Effects of Fuel Type,Driving Cycle,and Emission Status on In-Use Vehicle Exhaust Reactivity

ABSTRACT

The introduction of reformulated gasolines significantly reduced exhaust hydrocarbon (HC) mass emissions, but few data are available concerning how these new fuels affect exhaust reactivity. Similarly, while it is well established that high-emitting vehicles contribute a significant portion of total mobile source HC mass emissions, it is also important to evaluate the exhaust reactivity from these vehicles. The objective of this study was to evaluate the relative influence on in-use vehicle exhaust reactivity of three critical factors: fuel, driving cycle, and vehicle emission status. Nineteen in-use vehicles were tested with seven randomly assigned fuel types and two driving cycles: the Federal Test Procedure (FTP) and the Unified Cycle (UC). Total exhaust reactivity was not statistically different between the FTP and UC cycles but was significantly affected by fuel type. On average, the exhaust reactivity for California Phase 2 fuel was the lowest (16 % below the highest fuel type) among the seven fuels tested for cold start emissions. The average exhaust reactivity for high-emitting vehicles was significantly higher for hot stabilized (11%) and hot start (15%) emissions than for low-emitting vehicles. The exhaust reactivities for the FTP and UC cycles for light-end HCs and carbonyls were significantly different for the hot stabilized mode. There was a significant fuel effect on the mean specific reactivity (SR) for the mid-range HCs, but not for light-end HCs or carbonyls, while vehicle emission status affected the mean SR for all three HC compound classes.     

Metal release from bottom sediments of Ocoee Lake No. 3, a primary catchment area for the Ducktown Mining District

Ocoee Lake No. 3 is the first reservoir receiving suspended sediments contaminated with trace metals discharged by acid mine effluents from the Ducktown Mining District, Tennessee. Bottom sediments (0-5 cm) from the lake were sampled to assess the potential for future adverse environmental effects if no remediation controls or activities are implemented. The sediments were found to include a major component (173 +/- 19 g kg(-1)) that dissolved in 6 mol L(-1) HCl within 24 h. This acid-soluble and relatively labile fraction contained high concentrations of Fe (460 +/- 40 g kg(-1)), Al (99 +/- 11 g kg(-1)), Mn (10 +/- 8 g kg(-1)), Cu (2000 +/- 700 mg kg(-1)), Zn (1300 +/- 200 mg kg(-1)), and Pb (300 +/- 200 mg kg(-1)). When the pH of water in contact with the sediment was decreased experimentally from 6.4 to 2.6, the concentrations of dissolved trace metals increased by factors of 2200 for Pb, 160 for Cu, 21 for Zn, 9 for Cd, 8 for Ni, and 5 for Co. The order in which metals were released with decreasing pH was the reverse of that reported for pH-dependent sorption of these metals in upstream systems. Substantial release of trace metals from the sediment was observed even by a modest decrease of pH from 6.4 to 5.9. Therefore, the metal-rich sediment of the lake should be considered as potentially hazardous to bottom-dwelling aquatic species and other organisms in the local food chain. In addition, if the reservoir is dredged or if the dam is removed, the accumulated sediment may have to be treated for recovery of sorbed metals.     

EPIC modeling of soil organic carbon sequestration in croplands of Iowa

Depending on management, soil organic carbon (SOC) is a potential source or sink for atmospheric CO(2). We used the EPIC model to study impacts of soil and crop management on SOC in corn (Zea mays L.) and soybean (Glycine max L. Merr.) croplands of Iowa. The National Agricultural Statistics Service crops classification maps were used to identify corn-soybean areas. Soil properties were obtained from a combination of SSURGO and STATSGO databases. Daily weather variables were obtained from first order meteorological stations in Iowa and neighboring states. Data on crop management, fertilizer application and tillage were obtained from publicly available databases maintained by the NRCS, USDA-Economic Research Service (ERS), and Conservation Technology Information Center. The EPIC model accurately simulated state averages of crop yields during 1970-2005 (R(2) = 0.87). Simulated SOC explained 75% of the variation in measured SOC. With current trends in conservation tillage adoption, total stock of SOC (0-20 cm) is predicted to reach 506 Tg by 2019, representing an increase of 28 Tg with respect to 1980. In contrast, when the whole soil profile was considered, EPIC estimated a decrease of SOC stocks with time, from 1835 Tg in 1980 to 1771 Tg in 2019. Hence, soil depth considered for calculations is an important factor that needs further investigation. Soil organic C sequestration rates (0-20 cm) were estimated at 0.50 to 0.63 Mg ha(-1) yr(-1) depending on climate and soil conditions. Overall, combining land use maps with EPIC proved valid for predicting impacts of management practices on SOC. However, more data on spatial and temporal variation in SOC are needed to improve model calibration and validation.     

