Historical reconstruction of atmospheric lead pollution in central Yunnan province, southwest China: an analysis based on lacustrine sedimentary records

Atmospheric lead (Pb) pollution during the last century in central Yunnan province, one of the largest non-ferrous metal production centers in China, was reconstructed using sediment cores collected from Fuxian and Qingshui Lakes. Lead concentrations and isotopic ratios (²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb) were measured in sediment cores from both lakes. The operationally defined chemical fractions of Pb in sediment core from Fuxian Lake were determined by the optimized BCR procedure. The chronology of the cores was reconstructed using ²¹⁰Pb and ¹³⁷Cs dating methods. Similar three-phase variations in isotopic ratios and enrichment factors of Pb were observed in the sediment cores from both lakes. Before the 1950s, the sediment data showed low ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios and enrichment factors (EFs?=?~1), indicating that the sedimentary Pb was predominantly of lithogenic origin. However, these indices were increased gradually between the 1950s and the mid-1980s, implying an atmospheric Pb deposition. The EFs and isotopic ratios of Pb reached their peak during recent years, indicating aggravating atmospheric Pb pollution. The average anthropogenic Pb fluxes since the mid-1980s were estimated to be 0.032 and 0.053 g m^?2 year^?1 recorded in Fuxian and Qingshui cores, respectively. The anthropogenic Pb was primarily concentrated in the reducible fraction. Combining the results of Pb isotopic compositions and chemical speciations in the sediment cores and in potential sources, we deduced that recent aggravating atmospheric Pb pollution in central Yunnan province should primarily be attributed to regional emissions from non-ferrous metal production industries.     

电解-水生植物-软隔离带复合技术治理重污染河流的中试研究

为了探索重污染河流的治理技术,2011年3月在无锡市新区鸿山镇徐塘桥河开展生态治理示范工程,通过电解技术、种植高等水生植物和构建软隔离带复合工程技术改善河流水质。实验结果表明,通过电解技术,可以迅速降低TP、氨氮（NH4＋-N）和COD;但较难减少TN。通过软隔离带可以有效隔离外源污染,在较短时间内改善河流TN、TP、COD的平均水平,但是难以提高河流的生态系统稳定性。电解能够有效的降解大分子有机物,为水生植物提供良好的生长环境,之后再种植水生植物,能够进一步降低的TN、TP。通过电解一水生植物一软隔离带复合技术不仅能够全面改善河流水质的平均水平,而且能够修复水生生态系统,提高生态系统稳定性。     

浙东四明山红色旅游目的地的开发与建设

通过四明山红色旅游目的地开发建设的优势、机遇及劣势与挑战的分析,提出了开发与建设四明山红色旅游目的地的六大策略,即政府主导与市场运作相结合的开发策略、社会效益和经济效益兼顾的开发策略、红色旅游目的地品牌策略、"红绿结合"的开发策略、区域合作策略、基于和谐旅游发展的开发策略。     

油气集输站安全监控预警及管理信息系统的开发

提出油气集输站安全监控预警及管理信息系统建设的调研内容、需求分析以及安全相关控制系统的风险分析流程。设计了该系统建设的4层结构框架和拓扑图,深入研究了实时参数监控、分级报警与安全保护控制、智能诊断与预警、多媒体监控、安全生产管理信息子系统的主要开发内容和功能实现。     

考虑人为因素的可靠性评估

统计数据表明,系统的可靠运行不可忽略人为误操作造成的故障,该故障发生率有时甚至超过设备本身导致的系统故障发生率。将人为因素与设备自身因素造成的系统故障进行对比,分析人为因素造成系统故障后的特点,可得出人为因素的可靠性参数。根据解析法和模拟法的相关理论计算考虑人为因素的可靠性指标,可以看出考虑人为因素的计算结果更加符合实际运行特点,便于相关人员采取对策,保障系统的安全运行。     

