SIMULATION OF SEDIMENT AND PLANT NUTRIENT LOSSES BY THE CREAMS WATER QUALITY MODEL1

ABSTRACT: CREAMS was applied to a field-sized watershed planted to cotton in the Limestone Valley region of northern Alabama. The field was cultivated for three years with conventional tillage (CvT) followed by three years of conservation tillage (CsT). CREAMS is composed of three components: hydrology, erosion, and chemistry. Surface runoff and losses of sediment, N and P were simulated and results were compared with the observed data from the watershed. Curve numbers recommended in the CREAMS user's guide were not adequate for the watershed conditions. The hydrology submodel improved runoff simulation from CvT and CsT when field-data based curve numbers were used. The erosion submodel demonstrated that CsT reduced sediment loss more than CvT, even though CsT had higher runoff than CvT. The nutrient submodel based on the simulated runoff and sediment underpredicted N loss for both CvT and CsT. This submodel, however, accurately predicted P loss for CvT, but underpredicted for CsT (50 percent lower than the observed). The results of CREAMS simulation generally matched the observed order of magnitude for higher runoff, lower sediment, and higher N and P losses from CsT than from CvT.     

The role of local governments before and during chemical accidents,focusing on changes in hazardous chemical management systems

ABSTRACT

Disaster management spans actions before, during, and after disaster events. Changes in the roles and functions of local governments before a disaster can influence other stages of disaster management. After a chemical spill in 2012, South Korean hazardous chemical management tasks were returned to the central government and local governments’ roles and functions were reduced. To identify associated issues and enhance the hazardous chemical management system, this study analyzed changes in laws and policies and conducted interviews with stakeholders. While the changes helped with centralization, reinforcement, and specification, some loopholes were discovered. The information and human resource capacities of local governments and intra – and intergovernmental relations issues have hindered their active participation before and during chemical disasters. These loopholes can be addressed through institutional enhancements for local governments, such as including them in monitoring hazardous chemical handling facilities, developing codes articulating the division of tasks among departments within them, and providing adequate incentives for them to increase their personnel. This study provides empirical data that informs ongoing debates about the centralization and devolution of disaster management by linking local governments’ ordinary management systems to their disaster management activities.     

Characteristics of malodor pollutants and aromatic VOCs around an urban valley in Korea

In this study, the environmental behavior of malodor pollutants (MPs) [including reduced sulfur compounds (RSCs)] and aromatic volatile organic compounds (AVOCs) were investigated around urban valley areas during several field campaigns (February through December 2006). The MPs measured in the study area include the RSCs (H(2)S, CH(3)SH, DMS, and DMDS), ammonia (NH(3)), and styrene (STY); the AVOCs include benzene (BEN), toluene (TOL), ethylbenzene (EB), m,p-xylene (MPX), and o-xylene (OX). The variation of most MP concentrations (except for DMDS) was found to be larger than that of AVOCs. It was found that STY (2,346 +/- 4,867 ppbv) was the most dominant MP followed by NH(3) (447 +/- 285), CH(3)SH (16 +/- 41), and the others (<8). The magnitude of AVOCs was found in the following descending order: TOL (1.4 +/- 2.2 ppbv), EB (1.0 +/- 2.1), MPX (0.9 +/- 2.0), and the others (<0.8). The concentration levels of most MPs on industrial (I) and downwind (D) sites were up to an order of magnitude higher than those at non-industrial (N) and upwind (U) sites. For most AVOCs, the former was ~3 times higher than the latter. For malodor intensity in RSCs, CH(3)SH was the dominant contributor. The concentration difference in target compounds between the sites/periods is likely to be caused by the combined effects such as emission sources, geographical features (e.g., semi-closed topography), and meteorological conditions (e.g., wind directions) in and outside the urban valley.     

