A method of detecting carbonyl compounds in tree leaves in China

Background, aim, and scope  

Carbonyl compounds have been paid more and more attention because some carbonyl species have been proven to be carcinogenic or a risk for human health. Plant leaves are both an important emission source and an important sink of carbonyl compounds. But the research on carbonyl compounds from plant leaves is very scarce. In order to make an approach to the emission mechanism of plant leaves, a new method was established to extract carbonyl compounds from fresh plant leaves.     

产业结构演变的流域水环境响应研究——以社渎港流域为例

以太湖15个入湖河流之一的社渎港为研究对象,利用社渎港流域的水环境质量监测数据、工业企业污染排放调查数据、环境统计数据及社会经济统计数据,对社渎港流域产业结构的合理性进行了诊断,并采用典型相关分析方法探讨了产业结构演变对水环境的影响。结果表明,研究区的工业污染总体上得到了较好控制,其中屺亭街道的工业污染排放最为严重;城乡生活污染和农业面源污染是研究区水环境质量恶化的主要原因,城乡生活污染对COD和氨氮入河量的贡献率较高,分别为46.59%和60.55%,农业面源污染对TN和TP入河量的贡献率突出,分别为64.05%和76.50%;研究区产业结构与钱纳里三次产业结构模式(产业结构合理程度的参照标准)的Hamming贴近度从2001年的0.83下降到2007年的0.77,产业结构不尽合理,且不合理程度逐渐加剧;研究区第一产业对TN和TP入河量的影响最为显著,第三产业对氨氮和COD入河量的影响最为明显;可通过优化产业结构来减轻研究区的水环境污染状况,产业结构调整的主要目标应为降低第二产业产值比例及增加第三产业产值比例。     

贫营养异养硝化细菌的分离鉴定及硝化性能研究

从水库底泥中分离出1株贫营养异养硝化细菌,命名为菌株Y11。经菌株生理特性研究和16SrDNA测序,鉴定出菌株Y11属于假单胞菌属细菌(Pseudomonas sp.)。考察了温度、pH及C/N对菌株Y11的硝化性能影响,结果表明,菌株Y11进行硝化作用的最适温度为30℃,最适pH为中性,最适C/N为6.0,在该条件下进行4d的硝化反应,菌株Y11对氨氮去除率可达91.42%。     

水解酸化-A2O污泥减量工艺的运行性能研究

生物处理单元采用水解酸化、多级串联接触曝气、连续流的除磷脱氮A2／O工艺,并辅以外排厌氧富磷污水侧流除磷,开发了一个新型的具有强化除磷脱氮功能的污泥减量HA—A／A—MCO工艺。用该工艺处理校园生活污水发现,在SRT60d、进水COD316～407mg／L、NH4＋-N30～40mg／L、TN35～53mg／L、TP8—12mg／L的条件下,出水COD≤18mg／L、NH4＋-N≤2．1mg／L、TN≤10．3mg／L、TP≤0．44mg／L。研究还发现,水解酸化池处理产生的VFA能有效促进生物除磷脱氮,导致厌氧释磷量达57mg／L,进入化学除磷池的侧流液量仅相当于进水量的13％;系统最主要的脱氮形式是SND和缺氧反硝化,SND脱氮占脱氮总量的50％,缺氧反硝化占26％;HA-A／A—MCO系统有效实现了生物相分离,并利用生物捕食作用获得较低的污泥产率,0．1gMLSS／gCOD。     

中小型工业窑炉NOx废气的净化技术与应用

介绍了中小型工业窑炉生产过程中排放NOx的现状,并针对NOx的治理问题,从工程应用角度,简述了湿法和干法净化NOx的原理和化学反应过程。讨论了NOx排放特性和NOx废气中NO2/NOx比例的问题。提出了影响NOx治理的主要因素,包括吸收剂、吸附剂、催化剂和设备的部分应用参数,并结合工程实例指出工程需要注意的问题。介绍了多项采用湿法和干法净化NOx的工程应用项目,丰富了中小工业窑炉NOx废气的治理的实践经验,为中小工业窑炉排放NOx治理奠定了基础。     

Carbon dioxide and methane fluxes in the littoral zones of two lakes,east Antarctica

