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51.
Heterogeneous formation of chlorinated dibenzo-p-dioxins (CDDs) and dibenzofurans (CDFs) on CuCl2 from three phenols without ortho chlorine and one phenol with two ortho chlorines was studied in a flow reactor over a temperature range of 325-450 degrees C. Heated nitrogen gas streams containing 8% oxygen, 1.5% benzene vapor, and equal amounts of phenol, 3-chlorophenol, 3,4-dichlorophenol and 2,4,6-trichlorophenol vapor (700 ppmv, each) were passed through a 1 g particle bed of silica and 0.5% (Cu mass) CuCl2. Maximum product yields of greater than 1.4% phenol conversion to CDD and 5.7% phenol conversion to CDF were observed between 400 and 450 degrees C. CDDs formed with loss of one chlorine atom were favored. While total CDD/F yield varied with temperature, CDD/F homologue and isomer distributions did not vary significantly with temperature. Based on the results of experiments with single phenol precursors, phenol precursors could be assigned to all PCDD/F products. Of the chlorinated phenols without ortho chlorine that were studied, 3,4-dichlorophenol was found to have the greatest propensity to form CDFs. 相似文献
52.
Enhanced anaerobic biodegradability and inactivation of fecal coliforms and Salmonella spp. in wastewater sludge by using microwaves. 总被引:1,自引:0,他引:1
During continuous operation of three mesophilic-anaerobic digesters, the effect of microwave irradiation, as sludge thermal pretreatment (60 to 65 degrees C), was studied. The fecal coliforms log inactivation for microwaved/digested sludge was 4.2 +/- 0.4, whereas for conventionally heated/digested sludge and control were 2.9 +/- 0.5 and 1.5 +/- 0.5, respectively. In the case of Salmonella spp., no colonies were detected in 85% of the microwaved/digested samples. Considering the detection limit, the log inactivation of these samples was greater than 2.0 +/- 0.3. The conventionally heated/digested sludge and control showed log inactivations of 1.9 +/- 0.2 and 1.1 +/- 0.3, respectively. At the 95% confidence level, microwaved/digested sludge increased the biogas production by 16.4 +/- 5.6% and 6.3 +/- 2.4%, as compared to control and conventionally heated/digested sludge, respectively. When thermally treated sludge was analyzed for soluble chemical oxygen demand, microwaved waste-activated sludge showed considerable solubilization between 37 and 60 degrees C. Microwaved/digested sludge showed a reduction of capillary suction times by 11.1 +/- 5.9% and 10.7 +/- 5.6%, as compared to control and conventionally heated/digested sludge, respectively. 相似文献
53.
Corey Boles Grant Brown Jae Hong Park Matthew Nonnenmann 《Food and environmental virology》2020,12(3):199-208
Globally, norovirus is the most common gastroenteritis causing pathogen. Annually, norovirus causes 685 million cases of acute gastroenteritis and 200,000 相似文献
54.
Young Ryu Young-Oh Kim Seung Beom Seo Il Won Seo 《Mitigation and Adaptation Strategies for Global Change》2018,23(6):803-819
With concerns regarding global climate change increasing, recent studies on adapting to nonstationary climate change recommended a different planning strategy that could spread risks. Uncertainty in global climate change should be considered in any decision-making processes for flood mitigation strategies, especially in areas within a monsoon climate regime. This study applied a novel planning method called real option analysis (ROA) to an important water resources planning practice in Korea. The proposed method can easily be applied to other watersheds that are threatened by flood risk under climate change. ROA offers flexibility for decision-makers to reflect uncertainty at every stage during the project planning period. We successfully implemented ROA using a binomial tree model, including two real options—delay and abandon—to evaluate flood mitigation alternatives for the Yeongsan River Basin in Korea. The priority ranking of the four alternatives between the traditional discount cash flow (DCF) and ROA remained the same; however, two alternatives that were assessed as economically infeasible using DCF, were economically feasible using ROA. The binomial decision trees generated in this study are expected to be informative for decision-makers to conceptualize their adaptive planning procedure. 相似文献
55.
