography/mass spectrometry data characterizing the observed chemical changes are discussed.     

CONTEMPORANEOUS AUTOREGRESSIVE-MOVING AVERAGE (CARMA) MODELING IN WATER RESOURCES1

ABSTRACT: The Contemporaneous Autoregressive-Moving Average (CARMA) model is a simple and efficient model that can be used to fit many multivariate hydrological time series. For certain types of multistation river flow systems, the CARMA model is naturally obtained when the physical restrictions of the system or the characteristics of the data are taken in consideration during the formulation of the model. It is shown how the CARMA model can optimally be used to handle multiple time series where the number of observations in each series may be different. Adequate model building techniques, as well as computational and statistical efficient algorithms to estimate the parameters of the model, are given. The methodologies and applications of the CARMA model are illustrated with three examples. It is also shown how the full multivariate ARMA model may lead to losses in efficient of the estimators when the CARMA model is adequate.     

The environmental regulator and industrial development

Environmental regulatory agencies' administrative procedures have a significant impact on plant location. The authors review the basic reasons why companies build new plants and the constraints they operate under during site searches. The relationship between these issues and the regulatory agencies' administrative procedures is then shown, as well as the manner in which these procedures influence the site search. On the basis of this discussion, recommendations are made about how state environmental protection agencies can assist site seekers in a manner consistent with their regulatory responsibilities.     

Reduction of Urban Runoff Through Economic Incentives: Boulder,Colorado1

ABSTRACT: The problems of increased surface runoff which follow in step with urbanization can be conceptualized in terms of environmental economics. The private transformation of land from a permeable to an impermeable surface imposes the externality of increased surface runoff upon society as a whole and especially on those downstream. The city of Boulder, Colorado, has enacted an ordinance which attempts to internalize some of these external costs and at the same time decrease surface runoff from the urban environment.     

Improving Benefit Transfer Demand Functions: A GIS Approach

Methodologies for transfer of non-market, natural resource recreation benefits are an active research topic. This arises because of the appeal of modelling the impacts of possible changes in site quality or benefits at unsurveyed sites. However, successful benefit transfer must necessarily rely on development of reliable visitor demand functions that incorporate travel time, demographic and substitute factors. Previous efforts to include all of these elements in a single arrivals model are rare. By integrating data from numerous sources within a geographical information system (GIS) we have developed a model to predict the number of visitors to a recreational woodland in eastern England. Variables were classified into discrete groups that were combined into comparatively homogeneous zones from which to calculate visit rates. Poisson regression techniques were then applied in a stepwise procedure to assess the influence of each determinant. Our analysis highlighted both substantial promise and some caveats in using GIS for future benefit transfer work.     

Vinyl Chloride Marine Risk Assessment with Special Reference to the Osparcom Region: North Sea

This risk assessment on vinyl chloride was carried out specifically for the marine environment, according to the methodology laid down in the European Union (EU) risk assessment Regulation (1488/94) and the Technical Guidance Documents for New and Existing Substances (TGD, 1996). Vinyl chloride is used for the production of polyvinyl chloride (PVC). The study consisted of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programmes in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the Predicted Exposure Concentration (PEC) and the Predicted No-Effect Concentration (PNEC) for the marine aquatic environment. In total 6 studies for fish, 3 studies for invertebrates and one for algae have been evaluated. The appropriate assessment factors have been used to calculate a PNEC of 210 microg/l based on short-term exposure. For coastal waters and estuaries a worst case PEC of 0.15 microg/l is derived. For river waters a typical and worst case PEC of <0.008 and 0.4 microg/l is derived, respectively. These concentrations, which do not take into account any dilution within the sea, correspond to safety margins from 500 to 250,000 between the aquatic effect and the exposure concentration. Vinyl chloride is not a 'toxic, persistent and liable to bioaccumulate' substance sensu the Oslo and Paris Conventions for the Prevention of Marine Pollution (OSPAR-DYNAMEC). It can be concluded that the present use of vinyl chloride does not present a risk to the marine aquatic environment.