Effect of advanced oxidants generated via ultraviolet light on a sequentially loaded and regenerated granular activated carbon biofilter

The objective of this research was to investigate a sequentially loaded and regenerated granular activated carbon (GAC) biofilter system and to determine whether regenerative ozonation/advanced oxidation could improve the removal and biodegradation of a volatile organic compound from a contaminated airstream. Bench-scale reactors were constructed to operate in a manner analogous to a commercially available system manufactured by Terr-Aqua Environmental Systems (only with longer contact time). The GAC system consisted of two GAC biofilter beds that operated in a cyclical manner. On a given day, the first GAC bed adsorbed methyl isobutyl ketone from a simulated waste airstream, while the second bed underwent regeneration; then on the next day, the second bed was in the adsorption mode while the first was regenerated. Three bench-scale systems were used to compare the performance under three operating conditions: (1) ozone/ associated oxidant regeneration of a GAC biofilter system that was seeded with microorganisms from a field site, (2) a humid air regeneration of a seeded GAC biofilter, and (3) a humid air regeneration of an unseeded GAC biofilter. For the advanced oxidant regenerated GAC biofilter, a maximum removal efficiency of >95% was achieved with an empty bed contact time of 148 sec and an influent concentration of 125 ppm methyl isobutyl ketone, and 90-95% was achieved at 148-sec empty bed contact time and a 1150-ppm influent.     

Effects of Houseboats on Organisms of the La Parguera reserve, Puerto Rico

As coastal development increases so too does the number of artificial floating and permanent structures. It has been postulated that because of their size, many houseboats are similar to permanent structures in that they shade a significant portion of the benthos and thereby limit production by benthic flora. On the other hand, these structures can benefit biotic communities by providing sites for attachment of organisms in a substrate-limited environment and both habitat and food sources for fish. In this study, we examined whether houseboats benefit or harm the ecological integrity of a typical seagrass dominated system, at La Parguera, Puerto Rico. We performed a benthic survey to compare the diversity and health of seagrasses under houseboats to that at control locations. Species diversity (0-0.79) varied significantly among sites, but this variability was not attributed to the houseboats. Rather, the variability appeared related to the proximity of the study locations to new development along the shoreline. Average seagrass blade density and length were 52.7 blades/m(-2) and 23.6 cm, respectively. Neither parameter differed between houseboat and control areas; however, both varied significantly among sites. In addition, boat hulls were heavily encrusted with invertebrates. The overall averages of species diversity and richness of sessile organisms on hulls of the houseboats were 1.13 and 4.83, respectively. Fish also utilized these structures. Our results indicate that houseboats did not directly harm the seagrass communities at La Parguera primarily because of sound environmental management of wastes and mooring techniques.     

Computer software tool REALM for sustainable water allocation and management

REALM (REsource ALlocation Model) is a generalised computer simulation package that models harvesting and bulk distribution of water resources within a water supply system. It is a modeling tool, which can be applied to develop specific water allocation models. Like other water resource simulation software tools, REALM uses mass-balance accounting at nodes, while the movement of water within carriers is subject to capacity constraints. It uses a fast network linear programming algorithm to optimise the water allocation within the network during each simulation time step, in accordance with user-defined operating rules. This paper describes the main features of REALM and provides potential users with an appreciation of its capabilities. In particular, it describes two case studies covering major urban and rural water supply systems. These case studies illustrate REALM's capabilities in the use of stochastically generated data in water supply planning and management, modelling of environmental flows, and assessing security of supply issues.     

Loblolly pine response to wet-weather harvesting on wet flats after 5 years

The timing of forestry operations relative to weather conditions is a consideration in applying Forestry Best Management Practices (BMPs). Harvesting during different seasons can result in degrees of soil disturbance, the distribution of logging debris, and potentially future stand productivity. The purpose of this study is to examine the response of loblolly pine (Pinus taeda L.) stands after wet- and dry-weather harvesting combined with three site preparation treatments. A 20 × 20 meter grid was established in fifteen 20-year-old, 3.3-ha loblolly pine plantations in South Carolina. A census of soil physical disturbance and slash distribution was made after harvesting. Growth was measured on 1/125th-ha plots at ages two and five. Dry-weather harvested (DWH) sites were 91% undisturbed, and 9% compressed. Wet-weather harvested (WWH) sites were 41% undisturbed, and 59% disturbed. WWH sites averaged 9% bare soil, while DWH sites averaged 16% with 1 kg m^-2 less logging residue; primarily in the form of heavy and light slash. At age five, the green-weight biomass of flat-planted DWH and WWH sites were 13.3 and 12.6 kg tree^-1 respectively, and on the bedded DWH and WWH sites were 18.6 and 22.8 kg tree^-1. Wet weather harvesting did not seem to adversely affect stand growth, and may have improved it. Due to a prolonged drought, bedding had a larger effect on WWH sites than DWH harvested sites. The effects of droughty conditions may be influencing treatment response on these highly productive sites; however, the long-term effects of harvesting on stand growth remain to be seen.     

Spectral Analysis of Chemical Time Series from Long-Term Catchment Monitoring Studies: Hydrochemical Insights and Data Requirements

Hydrological and hydrochemical data from long-term monitoring stations are vital for inferring travel times and flowpaths of water, and transport of contaminants through catchments. Spectral analysis is particularly powerful for studying the hydrological and chemical dynamics of catchments across a wide range of time scales. Here, recent work is reviewed that illustrates how spectral analyses of long-term monitoring data can be used to infer the travel-time distribution of water through catchments, and to measure the chemical retardation of reactive solutes at the catchment scale. For spectral analysis, it is desirable to have data sets with high sampling frequency and long periods of coverage. Using two data sets, a 3-yr daily data series and a 17-yr weekly data series from the Hafren catchment at Plynlimon, Wales, we demonstrate that high-frequency sampling (e.g., daily or more frequent) is particularly useful for revealing the short-term chemical dynamics that most clearly reflect the interplay of subsurface chemical and hydrological processes. However, data sets that combine high-frequency sampling during storm events with low-frequency sampling between storms can cause spectral artifacts and must be treated with special care.     

