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81.
Quantity of trace arsenic in grain and soil was determined by hydride nondispersive atomic fluorescence method.Optimum conditions of measurement were selected in the experiment including the pH of the medium, reductive agent, the concentration and flowing velocity of KBH4, rate of carrier gas and atomized temperature. The reference sample of rice C was determined and the linear relationship of the calibration curve was plotted, indicating that the method was highly precise. In the experiment of recovery rate, the method was quite satisfactory.Based on the determination of hundreds of samples, it is proved that atomic fluorescence method is rapid, sensitive and low in interference. It is very efficient on determination of trace arsenic in soils and grains, especially in grains. 相似文献
82.
IntroductionHeavymetalsinwaterbodiesaresignificantlydifferentfromorganicpollutantsthatcanbemicrobiologicallydegradedordecomposed .Generally ,theyarepurifiedthroughtheiradsorptionontosuspendedsubstratesinrivers.Adsorptionofheavymetalsonriversuspendedsub… 相似文献
83.
Li Ning Li Guangming Yao Zhenya Zhao Jianfu 《Frontiers of Environmental Science & Engineering in China》2007,1(2):190-195
Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts
with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for
CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions
were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were
characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma
torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a
low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively
low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, CODCr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would
have a promising application in CWAO treatment of high concentration organic wastewater.
Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备] 相似文献
84.
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86.
1IntroductionNovelbiologicalactivatedcarbonandactivatedsludgesystemhasshownitsefectiveabilitytoreduceCODintoxicorganicwastewa... 相似文献
87.
Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works. 相似文献
88.
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区域环境质量综合评价的一种方法——Fuzzy概率法 总被引:7,自引:1,他引:7
本文应用Fuzzy概率原理,在对区域环境内各单项污染指标进行分级评价的基础上,考虑各单项污染指标在总体中的权重,并综合各单项污染指标的作用,给出区域环境内环境“总”质量的综合评价。 相似文献
90.
本报告介绍DDT经金属对处理后降解产物的分析鉴定和有关反应机制的初步研究。 降解产物主要是用气相色谱—质谱联用分析鉴定的。水溶液中的DDT用Cu-Zn金属对还原其降解产物经鉴定是DDD、DDMS、DDE_t,它们是DDT分子脱去烷基碳原子上不同数目的氯原子的产物。而在Cu-Fe金属对作用下,水溶液中的DDT的还原则是同时得到四种不同类型的产物。它们是DDT脱去烷基碳原子上的1个和3个氯原子的DDD和DDE_t;DDT脱氯、氧化产物DBP和DBH;DDT脱去HCI生成的DDE;两个DDT分子二聚脱氯的产物TTTB和TTDB。 实验证明金属对对DDT的作用是催化还原反应,金属对起着催化剂和还原剂双重作用。通过实验结果对DDT在金属对作用下的反应机制进行了初步探讨。 相似文献