Net impact of remediation

Following years of progress in designing and executing cleanups of contaminants at waste sites, the U.S. Air Force, state regulatory groups, and others are crafting methods to evaluate broader considerations of risk in remedial decisions. Integrating worker and climate risks into remediation efforts may confer significant benefits, but challenges exist to identifying, assessing, and accounting for them in the remedial process. For sites where future risk posed by contamination far exceeds the risk posed to workers who may be exposed to the contaminants during the remedial process, limiting the range of decision inputs to those presented by the site conditions made sense and provided a net benefit to human health and the environment. There are other sites, however, where future risk posed by the in situ contamination are at levels comparable to the real risks posed to workers, ecology, and even emerging concerns about climate change. For these sites, a net risk reduction cannot be assumed to be a result of remedial action, challenging the remedial community to develop new approaches to ensure positive results. © 2009 Wiley Periodicals, Inc.     

National and regional determinants of tropical deforestation in Colombia

Global tropical deforestation continues to occur at high rates despite political attention. National-level forest baselines are being established all over the world to guide the implementation of several policy mechanisms. However, identifying the direct and indirect drivers of deforestation and understanding the complexity of their interlinkages are often difficult. We first analyzed deforestation between 1990 and 2005 at the national level and found an annual deforestation rate of 0.62 %. Next, we performed separate analyses for four natural regions in Colombia and found annual deforestation rates between 0.42 and 1.92 %. Using general linear models, we identified several direct causes and underlying factors influencing deforestation at the national level: rural population density, cattle, protected areas, and slope. Significant differences in deforestation rates and causes were found across regions. In the Caribbean region, drivers of loss are urban population, unsatisfied basic needs, slope, and precipitation and four land use variables (illicit crops, pastures, cattle, and fires). In the Orinoco region, crops are the main driver of forest loss, and in the Amazonian region, deforestation is primarily due to fires related to the colonization front. Policy mechanisms will have to take into account regional patterns to successfully balance development and forest preservation in Colombia.     

Understanding the processes in a historically relevant thermal and mineral spring water by using mixing and inverse geochemical models

Environmental Geochemistry and Health - The thermal mineral water of Peñón de los Baños spa (Mexico City) has been used for over 500 years starting in pre-Hispanic times and...     

Batch and continuous adsorption of Cu(II) and Zn(II) ions from aqueous solution on bi-functionalized sugarcane-based biosorbent

Environmental Science and Pollution Research - A new one-pot synthesis method optimized by a 23 experimental design was developed to prepare a biosorbent, sugarcane bagasse cellulose succinate...     

Large-scale modeling of reactive solute transport in fracture zones of granitic bedrocks

Final disposal of high-level radioactive waste in deep repositories located in fractured granite formations is being considered by several countries. The assessment of the safety of such repositories requires using numerical models of groundwater flow, solute transport and chemical processes. These models are being developed from data and knowledge gained from in situ experiments such as the Redox Zone Experiment carried out at the underground laboratory of Äspö in Sweden. This experiment aimed at evaluating the effects of the construction of the access tunnel on the hydrogeological and hydrochemical conditions of a fracture zone intersected by the tunnel. Most chemical species showed dilution trends except for bicarbonate and sulphate which unexpectedly increased with time. Molinero and Samper [Molinero, J. and Samper, J. Groundwater flow and solute transport in fracture zones: an improved model for a large-scale field experiment at Äspö (Sweden). J. Hydraul. Res., 42, Extra Issue, 157–172] presented a two-dimensional water flow and solute transport finite element model which reproduced measured drawdowns and dilution curves of conservative species. Here we extend their model by using a reactive transport which accounts for aqueous complexation, acid–base, redox processes, dissolution–precipitation of calcite, quartz, hematite and pyrite, and cation exchange between Na⁺ and Ca²⁺. The model provides field-scale estimates of cation exchange capacity of the fracture zone and redox potential of groundwater recharge. It serves also to identify the mineral phases controlling the solubility of iron. In addition, the model is useful to test the relevance of several geochemical processes. Model results rule out calcite dissolution as the process causing the increase in bicarbonate concentration and reject the following possible sources of sulphate: (1) pyrite dissolution, (2) leaching of alkaline sulphate-rich waters from a nearby rock landfill and (3) dissolution of iron monosulphides contained in Baltic seafloor sediments. Based on these results, microbially mediated processes are postulated as the most likely hypothesis to explain the measured increase of dissolved bicarbonates and sulphates after tunnel construction.     