REVIVING URBAN STREAMS: LAND USE,HYDROLOGY, BIOLOGY,AND HUMAN BEHAVIOR1

ABSTRACT: Successful stream rehabilitation requires a shift from narrow analysis and management to integrated understanding of the links between human actions and changing river health. At study sites in the Puget Sound lowlands of western Washington State, landscape, hydrological, and biological conditions were evaluated for streams flowing through watersheds with varying levels of urban development. At all spatial scales, stream biological condition measured by the benthic index of biological integrity (B‐IBI) declined as impervious area increased. Impervious area alone, however, is a flawed surrogate of river health. Hydrologic metrics that reflect chronic altered streamflows, for example, provide a direct mechanistic link between the changes associated with urban development and declines in stream biological condition. These measures provide a more sensitive understanding of stream basin response to urban development than do treatment of each increment of impervious area equally. Land use in residential backyards adjacent to streams also heavily influences stream condition. Successful stream rehabilitation thus requires coordinated diagnosis of the causes of degradation and integrative management to treat the range of ecological stressors within each urban area, and it depends on remedies appropriate at scales from backyards to regional storm water systems.     

Herbicide loading to shallow ground water beneath Nebraska's Management Systems Evaluation Area

Better management practices can counter deterioration of ground water quality. From 1991 through 1996 the influence of improved irrigation practices on ground water pesticide contamination was assessed at the Nebraska Management Systems Evaluation Area. Three 13.4-ha corn (Zea mays L.) fields were studied: a conventional furrow-irrigated field, a surge-irrigated field and a center pivot-irrigated field, and a center pivot-irrigated alfalfa (Medicago sativa L.) field. The corn fields received one identical banded application of Bicep (atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] + metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamidel) annually; the alfalfa field was untreated. Ground water samples were collected three times annually from 16 depths of 31 multilevel samplers. Six years of sample data indicated that a greater than 50% reduction in irrigation water on the corn management fields lowered average atrazine concentrations in the upper 1.5 m of the aquifer downgradient of the corn fields from approximately 5.5 to <0.5 microg L(-1). Increases in deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to atrazine molar ratios indicated that reducing water applications enhanced microbial degradation of atrazine in soil zones. The occurrence of peak herbicide loading in ground water was unpredictable but usually was associated with heavy precipitation within days of herbicide application. Focused recharge of storm runoff that ponded in the surge-irrigated field drainage ditch, in the upgradient road ditch, and at the downgradient end of the conventionally irrigated field was a major mechanism for vertical transport. Sprinkler irrigation technology limited areas for focused recharge and promoted significantly more soil microbial degradation of atrazine than furrow irrigation techniques and, thereby, improved ground water quality.     

Modelling trends in woody vegetation structure in semi-arid Australia as determined from aerial photography

Accounting of carbon stocks in woody vegetation for greenhouse purposes requires definition of medium term trends with accurate error assessment. Tree and shrub cover was sampled through time at randomly located sites over a large area of central Queensland, Australia using aerial photography from 1945 to 1999. Calibration models developed from field data for the same land types as those represented within the study area allowed for the extrapolation of overstorey and understorey cover, basal area and biomass values and these were modelled as trends over the latter half of the 20th century. These structural attributes have declined over the region because of land clearing with values for biomass changing from a mean of 58.0(+/-1.2)t/ha in 1953 to 41.1(+/-1.0)t/ha in 1991. The biomass of Acacia on clay and Eucalypt on texture contrast soils land types has declined most dramatically. Within uncleared vegetation there was an overall trend of increase from 56.1(+/-1.2)t/ha in 1951 to 67.6(+/-1.3)t/ha in 1995. The increase in structural attributes within uncleared vegetation was most pronounced for the Eucalypt on texture contrast soils and Eucalypt on clay land types. It was demonstrated that the sites sampled were representative of their land types and that spatial bias of the photography, undetected tree-killing, sampling error, inherent variability of structural attributes and measurement error should not have impacted greatly on bias or precision of trend estimates for well-sampled land types. Certainly the errors are not likely to be substantial for trends averaged over all land types and they provide an accurate assessment of the magnitude and direction of change. The technique presented here would appear to be a robust means of accounting for the above-ground woody component of woodlands and open forests and will also contribute to a broader understanding of savanna dynamics.     

Elements of resilience after the World Trade Center disaster: reconstituting New York City's Emergency Operations Centre

In this paper we examine the reconstitution of the Emergency Operations Centre (EOC) after its destruction in the World Trade Center attack, using that event to highlight several features of resilience. The paper summarises basic EOC functions, and then presents conceptions of resilience as understood from several disciplinary perspectives, noting that work in these fields has sought to understand how a natural or social system that experiences disturbance sustains its functional processes. We observe that, although the physical EOC facility was destroyed, the organisation that had been established to manage crises in New York City continued, enabling a response that drew on the resources of New York City and neighbouring communities, states and the federal government. Availability of resources--which substituted for redundancy of personnel, equipment and space--pre-existing relationships that eased communication challenges as the emergency developed and the continuation of organisational patterns of response integration and role assignments were among the factors that contributed to resilience following the attack.