We have developed a new nanofilter using a carbon nanotube-silver composite material that is capable of efficiently removing waterborne viruses and bacteria.The nanofilter was subjected to plasma surface treatment to enhance its flow rate,which was improved by approximately 62%.Nanoscale pores were obtained by fabricating a carbon nanotube network and using nanoparticle fixation technology for the removal of viruses.The pore size of the nanofilter was approximately 38 nm and the measured flow rate ranged from 21.0 to 97.2 L/(min·m~2)under a pressure of 1–6 kgf/cm~2 when the amount of loaded carbon nanotube-silver composite was 1.0 mg/cm~2.The nanofilter was tested against Polio-,Noro-,and Coxsackie viruses using a sensitive real-time polymerase chain reaction assay to detect the presence of viral particles within the outflow.No trace of viruses was found to flow through the nanofilter with carbon nanotube-silver composite loaded above 0.8 mg/cm~2.Moreover,the surface of the filter has antibacterial properties to prevent bacterial clogging due to the presence of 20-nm silver nanoparticles,which were synthesized on the carbon nanotube surface. 相似文献
56.
Jae Gyu Hwang Hang Seok Choi Jun Hwa Kwon 《Journal of Material Cycles and Waste Management》2016,18(4):771-780
In the present study, an experiment was performed to investigate the mixing and segregation characteristics of standard sand and rice straw particles in a cylindrical bubbling fluidized bed. The mass ratio (rice straw/standard sand = 0.5–1.25 %) of two particles and superficial gas velocity (0.13–0.18 m/s) were changed as experimental variables. The pressure drop curve and Kramer’s equation were used to determine the minimum fluidization velocity and mixing index, respectively. In all cases, the mixing index was the lowest at U/U mf = 1.15. Based on the point of U/U mf = 1.15, the segregation region and mixing region were observed. In the segregation region, mass ratio of 0.75 % showed the lowest mixing index. At the U/U mf = 1.23 which was selected as the starting of fast pyrolysis considering residence time and the previous fast pyrolysis experiment, mass ratio of 1.25 % showed the highest mixing index which was 0.90. 相似文献
57.
Objective: In 2012, 4,743 pedestrians were killed in the United States, representing 14% of total traffic fatalities. The number of pedestrians injured was higher at 76,000. Therefore, 36 out of 52 of the largest cities in the United States have adopted a citywide target of reducing pedestrian fatalities. The number of cities adopting the reduction goal during 2011 and 2012 increased rapidly with 8 more cities. We examined the scaling relationship of pedestrian fatality counts as a function of the population size of 115 to 161 large U.S. cities during the period of 1994 to 2011. We also examined the scaling relationship of nonpedestrian and total traffic fatality counts as a function of the population size.Methods: For the data source of fatality measures we used Traffic Safety Facts Fatality Analysis Reporting System/General Estimates System annual reports published each year from 1994 to 2011 by the NHTSA. Using the data source we conducted both annual cross-sectional and panel data bivariate and multivariate regression models. In the construction of the estimated functional relationship between traffic fatality measures and various factors, we used the simple power function for urban scaling used by Bettencourt et al. (2007, 2010) and the refined STIRPAT (stochastic impacts by regression on population, affluence, and technology) model used in Dietz and Rosa (1994, 1997) and York et al. (2003).Results: We found that the scaling relationship display diseconomies of scale or sublinear for pedestrian fatalities. However, the relationship displays a superlinear relationship in case of nonpedestrian fatalities. The scaling relationship for total traffic fatality counts display a nearly linear pattern. When the relationship was examined by the 4 subgroups of cities with different population sizes, the most pronounced sublinear scaling relationships for all 3 types of fatality counts was discovered for the subgroup of megacities with a population of more than 1 million.Conclusions: The scaling patterns of traffic fatalities of subgroups of cities depend on population sizes of the cities in subgroups. In particular, 9 megacities with populations of more than 1 million are significantly different from the remaining cities and should be viewed as a totally separate group. Thus, analysis of the patterns of traffic fatalities needs to be conducted within the group of megacities separately from the other cities with smaller population sizes for devising prevention policies to reduce traffic fatalities in both megacities and smaller cities. 相似文献
58.