Perfluorinated compounds in whole fish homogenates from the Ohio, Missouri, and Upper Mississippi Rivers, USA

A method for the analysis of 10 perfluorinated compounds (PFCs) in whole fish homogenate is presented and applied to 60 fish samples collected from the Ohio, Missouri, and upper Mississippi Rivers in 2005. Method accuracy ranged between 86 and 125% with limits of quantitation between 0.2 and 10 ng/g wet weight. Intra- and inter-batch precision was generally ±20%. Perfluorooctane sulfonate (PFOS) was the predominant compound identified in these samples, contributing over 80% of total PFC composition in the fish from these rivers, with median PFOS concentrations of 24.4, 31.8, and 53.9 ng/g wet wt in the Missouri, Ohio, and Mississippi Rivers, respectively. Median PFOS levels were significantly (p = 0.01) elevated in piscivorous fish (88.0 ng/g) when compared with non-piscivorous fish (15.9 ng/g). The 10 samples with PFOS concentrations above 200 ng/g were broadly scattered across all three rivers, providing evidence of the widespread presence of this compound in these US waterways.     

International commodity transactions : The role of the commodity futures trading commission

The creation of so-called ‘financial’ futures contracts in the USA has spurred the growth of futures trading by other countries, including the UK. The increased expansion of commodity futures trading has also led to heightened regulatory concerns throughout the world. The USA has been especially aggressive in asserting jurisdiction and establishing regulatory controls over persons dealing in the US markets. The complexity of the regulations adopted is compounded by the fact that they are often directed at specific instruments, while similar instruments are not given comparable regulatory treatment. This article discusses the growth of futures trading worldwide, as well as regulatory concerns and requirements existing in the USA.     

Effects of workplace thermal conditions on safe work behavior

The effect of workplace thermal conditions on worker safety has not previously been adequately investigated, due in part to the difficulty of defining a suitable safety performance measure. This report describes a study conducted in two industrial plants to determine if a correlation exists between the safety-related behavior of workers and workplace thermal conditions. Both heat exposure measurements and behavioral observations were taken over a 14-month period, for a total of over 17,000 observations. The results indicate that temperatures below and above those typically preferred by most people have a significantly detrimental effect on the safety-related behavior of workers. This is demonstrated by an index based on the ratio of observed unsafe behaviors to the total number of observed behaviors. The relationship between this index of unsafe behavior and the ambient temperature formed a U-shaped curve. The minimum unsafe behavior index occurred within the zone of preferred temperature (approximately 17°C to 23°C, WBGT). Other factors such as metabolic workload and time during the shift also had significant effects on worker safety-related behavior.     

A COMPARISON OF THREE METHODS FOR MEASURING RECENT RATES OF SEDIMENT ACCUMULATION1

ABSTRACT: The determination of sediment accumulation rates is important in understanding how these materials are affecting lakes and reservoirs ecosystems. In this study three methods were used to estimate sediment accumulation rates in the impounded backwater lakes behind Lock and Dam Nos. 8 and 9 on the upper Mississippi River. The three methods were: 1) a “spud” survey, 2) a survey of bottom contours, and 3) the use of fallout cesium-137. The field use of these three methods of determining sediment accumulation and the potential errors and merits involved in each method are discussed. The results from the field study in backwater areas along the upper Mississippi River showed the survey of bottom contour method gave the lowest rate of sediment deposition and the ¹³⁷Cs method gave the highest rates. Sediment accumulation rates from 0 to 7.8 cm per year were measured in the study area. All three methods are useful and have unique characteristics for determining rates and patterns of sediment accumulation. Thus the choice of a method to be used in a sediment survey is dependent on the type of information needed and the time available.     

Six-phase heating™: The new power tool

The removal of dense non-aqueous phase liquids (DNAPL) in-situ remains one of the remediation industry's toughest burden. Numerous treatment methods have been applied in an effort to deal with this problem, most requiring many years of continued application to produce even marginally successful results. Current Environment Solutions (CES) has brought a new technology, known as Six-Phase Heating? (SPH), to bear on this problem. This new technology is proving capable of providing rapid remediation of DNAPL-contaminated sites at reasonable costs.     

Derivative mine valuation: strategic investment decisions in competitive markets

Successful management in competitive markets requires evaluation methods that respond to global market dynamics and provide investors with relevant information to make strategic investment decisions. These strategic decisions include decisions on investment timing, feasibility study and risk management and mine operating options. Conventional methods do not have the built-in capabilities to help investors handle these strategic issues. Advances in modern finance have had profound impacts on financial markets for options, futures and collaterized securities and offer appropriate tools in solving these problems. In this paper, the authors have extended the Brennan and Schwartz mineral resource model to develop the derivative mine valuation method based on the dynamic arbitrage theory. A copper mining venture has been evaluated using the derivative mine valuation and conventional methods. The results show that the derivative mine valuation method allows investors to maximize the venture's market value by exercising these strategic options.