Distribution of perfluorochemicals between sera and milk from the same mothers and implications for prenatal and postnatal exposures

The levels of six perfluorocarboxylates (PFCAs), four perfloroalkylsulfonates (PFASs), and one sulfonamide were measured in paired samples of maternal serum, umbilical cord serum, and breast milk. The maternal and cord sera were strongly correlated with each other for all measured compounds (r > 0.5 and p < 0.01). Nevertheless, there was a significant difference in compound composition profile between the two sera matrices, with a more depletion of the longer chain compounds in cord serum. The transfer efficiency values from maternal to cord serum (TF_CS/MS) decreased by 70% with each increasing unit of -CF₂ chain within a PFCA group, and for perfluorooctanesulfonate (PFOS), by a half compared to perfluorooctanoate (PFOA). In contrast to the strong correlation in concentrations between the two sera matrices, the pattern of compounds in breast milk differed considerably with those in sera. Accordingly, compound- and matrix-specific transfer must be considered when assessing prenatal and postnatal exposure.     

Fine particle removal performance of a two-stage wet electrostatic precipitator using a nonmetallic pre-charger

A novel two-stage wet electrostatic precipitator (ESP) has been developed using a carbon brush pre-charger and collection plates with a thin water film. The electrical and particle collection performance was evaluated for submicrometer particles smaller than 0.01- 0.5 micrometer in diameter by varying the voltages applied to the pre-charger and collection plates as well as the polarity of the voltage. The collection efficiency was compared with that calculated by the theoretical models. The long-term performances of the ESP with and without water films were also compared in tests using Japanese Industrial Standards dust. The experimental results show that the carbon brush pre-charger of the two-stage wet ESP had approximately 10% particle capture, while producing ozone concentrations of less than 30 ppb. The produced amounts of ozone are significantly lower than the current limits set by international agencies. The ESP also achieved a high collection rate performance, averaging 90% for ultrafine particles, as based on the particle number concentration at an average velocity of 1 m/sec corresponding to a residence time of 0.17 sec. Higher particle collection efficiency for the ESP can be achieved by increasing the voltages applied to the pre-charger and the collection plates. The decreased collection efficiency that occurred during dust loading without water films was completely avoided by forming a thin water film on the collection plates at a water flow rate of 6.5 L/min/m(2).     

Chemical characteristics of long-range transport aerosol at background sites in Korea

In this study, background concentration sites of Deokjeok and Gosan, which were deemed suitable for monitoring the impact of long-range transported air pollutants, were selected. An investigation of the source types of pollutants, their locations, and relative quantitative contributions to the particulate concentrations at both sites using appropriate methodologies to make initial estimations was conducted. Episodic measurements of PM_2.5, PM₁₀, and size distribution, along with its ion and carbon components were performed from 2005 to 2007, and a comprehensive analysis of the results was conducted utilizing back trajectory analysis. As for frequency of wind direction, it was quite apparent that the two sites are heavily influenced by air masses originating from the eastern and northern regions of China. For PM_2.5 and PM₁₀, the mass concentrations from north and east China were higher than other cases, originating from the ocean. In the northerly-wind case, meteorological properties for Deokjeok and Gosan and the influence of carbon emissions from northwest Korea resulted in a changing of air mass properties during transport. As was the case with mass concentration, the highest contribution for ionic and carbon components of PM_2.5 and PM₁₀ for both sites appeared for the westerly wind case. A specially high relative contribution, greater than 1.4 times, was apparent in the secondary aerosol case because of a large influence of long-range transported pollutants from east China. Carbon components exhibited different behaviors for the northerly and westerly wind cases compared with secondary aerosol. The major reason for this discrepancy appears to be the carbon emissions from northwest Korea.     

Fine Particle Removal Performance of a Two-Stage Wet Electrostatic Precipitator Using a Nonmetallic Pre-Charger

