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21.
Genevieve Obermeyer Sara M. Aschmann Roger Atkinson Janet Arey 《Atmospheric environment (Oxford, England : 1994)》2009,43(24):3736-3744
To convert gaseous carbonyls to oximes during sampling, an XAD-4 resin denuder system pre-coated with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine and followed by analysis with methane positive chemical ionization gas chromatography/mass spectrometry was used to measure carbonyls in ambient air samples in Riverside, CA. In conjunction with similar analyses of environmental chamber OH radical-initiated reactions of o- and p-xylene, 1,2,4-trimethylbenzene, ethylbenzene, 4-hydroxy-2-butanone and 1,4-butanediol, we identified benzaldehyde, o-, m- and p-tolualdehyde and acetophenone and the dicarbonyls glyoxal, methylglyoxal, biacetyl, ethylglyoxal, 1,4-butenedial, 3-hexene-2,5-dione, 3-oxo-butanal, 1,4-butanedial and malonaldehyde in the ambient air samples. As discussed, these carbonyls and dicarbonyls can be formed from the OH radical-initiated reactions of aromatic hydrocarbons and other volatile organic compounds emitted into the atmosphere, and we conclude that in situ atmospheric formation is a major source of these carbonyls in our Riverside, CA, ambient air samples. 相似文献
22.
Morris L. Maslia Mustafa M. Aral Robert C. Williams Allan S. Susten Janet L. Heitgerd 《Journal of the American Water Resources Association》1994,30(6):1025-1041
ABSTRACT: Simulation of ground-water flow and fate of contaminants in the subsurface environment constitutes a major phase of most environmental assessment and site remediation studies. These simulation studies yield information on spatial and temporal distributions of contaminants in the subsurface media. An important use of this information is to conduct exposure assessment studies. Spatial and temporal distributions of both chemical concentrations and exposed populations render this integrated exposure analysis task rather difficult. Geographic Information Systems (GIS), on the other hand, provide a platform in which layered, spatially distributed databases can be manipulated with ease, thereby simplifying exposure analysis tasks significantly. In this paper, we describe procedures that combine the simulation models and demographic databases under a GIS platform to automate the exposure assessment phase of a typical health assessment study. Procedures developed herein significantly simplify the post-processing phase of the analysis, and render the overall task more ‘user friendly.’ A site-specific application is included as a demonstration of the proposed process. 相似文献
23.
Terrie K. Boguski Robert G. Hunt William E. Franklin 《Resources, Conservation and Recycling》1994,12(3-4)
Life cycle inventory (LCI) is becoming more widely used as a tool to evaluate the resource and energy use and the environmental releases associated with various products. The methodology for handling different recycling scenarios is also becoming increasingly important. Several different methods exist for handling recycling in an LCI. The method described in this paper uses mathematical models to show that the same basic equations can be used to handle a variety of recycling options for multi-product systems. 相似文献
24.
Clay L. Montague Alexander V. Zale H. Franklin Percival 《Environmental management》1987,11(6):743-756
Many coastal resource managers believe estuarine marshes are critically important to estuarine fish and shellfish, not only because of the habitat present for juvenile stages, but also because of the export of detritus and plant nutrients that are consumed in the estuary. Concern has been widely expressed that diking and flooding marshes (impounding) for mosquito control and waterfowl management interferes with these values of marshes. Major changes caused by impoundment include an increase in water level, a decrease in salinity, and a decrease in the exchange of marsh water with estuarine water. Alteration of species composition is dramatic after impoundment. Changes in overall production and transport phenomena, however—and the consequences of these changes— may not be as great in some cases as the concern about these has implied. Although few data are available, a more important concern may be the reduction of access by estuarine fish and shellfish to the abundant foods and cover available in many natural, as well as impounded, marshes. Perhaps even more important is the occasional removal of free access to open water when conditions become unfavorable in impounded marsh that is periodically opened and closed. Collection of comparative data on the estuarine animal use of various configurations of natural and impounded marshes by estuarine animals should lead to improved management of both impounded and unimpounded marshes. 相似文献
25.
Sheryl L. Franklin David R. Maidment 《Journal of the American Water Resources Association》1986,22(4):611-621
ABSTRACT: A cascade model for forecasting municipal water use one week or one month ahead, conditioned on rainfall estimates, is presented and evaluated. The model comprises four components: long term trend, seasonal cycle, autocorrelation and correlation with rainfall. The increased forecast accuracy obtained by the addition of each component is evaluated. The City of Deerfield Beach, Florida, is used as the application example with the calibration period from 1976–1980 and the forecast period the drought year of 1981. Forecast accuracy is measured by the average absolute relative error (AARE, the average absolute value of the difference between actual and forecasted use, divided by the actual use). A benchmark forecast is calculated by assuming that water use for a given week or month in 1981 is the same as the average for the corresponding period from 1976 to 1980. This method produces an AARE of 14.6 percent for one step ahead forecasts of monthly data and 15.8 percent for weekly data. A cascade model using trend, seasonality and autocorrelation produces forecasts with AARE of about 12 percent for both monthly and weekly data while adding a linear relationship of water use and rainfall reduces the AARE to 8 percent in both cases if it is assumed that rainfall is known during the forecast period. Simple rainfall predictions do not increase the forecast accuracy for water use so the major utility of relating water use and rainfall lies in forecasting various possible water use sequences conditioned on sequences of historical rainfall data. 相似文献
26.