橡胶促进剂M盐废水生物处理技术研究

为探讨微生物技术在橡胶促进剂M盐废水处理中的应用,利用高效优势蘸强化A2O工艺对橡胶促进剂M盐废水进行处理,整个系统运行过程分为污泥的培养与驯化阶段及稳定运行阶段。在稳定运行阶段COD0平均去除率达90．71％,氨氮平均去除率达78．31％。以Mn^2＋、Fe^2＋、Mg^2＋、Ni^2＋为4个影响因子,通过正交实验分析无机离子对橡胶促进剂M盐废水中有机物降解的促进作用。由实验数据的摄差大小可知,各无机离子对优势复合菌降解橡胶有机废水的影响从大到小依次为：Mn^2＋、Fe^2＋、Ni^2＋和Mg^2＋。4种离子最佳质量浓度组合为：0．500mg／L的Mn^2＋、1．00mg／L的Fe^2＋、35．0mg／L的Mg^2＋和0．025mg／L的Ni^2＋。     

高危职业危害监测内涵及预警系统探讨

我国目前职业病危害形势严峻,职业卫生管理和服务模式不能适应社会发展的需求,优先管理高危职业危害,建立高危职业危害监测预警系统是控制和减少重大职业危害事故的关键.通过职业危害监测、风险评估、风险分级和预警等术语阐述高危职业危害监测的内涵,并探讨建立利用现有技术平台、重点监控、多部门合作、多层次的纵向多维监测预警系统.     

区域性安全生产风险影响因素及其权重确定研究

影响地区安全生产风险的因素众多,使得评价地区安全生产风险的控制水平极为复杂.系统分析地区安全生产风险的影响因素,并确定其权重,对提高区域性定量风险评价的科学性,有效实施区域安全生产风险管理具有重要意义.本文针对我国安全生产监督管理特点,对我国当前安全生产风险的多源化趋势进行了分析,提出了安全生产责任制、安全管理组织机构、安全生产法规、安全生产投入、安全科学技术等12个影响安全生产风险的核心因素,采用层次分析法(AHP)确定了安全生产风险影响因素的权重值,并设计了安全生产风险控制因子,以表征地区的安全生产风险控制水平.计算结果表明,安全生产规划、安全生产控制指标、安全生产法规和安全管理组织机构对地区安全生产风险的影响程度最高.     

危险化学品重大危险源安全监控通用技术规范研究

本文通过分析我国重大危险源监控预警系统建设的经验和不足以及国外技术发展的最新趋势,根据功能安全的设计理念,针对储罐区、库区和生产场所安全监控通用技术规范开展研究,提出了规范的编制思路,重点讨论了系统的监控参数、硬件架构、功能设计、软件和性能指标等内容.     

Identification of Odor Causing Compounds in a Commercial Dairy Farm

The odorous air emissions from confined animal feeding operations (CAFOs), such as swine, poultry and dairy farms, are increasingly raising community complaints. Odorous emissions can result in health damages, psychological discomforts and adverse aesthetic effects in the community. However, these emissions are not well characterized up to now due to the lack of legislation, the limitations in sampling and instrumentation techniques, and the complexity of the emissions themselves. This study is aimed at the development of a high volume sampler and sorbent assembly to identify the odor causing compounds from a diary CAFO. The sorbent was custom designed to target the potential compounds that may exist in a dairy farm and was validated in laboratory with a synthetic odor from the swine manure. The actual samples at the diary farm were collected in spring and summer of 2005. The sorbents were solvent extracted and individual odor compounds were identified using GC–MS (gas chromatography–mass spectroscopy). The data obtained indicated that high volume sampling can shorten the sampling time from days to within 4 h. Both volatile organic compounds (VOCs) and volatile fatty acids (VFAs) have been identified from the dairy farm, such as phenol, methylphenol, 4-ethyl phenol, indole, methyl indole, benzyl alcohol, hexanoic acid, valeric acid and iso-valeric acid, together with some nitrogen containing compounds that have not been reported before.