ABSTRACT

A novel two-stage wet electrostatic precipitator (ESP) has been developed using a carbon brush pre-charger and collection plates with a thin water film. The electrical and particle collection performance was evaluated for submicrometer particles smaller than 0.01～0.5 μm in diameter by varying the voltages applied to the pre-charger and collection plates as well as the polarity of the voltage. The collection efficiency was compared with that calculated by the theoretical models. The long-term performances of the ESP with and without water films were also compared in tests using Japanese Industrial Standards dust. The experimental results show that the carbon brush pre-charger of the two-stage wet ESP had approximately 10% particle capture, while producing ozone concentrations of less than 30 ppb. The produced amounts of ozone are significantly lower than the current limits set by international agencies. The ESP also achieved a high collection rate performance, averaging 90% for ultrafine particles, as based on the particle number concentration at an average velocity of 1 m/sec corresponding to a residence time of 0.17 sec. Higher particle collection efficiency for the ESP can be achieved by increasing the voltages applied to the pre-charger and the collection plates. The decreased collection efficiency that occurred during dust loading without water films was completely avoided by forming a thin water film on the collection plates at a water flow rate of 6.5 L/min/m2 Zukeran, A., Ikeda, Y., Ehara, Y., Matsuyama, M., Ito, T., Takahashi, T., Kawakami, H. and Takamatsu, T. 1999. Two-Stage-Type Electrostatic Precipitator Re-entrainment Phenomena under Diesel Flue Gases. IEEE. Trans. Ind. Appl, 35: 346–351. [Crossref], [Web of Science ®] , [Google Scholar].

IMPLICATIONS Current two-stage electrostatic precipitators (ESPs) have several technical problems such as a drop in collection efficiencies by small-particle re-entrainment during rapping and corrosion of metallic electrodes of the ESPs by corrosive gases. This paper evaluates a novel two-stage ESP that uses a nonmetallic pre-charger and water film collection plates to avoid the above mentioned problems of other ESPs. This ESP can be used not only for industrial applications but also for residential purposes because it has a high removal performance for fine particles with low ozone generation and maintains its efficiency due to the continuous cleaning of the collection plates with water film.     

Assessment of lead uptake in reptilian prey species

As part of an investigation determining the trophically available fraction of metals in a model terrestrial food web, i.e., invertebrate prey to Western fence lizards (Sceloporus occidentalis), we evaluated the ability of several invertebrate prey to bioaccumulate lead and to form metals-rich granules, which are hypothesized to be non-available to predators. Crickets (Acheta domestica), tenebroid beetle larvae (Tenebrio molitor), and isopods (Porcellio scaber) were selected as model prey organisms. Lack of standard exposure methodologies for these species has presented a barrier to trophic transfer evaluations, as each species has particular requirements that create challenges for designing exposure conditions. We were able to devise exposure conditions for all three species that allow long-term exposure studies. All prey organisms accumulated lead from contaminated food, and for all species the majority of the accumulated Pb was associated with the exoskeleton (>50%), with metals-rich granules accounting for most of the remaining accumulated lead.     

Decision-Tree-based data mining and rule induction for predicting and mapping soil bacterial diversity

Soilmicrobial ecology plays a significant role in global ecosystems. Nevertheless, methods of model prediction and mapping have yet to be established for soil microbial ecology. The present study was undertaken to develop an artificial-intelligence- and geographical information system (GIS)-integrated framework for predicting and mapping soil bacterial diversity using pre-existing environmental geospatial database information, and to further evaluate the applicability of soil bacterial diversity mapping for planning construction of eco-friendly roads. Using a stratified random sampling, soil bacterial diversity was measured in 196 soil samples in a forest area where construction of an eco-friendly road was planned. Model accuracy, coherence analyses, and tree analysis were systematically performed, and four-class discretized decision tree (DT) with ordinary pair-wise partitioning (OPP) was selected as the optimal model among tested five DT model variants. GIS-based simulations of the optimal DT model with varying weights assigned to soil ecological quality showed that the inclusion of soil ecology in environmental components, which are considered in environmental impact assessment, significantly affects the spatial distributions of overall environmental quality values as well as the determination of an environmentally optimized road route. This work suggests a guideline to use systematic accuracy, coherence, and tree analyses in selecting an optimal DT model from multiple candidate model variants, and demonstrates the applicability of the OPP-improved DT integrated with GIS in rule induction for mapping bacterial diversity. These findings also provide implication on the significance of soil microbial ecology in environmental impact assessment and eco-friendly construction planning.