Modeling the Highly Dynamic Loading of Mercury Species in the Carson River and Lahontan Reservoir System,Nevada

The semiarid Carson River — Lahontan Reservoir system in Nevada, United States is highly contaminated with mercury (Hg) from historic mining with contamination dispersed throughout channel and floodplain deposits. Work builds on previous research using a fully dynamic numerical model to outline a complete conceptualization of the system that includes transport and fate of both sorbed and dissolved constituents. Flow regimes are defined to capture significant mechanisms of Hg loading that include diffusion, channel pore water advective flux, bank erosion, and overbank deposition. Advective flux of pore water is required to reduce dilution and likely represents colloidal‐mediated transport. Fluvial concentrations span several orders of magnitude with spatial and temporal trends simulated within 10‐24% error for all modeled species. Over the simulation period, 1991‐2008, simulated loads are 582 kg/yr (THg²⁺), 4.72 kg/yr (DHg²⁺), 0.54 kg/yr (TMeHg), and 0.07 kg/yr (DMeHg) with bank erosion processes the principal mechanism of loading for both total and dissolved species. Prediction error in the reservoir is within one‐order of magnitude and considered qualitative; however, simulated results indicate internal cycling within the receiving reservoir accounts for only 1% of the reservoir's water column contamination, with river channel sediment sources more influential in the upper reservoir and bank erosion processes having greater influence in the lower reservoir.     

Climate change effects on aquatic biota, ecosystem structure and function

Climate change is projected to cause significant alterations to aquatic biogeochemical processes, (including carbon dynamics), aquatic food web structure, dynamics and biodiversity, primary and secondary production; and, affect the range, distribution and habitat quality/quantity of aquatic mammals and waterfowl. Projected enhanced permafrost thawing is very likely to increase nutrient, sediment, and carbon loadings to aquatic systems, resulting in both positive and negative effects on freshwater chemistry. Nutrient and carbon enrichment will enhance nutrient cycling and productivity, and alter the generation and consumption of carbon-based trace gases. Consequently, the status of aquatic ecosystems as carbon sinks or sources is very likely to change. Climate change will also very likely affect the biodiversity of freshwater ecosystems across most of the Arctic. The magnitude, extent, and duration of the impacts and responses will be system- and location-dependent. Projected effects on aquatic mammals and waterfowl include altered migration routes and timing; a possible increase in the incidence of mortality and decreased growth and productivity from disease and/or parasites; and, probable changes in habitat suitability and timing of availability.     

Spectrophotometric determination of uranium with arsenazo-III in perchloric acid

A short, sensitive and reliable spectrophotometric method, which has advantages over all known "wet chemistry" methods for uranium determination with regard to tolerance to common interferences, has been developed for the determination of uranium. Selectivity, molar absorptivity and the determination range of uranium have been enhanced by using 0.07% arsenazo-III as a chromogenic reagent. The use of 3 mol dm(-3) perchloric acid as a medium of determination was found to be excellent in terms of good solvent compatibility on dilution, destruction of organic contamination and simplicity of operation. The uranium-arsenazo-III complex formed instantly, and was found to be stable for more than 3 weeks with constant absorbance. Beer's law was obeyed up to a uranium concentration of 16 microg g(-1), with a molar absorptivity at 651 nm of 1.45x10(5) mol(-1) dm(3) cm(-1) at 24+/-2 degrees C. Only phosphate and citrate at 70-fold excess over uranium interfere seriously, whereas other anions studied could be tolerated up to a 70-fold excess over uranium. Of the cations studied, only Mn(II), Co(II), Ni(II), Cu(II) and Cr(III) decreased the normal absorbance of the complex. Iron(III), Ce(III) and Y(III) enhanced the absorbance. Other cations studied did not affect the absorbance up to a 50-fold excess. The accuracy was checked by determining uranium from standard solutions in the range 10-50 microg g(-1). It was found to be accurate with a 96.0-98.6% recovery rate. The method has been successfully applied to standard reference materials and ore samples at microg g(-1) levels.     