Eric C. Schuck Gareth P. Green Janet Clements W. Marshall Frasier 《Journal of the American Water Resources Association》2006,42(6):1483-1492
Abstract: Agricultural runoff, such as dissolved mineral salts and selenium, creates pronounced downstream impacts to agricultural producers and to wildlife. The ability to manage these problems efficiently depends critically on the institutional pricing structure of irrigation water delivery agencies. An important characteristic of irrigation water delivery is whether irrigators pay per unit of water received or make one payment regardless of the quantity of water received. In this study we compare the effectiveness of agricultural runoff reduction policies in two regions that employ these different water pricing structures. We find that reduction policy is more effective and can be achieved at a lower cost when water is priced on a per unit basis and that growers have greater incentive to act on their own to reduce runoff problems. Operating under a per unit pricing system encourages water conservation and runoff reduction, which creates public benefits that are not achieved under the single-payment, fixed allotment method of irrigation water delivery. 相似文献
27.
Joseph C. Rode Christine H. Mooney Marne L. Arthaud‐Day Janet P. Near Timothy T. Baldwin Robert S. Rubin William H. Bommer 《组织行为杂志》2007,28(4):399-421
We examined the direct and moderated effects of an ability‐based measure of emotional intelligence (MSCEIT© V2.0) on individual performance in a sample of business undergraduates. Controlling for general mental ability and personality, emotional intelligence explained unique incremental variance in performance ratings on only one of two measures of interpersonal effectiveness (public speaking effectiveness). However, the interaction of emotional intelligence with conscientiousness explained unique incremental variance both in public speaking and group behavior effectiveness, as well as academic performance (cumulative GPA). We conclude that the effects of emotional intelligence on performance are more indirect than direct in nature. Individuals must not only have emotional intelligence, but also must be motivated to use it. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
28.
S. Taku Ide Kristian Jessen Franklin M. Orr Jr. 《International Journal of Greenhouse Gas Control》2007,1(4):481-491
CO2 can be effectively immobilized during CO2 injection into saline aquifers by residual trapping – also known as capillary trapping – a process resulting from capillary snap-off of isolated CO2 bubbles. Simulations of CO2 injection were performed to investigate the interplay of viscous and gravity forces and capillary trapping of CO2. Results of those simulations show that gas injection processes in which gravitational forces are weak compared to viscous forces (low gravity number Ngv) trap significantly more CO2 than do flows with strong gravitational forces relative to the viscous forces (high Ngv). The results also indicate that over a wide range of gravity numbers (Ngv), significant fractions of the trapping of CO2 can occur relatively quickly. The amount of CO2 that is trapped after injection ceases is demonstrated to correlate with Ngv. For some simulated displacements, effects of capillary pressure and aquifer dip angle on the amount and the rate of trapping are reported. Trapping increases when effects of capillary pressure and aquifer inclination are included in the model. Finally we show that injection schemes such as alternating injection of brine and CO2 or brine injection after CO2 injection can also enhance the trapping behavior. 相似文献
29.
Jerry F. Franklin 《Environmental management》1979,3(1):2-5
Simulation models are becoming increasingly important as tools for synthesizing and applying information in almost all aspects of land management. They are particulary valuable for predicting and comparing outcomes of alternative decisions and assumptions. Models also permit managers to consider and integrate the potential influences of a large number of variables. 相似文献
30.
Franklin H. Jackson 《Journal of the American Water Resources Association》1981,17(2):301-306
ABSTRACT: A method of project planning for systematically assessing and recording impacts of alternative timber harvest startegies for subareas of a sale planning area is presented. This method uses an interdisciplinary team composed of specialists and decisionmaker to develop and analyze treatment alternatives and uses impact prediction matrices with explicit evaluation criteria to illustrate and record ratings of impacts on resource factors. The method is a system for organizing, for discovering appropriate alternatives, for facilitating interaction, and for documenting environmental analysis. It provides for decisionmaker control over the project, for exchange of value perspectives, and for reduction in conflict between specialists. The quality of decisions which result from the method presented depends upon the information available and the effectiveness of interaction between all members of the interdisciplinary team. 相似文献