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881.
Martín-Díaz ML Tuberty SR McKenney CL Blasco J Sarasquete C Delvalls TA 《Environmental monitoring and assessment》2006,116(1-3):169-184
Individuals of the crayfish Procambarus clarkii (males and females) were exposed simultaneously to cadmium and zinc during 21 days. Exposure concentrations were those determined
at the Guadiamar river after the Aznalcóllar mining spill (SW, Spain): 10 and 30 μg L−1 of cadmium and 1000 and 3000 μg L−1 of zinc. Three biomarkers (MT: metallothioneins like proteins, VTG: vitellogenin/vitellin like proteins and histopathology)
together with heavy metal bioaccumulation were determined in soft tissues of male and female P. clarkii. At the concentrations tested, increasing cadmium exposure resulted in increasing cadmium bioaccumulation and increasing subletal
effects (induction of MT, VTG and histopathological damage in tissues). Nevertheless, although increasing zinc exposure showed
increasing VTG induction and histopathological damages, not a positive relationship was determined with MT induction. Concerning
to responses determined in male and female crayfishes only differences were found between sexes at the highest cadmium exposure
concentration related to bioaccumulation in hepatopancreas tissues. Biomarkers responses to heavy metal contamination in this
crayfish, even VTG induction not before tested in heavy metal contamination assessment in crustaceans resulted potential tools
for the monitoring of heavy metal environmental contamination. 相似文献
882.
Weyer PJ Smith BJ Feng ZF Kantamneni JR Riley DG 《Environmental monitoring and assessment》2006,116(1-3):81-90
Nitrate contamination of water sources is a concern where large amounts of nitrogen fertilizers are regularly applied to soils.
Ingested nitrate from dietary sources and drinking water can be converted to nitrite and ultimately to N-nitroso compounds,
many of which are known carcinogens. Epidemiologic studies of drinking water nitrate and cancer report mixed findings; a criticism
is the use of nitrate concentrations from retrospective drinking water data to assign exposure levels. Residential point-of-use
nitrate data are scarce; gaps in historical data for municipal supply finished water hamper exposure classification efforts.
We used generalized linear regression models to estimate and compare historical raw water and finished water nitrate levels
(1960s--1990s) in single source Iowa municipal supplies to determine whether raw water monitoring data could supplement finished
water data to improve exposure assessment. Comparison of raw water and finished water samples (same sampling date) showed
a significant difference in nitrate levels in municipalities using rivers; municipalities using other surface water or alluvial
groundwater had no difference in nitrate levels. A regional aggregation of alluvial groundwater municipalities was constructed
based on results from a previous study showing regional differences in nitrate contamination of private wells; results from
this analysis were mixed, dependent upon region and decade. These analyses demonstrate using historical raw water nitrate
monitoring data to supplement finished water data for exposure assessment is appropriate for individual Iowa municipal supplies
using alluvial groundwater, lakes or reservoirs. Using alluvial raw water data on a regional basis is dependent on region
and decade. 相似文献
883.
A Characterization of Selected Endocrine Disruptor Compounds in a Portuguese Wastewater Treatment Plant 总被引:1,自引:0,他引:1
Maurício R Diniz M Petrovic M Amaral L Peres I Barceló D Santana F 《Environmental monitoring and assessment》2006,118(1-3):75-87
Anthropogenic compounds that are able to disrupt the endocrine system of wildlife species are a major cause for concern and
have led to a demand for new screening methods. The identification and quantification of endocrine disruptor compounds at
wastewater treatment plant is of major interest to assess the endocrine activity of wastewater treatment plant discharges
into the environment. This study consists of a preliminary survey of concentrations of previously selected endocrine disruptor
compounds, undertaken to establish environmental concentrations and to support a biological program assay exposing freshwater
fish to them. Selected endocrine disrupting chemicals (APEs, bisphenol A and 17 β-estradiol) were measured in samples from a wastewater treatment plant located in Lisbon (Portugal), using recent commercial
enzyme-linked immunosorbent assay kits and also LC-MS/MS. The results show that the wastewater treatment plant treatment process
is efficient on the removal of target endocrine disruptor compounds. However, environmentally significant concentrations are
still present in the treated effluent. The results also show that enzyme-linked immunosorbent assay kit is suitable for routine
analysis of the selected compounds. The results are also useful since the wastewater treatment plant is located in a Mediterranean
region, which results in an effluent with its own characteristics. 相似文献
884.