USE OF FIRST-ORDER UNCERTAINTY ANALYSIS TO OPTIMIZE SUCCESSFUL STREAM WATER QUALITY SIMULATION1

ABSTRACT: A first-order uncertainty technique is developed to quantify the relationship between field data collection and a modeling exercise involving both calibration and subsequent verification. A simple statistic (LTOTAL) is used to quantify the total likelihood (probability) of successfully calibrating and verifying the model. Results from the first-order technique are compared with those from a traditional Monte Carlo simulation approach using a simple Streeter-Phelps dissolved oxygen model. The largest single difference is caused by the filtering or removal of unrealistic outcomes within the Monte Carlo framework. The amount of bias inherent in the first-order approach is also a function of the magnitude of input variability and sampling location. The minimum bias of the first-order technique is approximately 20 percent for a case involving relatively large uncertainties. However the bias is well behaved (consistent) so as to allow for correct decision making regarding the relative efficacy of various sampling strategies. The utility of the first-order technique is demonstrated by linking data collection costs with modeling performance. For a simple and inexpensive project, a wise and informed selection resulted in an LTOTAL value of 86 percent, while an uninformed selection could result in an LTOTAL value of only 55 percent.     

HYDRODYNAMIC MODELING OF THE CARSON RIVER AND LAHONTAN RESERVOIR,NEVADA1

ABSTRACT: The RIVMOD hydrodynamic model was used to route upstream flows through a 115 km section of the Carson River and Lahontan Reservoir, Nevada. RIVMOD results will later be used to predict sediment movement and ultimately to determine mercury transport within the river/reservoir system. Significant modifications to the model computer code were necessary to represent the narrow, steeply sloping rectangular channel and relatively shallow sloping floodplain of the Carson River and its confluence with the Lahontan Reservoir. These changes include expansion of the continuity and momentum equations to account for rapidly changing channel widths along with the characterization of a complex cross-sectional shape. This modified version of the RIVMOD model can handle shallower side slopes and much more severe flood flow simulations than the original version. A 0.25 km spatial increment was required in the zone of confluence between the river and reservoir. Model predictions show excellent agreement with observed downstream flow and reservoir stage for the entire 1986 water year, which includes one of the most severe flood events of recent record. (KEY TERMS: hydraulics; modeling; simulation; surface water hydrology.)     

COMPUTING THE RISKS ASSOCIATED WITH WASTELOAD) ALLOCATION MODELING1

ABSTRACT: The risks associated with a traditional wasteload allocation (WLA) analysis were quantified with data from a recent study of the Upper Trinity River (Texas). Risk is define here as the probability of failing to meet an established in-stream water quality standard. The QUAL-TX dissolved oxygen (DO) water quality model was modified to a Monte Carlo framework. Flow augmentation coding was also modified to allow an exact match to be computed between the predicted and an established DO concentration standard, thereby providing an avenue for linking input parameter uncertainty to the assignment of a wasteload permit (allowable mass loading rate). Monte Carlo simulation techniques were employed to propagate input parameter uncertainties, typically encountered during WLA analysis, to the computed effluent five-day carbonaceous biochemical oxygen demand requirements for a single major wastewater treatment plant (WWTP). The risk of failing to meet an established in-stream DO criterion may be as high as 96 percent. The uncertainty associated with estimation of the future total Kjeldahl nitrogen concentration for a single tributary was found to have the greatest impact on the determination of allowable WWTP loadings.     