A multilevel study of group‐focused and individual‐focused transformational leadership,social exchange relationships,and performance in teams
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Using matched reports from 73 team leaders and 359 of their members across 23 companies in Korea, we examined a multilevel model where group‐ and individual‐focused transformational leadership and their influence processes operate at the team and dyadic levels independently and interactively to be associated with team and member performance. Results indicated that group‐focused transformational leadership was positively associated with team performance through team member exchange (TMX), whereas individual‐focused transformational leadership positively related to team members' in‐role and extra‐role performance through leader–member exchange (LMX). TMX not only positively mediated the relationships between group‐focused transformational leadership and member performance after controlling for LMX but also positively moderated LMX–performance relationships. Moreover, the indirect effect of individual‐focused transformational leadership through LMX on member performance was contingent upon the level of TMX. Theoretical and applied implications are discussed. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
59.
Sung Ho Hwang Chung Sik Yoon Kyong Nam Ryu Samuel Y. Paik Jun Ho Cho 《Atmospheric environment (Oxford, England : 1994)》2010,44(13):1658-1662
This study assessed bacterial concentrations in indoor air at 25 underground railway stations in Seoul, Korea, and investigated various related factors including the presence of platform screen doors (PSD), depth of the station, year of construction, temperature, relative humidity, and number of passengers. A total of 72 aerosol samples were collected from all the stations. Concentrations of total airborne bacteria (TAB) ranged from not detected (ND) to 4997 CFU m?3, with an overall geometric mean (GM) of 191 CFU m?3. Airborne bacteria were detected at 23 stations (92%) and Gram-negative bacteria (GNB) were detected at two stations (8%). TAB concentrations of four stations (16%) exceeded 800 CFU m?3, the Korea indoor bio-aerosol guideline. The results of the study showed that TAB concentrations at the stations without PSD showed higher TAB concentrations than those with PSD, though not at statistically significant levels. TAB concentrations of deeper stations revealed significantly higher levels than those of shallower stations. Based on this study, it is recommended that mitigation measures be applied to improve the indoor air quality (IAQ) of underground railway stations in Seoul, with focused attention on deeper stations. 相似文献
60.
Chul H. Song Mi E. Park En J. Lee Jae H. Lee Bo K. Lee Dong S. Lee Jhoon Kim Jin S. Han Kwang J. Moon Yutaka Kondo 《Atmospheric environment (Oxford, England : 1994)》2009,43(13):2168-2173
Simultaneous measurements of gaseous species and fine-mode, particulate inorganic components were performed at the University of Seoul, Seoul in Korea. In the simultaneous measurements, a certain level of nitrous acid (HONO) was observed in the gas-phase, indicating possible heterogeneous HONO production on the surface of the ambient aerosols. On the other hand, high particulate nitrite (NO2?) concentrations of 1.41(±2.26) μg/m3 were also measured, which sometimes reached 18.54 μg/m3. In contrast, low HONO-to-NO2 ratios of 0.007(±0.006) were observed in Seoul. This indicates that a significant fraction of HONO is dissolved in atmospheric aerosols. Around the Seoul site, sufficient alkalinity may have been provided to the atmospheric aerosols from the excessive presence of NH3 in the gas-phase. Due to the alkaline particulate conditions (defined in this study as a particle pH >~3.29), the HONO molecules produced at the surface of the atmospheric aerosols appeared to have been converted into particulate nitrite, thereby preventing their further participation in the atmospheric O3/NOy/HOx photochemical cycles. It was estimated that a minimum average of 65% of HONO was captured by alkaline, anthropogenic, urban particles in the Seoul measurements. 相似文献