During the summertime of 2007/2008, carbon dioxide (CO₂) and methane (CH₄) fluxes across air–water interface were investigated in the littoral zones of Lake Mochou and Lake Tuanjie, east Antarctica, using a static chamber technique. The mean fluxes of CO₂ and CH₄ were ?70.8 mgCO₂ m^?2 h^?1 and 144.6 μgCH₄ m^?2 h^?1, respectively, in the littoral zone of Lake Mochou; The mean fluxes were ?36.9 mgCO₂ m^?2 h^?1 and 109.8 μgCH₄ m^?2 h^?1, respectively, in the littoral zone of Lake Tuanjie. Their fluxes showed large temporal and spatial dynamics. The CO₂ fluxes showed a significantly negative correlation with daily total radiation (DTR) and a weakly negative correlation with air temperature and water temperature, indicating that sunlight intensity controlled the magnitude of CO₂ fluxes from the open lakes. The CH₄ fluxes significantly correlated with local air temperature, water table and total dissolved solids (TDS), indicating that they were the predominant factors influencing CH₄ fluxes. Summertime CO₂ budgets in the littoral zones of Lake Mochou and Lake Tuanjie were estimated to be ?152.9 gCO₂ m^?2 and ?79.7 gCO₂ m^?2, respectively, and net CH₄ emissions were estimated to be 312.3 mgCH₄ m^?2 and 237.2 mgCH₄ m^?2, respectively. Our results show that shallow, open, alga-rich lakes might be strong summertime CO₂ absorbers and small CH₄ emitters during the open water in coastal Antarctica.     

A 3D aerosol and visibility information system for urban areas using remote sensing and GIS

Currently, the depiction of urban air quality at boundary layer scale uses modelled climatic and land cover data. However, such models are difficult to verify, and only low to moderate accuracy may be achieved due to the complexity of the input data required and the reliance on assumptions about dispersion patterns. The provision of comprehensive air quality data to urban residents in city districts, at a level of detail commensurate with other Location-Based Services (LBS) which are time- and place-sensitive, has therefore not been possible. A method for urban air quality monitoring over cities at boundary layer scale, other than by the use of air quality models is presented here. The system presented uses empirical Aerosol Optical Thickness (AOT) data in near-real time, combining AOT data from AERONET with aerosol vertical profiles computed from twice-daily MODIS satellite images at 500 m resolution, to give three dimensional (3D) air quality data over the urban landscape. There has been no previous attempt to project the horizontal spatial distribution of aerosols from satellite image pixels into a vertical dimension to give a spatially comprehensive three dimensional record of air quality. The paper describes the sources and accuracy of the AOT data input to the system as well as its storage and retrieval on a Geographic Information System (GIS) platform, to provide air quality and visibility information according to user query at any 3D geographical location, including individual buildings or building floor.     

铁炭复配修复地下水中NO_3~--N的条件研究

采用了铁炭复配修复地下水中NO3--N,探讨了实验条件对修复效果的影响。结果表明,在pH值近中性条件(初始pH 6.42)下,反应时间为1 h时NO3--N修复率达到60.85%;Fe/C=1∶1时介质最佳用量分别为4~5 g;Fe/C=1/1.5时修复率为72.80%;反应速率在高振荡强度下大于低振荡强度;氧化铜的催化效果最好,可使修复率提高7.5个百分点。铁炭复配介质修复地下水中NO3--N是有效可行的,修复率随反应时间的增加而提高,在Fe/C=1∶1时修复率与介质用量呈正相关,无限减小Fe/C比并不能无限提高修复率,振荡强度对修复具有显著影响,低振荡强度下的修复过程较高强度存在滞后现象,并非所有金属氧化物催化剂对铁炭修复NO3--N均有促进作用。     

厌氧氨氧化ASBR中亚硝氮和氨氮降解规律研究

采用生物膜ASBR反应器,研究了厌氧氨氧化反应过程中亚硝氮与氨氮降解速度的变化规律。结果表明,降解过程主要分为2个阶段:速度上升期(0~30 min)和速度下降期(30~150 min)。一阶指数衰减模型的模拟结果表明,20 min以后亚硝氮、氨氮降解速度逐渐减少,亚硝氮降解速度始终高于氨氮降解速度,但是两者差值随时间逐渐减少。     

介质阻挡放电联合催化臭氧化降解甲苯

采用介质阻挡放电区后结合MnOx/Al2O3/发泡镍去除甲苯,考察甲苯进气方式、臭氧产生方法及湿度对甲苯与O3同时去除的影响。结果表明,O3是等离子体区后催化降解甲苯的主要物种,介质阻挡放电联合催化臭氧化可实现甲苯及O3的同时高效去除。输入电压为9.0 kV时,甲苯的去除效率达92.8%,在80 min内O3的去除效率维持在99%以上。水蒸气对催化剂催化分解臭氧的活性没有直接的影响,O3浓度较高时湿度对甲苯降解效率的影响很小。GC-MS分析结果表明,甲苯降解的主要气相副产物有烷烃、酸、酮和含苯环有机物,提出了甲苯的降解途径。