Abstact The present study was designed to evaluate indirect, non-invasive, on-line measurement of biofilm thickness using an electrical capacitance technique. Several assays were carried out and the results showed that, at a frequency of 1 kHz, electrical capacitance could be used to measure biofilm thickness indirectly (with a correlation coefficient of 0.9495). The reproducibility revealed by the assays was also highly satisfactory.However, in contrast to what was expected, there was an inverse relationship between electrical capacitance and biofilm thickness, i.e. electrical capacitance diminished with the increase in the biofilm thickness.The tests were also carried out at different frequencies (1 kHz, 10 kHz and 100 kHz) 相似文献
885.
Stromberg JC Lite SJ Rychener TJ Levick LR Dixon MD Watts JM 《Environmental monitoring and assessment》2006,115(1-3):145-173
A portion of Arizona’s San Pedro River is managed as a National Riparian Conservation Area but is potentially affected by ground-water withdrawals beyond the conservation area borders. We applied an assessment model to the Conservation Area as a basis for monitoring long-term changes in riparian ecosystem condition resulting from changes in river water availability, and collected multi-year data on a subset of the most sensitive bioindicators. The assessment model is based on nine vegetation bioindicators that are sensitive to changes in surface water or ground water. Site index scores allow for placement into one of three condition classes, each reflecting particular ranges for site hydrology and vegetation structure. We collected the bioindicator data at 26 sites distributed among 14 reaches that had similar stream flow hydrology (spatial flow intermittency) and geomorphology (channel sinuosity, flood-plain width). Overall, 39% of the riparian corridor fell within condition class 3 (the wettest condition), 55% in condition class 2, and 6% in the driest condition class. Condition class 3 reaches have high cover of herbaceous wetland plants (e.g., Juncus and Schoenoplectus spp.) along the perennial stream channel and dense, multi-aged Populus-Salix woodlands in the flood plain, sustained by shallow ground water in the stream alluvium. In condition class 2, intermittent stream flows result in low cover of streamside wetland herbs, but Populus-Salix remain abundant in the flood plain. Perennial wetland plants are absent from condition class 1, reflecting highly intermittent stream flows; the flood plain is vegetated by Tamarixa small tree that tolerates the deep and fluctuating ground water levels that typify this reach type. Abundance of herbaceous wetland plants and growth rate of Salix gooddingii varied between years with different stream flow rates, indicating utility of these measures for tracking short-term responses to hydrologic change. Repeat measurement of all bioindicators will indicate long-term trends in hydro-vegetational condition. 相似文献
886.
Archambault DJ Li X Foster KR Jack TR 《Environmental monitoring and assessment》2006,115(1-3):509-530
Ethephon, which releases ethylene within plant tissues after application, was chosen to perform assessments of the relative sensitivity of crops to ethylene and to determine which stages of plant development were most sensitive. The species chosen were: barley, wheat, oats, canola and field pea, all of which are important crops in the province of Alberta, Canada. Plants were treated with ethephon at one of 7 different stages. Plants were assessed for their vegetative and reproductive growth, including height, biomass, yield and seed quality. Visual symptoms were photographed and documented to compare them with symptoms caused by ethylene applied as a gas. It was concluded that in barley, wheat and canola the late vegetative and early reproductive stages were most sensitive, at least when sensitivity was defined as reductions in yield and quality. As for field pea, ethephon had no effect on yield but did cause increased numbers of pods, which in certain conditions could lead to increased yields. Significant effects on vegetative growth were only observed in the early vegetative stages of development but with no effects on yield. The screening protocol successfully identified sensitive cultivars and growth stages for further investigation of the effects of ethylene exposure. 相似文献
887.