Sampling and analyses of colloids at the Drigg low level radioactive waste disposal site

Water samples have been extracted from inside (from standpipes) and from outside (from boreholes) of the trenches at the low level radioactive waste disposal site at Drigg in Cumbria, UK. The samples were taken anaerobically from between 8.5 and 10.0 m below the surface using a submersible pump at low flow rates to ensure that the waters in the standpipes and boreholes were maintained at constant levels. To ensure representative samples, the Eh, pH. conductivity, temperature, iron and dissolved oxygen concentrations of the waters were taken during initial purging and during sampling. The gross tritium, gross non-tritium beta, gross alpha and gamma activities of each sample were determined using suitable sample preparation and counting techniques. Samples were then anaerobically, sequentially filtered through 12 microm, 1 microm, 30 kDa and 500 Da filter membranes. The filtrates were analysed for gross alpha, gross non-tritium beta and gamma activities. SEM and STEM analyses were used to determine the colloid population. An energy dispersive analyser on the SEM was used to determine the major elements present in the colloids. UV-visible spectrophotometry, fluorescence spectrophotometry and high performance size exclusion liquid chromatography were used to analyse the waters before and after treatment with ion exchange materials to determine whether natural organic matter was present in the waters. Results showed that two major types of colloids (iron containing colloids and silicon containing colloids) were present in the waters. There were also a small number of other colloids that contain, as major elements, aluminium, calcium and chromium. Organic colloids were also present. The majority of the radioactivity in the waters was due to tritium. Waters taken from outside the trenches contained low levels of non-tritium beta activities and alpha activities which were lower than the minimum detectable amount. Waters taken from the trenches contained non-tritium beta activities and low levels of alpha emitters. Filtration of the trench waters showed that some of the alpha activity was retained by the 30 kDa and 500 Da membranes suggesting that this activity was associated with small colloids. Radioactivity was not found to be associated with colloids present in the waters taken from outside the trenches. Possible reasons for this observation could be that radionuclide bearing colloids have not yet reached the far-field or that the radionuclide concentration is diluted to below the minimum detectable amount. After concentrating two of the samples by factors of x20 and x 16 respectively, 2.4+/-0.1 and 0.6+/-0.1 Bq dm(-3) of 137Cs were measured.     

Freeliving marine nematodes as a pollution indicator of the Bohai Sea

A hierarchical diversity index-taxonomic distinctness index Δ , which was first defined by Warwick and Clark in 1998, was　employed to evaluate the pollution status of the Bohal Sea with freeliving marine nematodes. The result showed that the Bohal Bay and other　coastal sampling sites might be affected by oil and gas production and other anthropogenic influences. In other words, anthropogenic disturbance　was affecting this component of the benthos in these locations. And most offshore sampling sites in the middle of the Bohai Sea were clear and　unpolluted.     

Freeliving marine nematodes as a pollution indicator of Bohai Sea

A hierarchical diversity index--taxonomic distinctnessindex +, which was first defined by Warwick and Clark in 1998, wasemployed to evaluate the pollution status of the Bohai Sea withfreeliving marine nematodes. The result showed that the Bohai Bayand other coastal sampling sites might be affected by oil and gasproduction and other anthropogenic influences. In other words,anthropogenic disturbance was affecting this component of thebenthos in these locations. And most offshore sampling sites in themiddle of the Bohai Sea were clear and unpolluted.     

Ecophilosophy and science

Summary This paper aims to do two main things: first, to provide an introduction to ecophilosophy by presenting a spectrum of positions that have been developed to characterise the relationship between humans and their environment; second, to examine the variety of ways in which scientific work impacts upon human thought in regard to each of these positions. The import of this discussion should be twofold: first, it should help to acquaint readers with, and hopefully, interest them in, the kinds of developments that have been occurring in the area of ecophilosophy; second, it should help to acquaint environmentally concerned people with, and, hopefully, interest them in, the relevance of science to their arguments. Although many environmentally concerned people are scientifically informed, this second aim is worth stating because a number of environmentally concerned people unfortunately remain suspicious of the role of science in general.Dr Warwick Fox is a Research Fellow at the Centre for Environmental Studies at the University of Tasmania. His first degree, in experimental psychology from the University of Western Australia, was followed by PhD in environmental philosophy. Currently his research interests are concerned with the development of a comprehensive and coherent oriented world view, from epistemology and cosmology to psychology, ethnics and politics.