Plant-Mammal Interactions in Tropical Bolivian Forests with Different Hunting Pressures

Abstract: We studied plant-animal interactions and vegetation structure in two geographically close tropical Bolivian forests subjected to different hunting intensities. We hypothesized that reduction of mammals openface> 1 kg in an "intensively hunted forest," compared with an "occasionally hunted forest," should correlate with decreased seed predation and seedling trampling, increased seedling survival and density, and decreased tree-species diversity at the seedling stage in relation to the adult stage. The occasionally hunted forest held 1.7 times as many mammalian species as the intensively hunted forest. As predicted, predation of Astrocaryum murumuru seeds was 34.2% lower in the intensively hunted forest. Similarly, trampling of model seedlings was 5.4 times lower and seedling survival was 1.15 times greater in the intensively hunted forest than that in the occasionally hunted forest. But the intensively hunted forest displayed lower seedling densities and a higher ratio of seedling diversity to tree diversity than did the occasionally hunted forest. Reduction of peccaries from the intensively hunted forest may explain much of the between-site differences in seed predation, trampling, and seedling survival. Lack of consistent differences in seedling density and diversity could mean that reduced granivory and trampling may be counteracted by reduced seed dispersal. The reduction of mammalian populations may produce a complex mosaic of forest patches with distinct degrees of structural change, depending on the intensity of defaunation.     

Two- and three-dimensional ultrasound in malformations of the medullary canal: report of four cases

A comparison between two-dimensional (2D), and three-dimensional (3D) ultrasonography was made in four fetuses diagnosed with neural tube defect (NTD) in the first half of pregnancy. 3D ultrasonography (orthogonal and multiplanar systems) proved to be an excellent complement to 2D, particularly when using orthogonal planes. When using the 3D multiplanar surface imaging system, excellent images of the malformations can be rapidly obtained. Copyright © 2001 John Wiley & Sons, Ltd.     

Preventive activity in the greenhouse-construction industry of south-eastern Spain

Preventive action in companies is one of the bases of ergonomic intervention. Therefore, in the present work, the preventive activity of greenhouse-construction companies in south-eastern Spain is characterized. A sample was taken by means of a questionnaire structured in four groups of variables: general characteristics of the company, characteristics of safety and health in the construction procedures, characteristics of prevention and management in safety and health, and characteristics of the coordination during the execution of the work. The results indicate that the prevention is very poor, not adopting any preventive-management model for internationally recognized work hazards so that the information and training in preventive matters of companies and workers is insufficient. In addition, the companies have been classified into three clusters, correlating the company size and prevention management of labour hazards, revealing that the companies with higher gross income and number of workers showed better prevention management.     

Fire hazard after prescribed burning in a gorse shrubland: implications for fuel management

Prescribed burning is commonly used to prevent accumulation of biomass in fire-prone shrubland in NW Spain. However, there is a lack of knowledge about the efficacy of the technique in reducing fire hazard in these ecosystems. Fire hazard in burned shrubland areas will depend on the initial capacity of woody vegetation to recover and on the fine ground fuels existing after fire. To explore the effect that time since burning has on fire hazard, experimental tests were performed with two fuel complexes (fine ground fuels and regenerated shrubs) resulting from previous prescribed burnings conducted in a gorse shrubland (Ulex europaeus L.) one, three and five years earlier. A point-ignition source was used in burning experiments to assess ignition and initial propagation success separately for each fuel complex. The effect of wind speed was also studied for shrub fuels, and several flammability parameters were measured. Results showed that both ignition and initial propagation success of fine ground fuels mainly depended on fuel depth and were independent of time since burning, although flammability parameters indicated higher fire hazard three years after burning. In contrast, time since burning increased ignition and initial propagation success of regenerated shrub fuels, as well as the flammability parameters assessed, but wind speed had no significant effect. The combination of results of fire hazard for fine ground fuels and regenerated shrubs according to the variation in relative coverage of each fuel type after prescribed burning enabled an assessment of integrated fire hazard in treated areas. The present results suggest that prescribed burning is a very effective technique to reduce fire hazard in the study area, but that fire hazard will be significantly increased by the third year after burning. These results are valuable for fire prevention and fuel management planning in gorse shrubland areas.