Mean values of eight contaminants in Herring Gull (Larus argentatus) eggs were calculated for 15 Great Lakes sites for the 5 year period 1998–2002. The sites were ranked according to the concentrations of each of seven compounds relative to fish flesh criteria for the protection of piscivorous wildlife, and a single overall rank of contamination was calculated for each site. Based on this weighted ranking scheme, we found that sum PCBs, dioxin and DDE contributed the most (60.2, 30.5% and 8.5%, respectively) to the overall rankings. The weighted ranking scheme showed that eggs from Channel-Shelter Island (Saginaw Bay, Lake Huron), Strachan Island (St. Lawrence River) and Gull Island (northern Lake Michigan) ranked as the three most contaminated sites, while Agawa Rocks (eastern Lake Superior), Chantry Island (southern Lake Huron) and Port Colborne (eastern Lake Erie) ranked as the three least contaminated sites. Two of the three most contaminated sites are Areas of Concern; none of the three least contaminated sites are Areas of Concern. 相似文献
888.
Kim KH Mishra VK Kang CH Choi KC Kim YJ Kim DS Youn YH Lee JH 《Environmental monitoring and assessment》2006,121(1-3):379-397
In the present study, the distribution patterns of various metals were analyzed and compared using PM samples collected concurrently from three monitoring sites located in Korea (Seoul, Busan, and Jeju island) in December 2002. As these sites can represent metal pollution with different degrees of anthropogenic activities, their concentration levels were distinguished in a systematic manner in the order of Jeju, Busan, and Seoul. By comparing the present data sets with those measured previously from other locations in Korea and around the world, we attempted to diagnose the general status of elemental pollution on the Korean peninsula. Through an application of different statistical approaches, the major processes controlling elemental levels were assessed for each of the three study sites. The results indicated the importance of both crustal and anthropogenic sources in all sites with their relative roles varying significantly from each other. The results of the metal analysis data, when examined in relation to back trajectory analysis, confirmed that their concentration changes are affected quite sensitively with air mass movement patterns. The overall results of this study consistently indicated the contribution of a strong anthropogenic source area (e.g., China) to the observed metal concentration levels in the study area, but the strengths of such signals vary considerably across the Korean peninsula. 相似文献
889.
This work represents an attempt to define a simple method to classify the relative degree of disturbance of sites in lotic
systems on the basis of comparison of their faunistic composition with reference sites. Two ecotypes were selected in northern
Portugal where benthic invertebrates were sampled in reaches with different levels of contamination. As a first stage, previous
Geographic Information System information was used to define reference sites in each ecotype. Afterwards, multivariate techniques
and non linear estimation models were combined to assess biological quality. This method allowed us to quantify sites according
to increasing levels of contamination, after the probabilities of occurrence of taxa along a gradient of contamination taking
into account the reference condition. The results suggest that this method is sensitive to organic pollution, easy to interpret,
namely the species tolerance, and could be a good framework to establish regional rankings depending on the ecological impact
of river sites. 相似文献
890.
Supervisor expediency to employee expediency: The moderating role of leader–member exchange and the mediating role of employee unethical tolerance 下载免费PDF全文
Rebecca L. Greenbaum Mary B. Mawritz Julena M. Bonner Brian D. Webster Joseph Kim 《组织行为杂志》2018,39(4):525-541
We utilize social learning theory to test the role‐modeling effect of supervisor expediency (i.e., a supervisor's use of unethical practices to expedite work for self‐serving purposes). In particular, we examine the relationship between supervisor expediency and employee expediency, as moderated by leader–member exchange (LMX) and mediated by employee unethical tolerance. We predict that employees are more likely to model their supervisors' expedient behaviors when their relationship is characterized by high‐LMX (a high‐quality exchange relationship that is rich in socioemotional support). Furthermore, we argue that supervisor expediency, especially when LMX is high, influences employees' attitudes of unethical tolerance, which then affects employees' expedient behaviors. Across 2 multisource field studies and a third time‐lagged field study, we found general support for our theoretical predictions. Theoretical and practical implications are discussed. 相似文献