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581.
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Peng Xu Junke Zhang Dongsheng Ji Zirui Liu Guiqian Tang Changsheng Jiang Yuesi Wang 《环境科学学报(英文版)》2018,30(1):16-27
In this study, we performed a highly time-resolved chemical characterization of nonrefractory submicron particles(NR-PM_1) in Beijing by using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer(HR-ToF-AMS). The results showed the average NR-PM_1 mass concentration to be 56.4 ± 58.0 μg/m~3, with a peak at 307.4 μg/m~3. Due to the high frequency of biomass burning in autumn, submicron particles significantly increased in organic content, which accounted for 51% of NR-PM_1 on average. Secondary inorganic aerosols(sulfate + nitrate + ammonium) accounted for 46% of NR-PM_1, of which sulfate,nitrate, and ammonium contributed 15%, 20%, and 11%, respectively. To determine the intrinsic relationships between the organic and inorganic species, we used the positive matrix factorization(PMF) model to merge the high-resolution mass spectra of the organic species and NO+and NO_2~+ions. The PMF analysis separated the mixed organic and nitrate(NO+and NO_2~+) spectra into four organic factors, including hydrocarbon-like organic aerosol(HOA), oxygenated organic aerosol(OOA), cooking organic aerosol(COA), and biomass burning organic aerosol(BBOA), as well as one nitrate inorganic aerosol(NIA) factor. COA(33%) and OOA(30%) contributed the most to the total organic aerosol(OA) mass, followed by BBOA(20%) and HOA(17%). We successfully quantified the mass concentrations of the organic and inorganic nitrates by the NO+and NO2+ions signal in the organic and NIA factors. The organic nitrate mass varied from 0.01-6.8 μg/m~3, with an average of 1.0 ±1.1 μg/m~3, and organic nitrate components accounted for 10% of the total nitrate mass in this observation. 相似文献
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Great efforts have been devoted to improve the photocatalytic activity of TiO_2 in the visible light region. Rational design of the external structure and adjustment of intrinsic electronic status by impurity doping are two main effective ways to achieve this purpose. A facile onepot synthetic approach was developed to prepare C-doped hollow TiO_2 spheres, which simultaneously realized these advantages. The synthesized TiO_2 exhibits a mesoporous hollow spherical structure composed of fine nanocrystals, leading to high specific surface area(~180 m~2/g) and versatile porous texture. Carbonate-doping was achieved by a postthermal treatment at a relatively low temperature(200°C), which makes the absorption edge red-shifted to the visible region of the solar spectrum. Concomitantly, Ti~(3+) induced by C-doping also functions in improving the visible-light photocatalytic activity by reducing the band gap. There exists a synergistic effect from multiple stimulatives to enhance the photocatalytic effect of the prepared TiO_2 catalyst. It is not out of expectation that the asprepared C-doped hollow TiO_2 spheres exhibits an improved photocatalytic activity under visible light irradiation in organic pollutant degradation. 相似文献
585.
Origin of 3He in the Earth is a mystery. Lacking a production mechanism, scientists assume 3He was trapped in the Earth, when the Earth was formed. In contrast to this assumption, we have found 3He and 3H concentrations in excess of the atmospheric values in the deep waters of the volcanic Lakes Pavin (France), Laacher (Germany)
and Nemrut (Turkey). This paper reports the result of finding 3H in these three volcanic lakes that appear to originate from the mantle. Because 3H has a half-life of 12.3 years, this 3H and the resulting 3He must have formed recently in the mantle and not be part of a primordial reservoir. The nuclear reactions that generate
tritium might be a source of “missing” energy in the interior of the Earth. 相似文献
586.
江苏省重要生态功能保护区的划分,为实现社会经济和生态环境的协调发展奠定了良好基础。针对重要生态功能保护区划分过程中存在的各种问题,如划分区域分割、划分随意性大、禁止开发区少、管理不到位等,分别从技术层面和管理层面提出了相应的对策与建议,为重要生态功能保护区划分的完善和生态功能的充分发挥提供了可行方案。 相似文献
587.
施工现场管理水平高低直接影响着施工质量、安全和效益,特别是油水井大修侧钻、维护性作业,是体现队伍管理水平的重要标志。近年来,江苏油田分公司井下作业处作业一大队积极探索“四个到位”管理,推进作业现场标准化建设,提升安全管理水平。 相似文献
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589.
Liangliang Wei Kun Wang Qingliang Zhao Junqiu Jiang Chunmei Xie Wei Qiu 《环境科学学报(英文版)》2010,22(5):641-647
In order to characterize the organic properties of waste activated sludge in a wastewater treatment plant,organic matter within sludge was extracted with NH 3 ·H 2 O preferentially,and subsequently fractionated into five fractions using XAD-8/XAD-4 resins.Up to a 63.8%-71.1% of organic matter within the sludge could be efficiently extracted by NH 3 ·H 2 O.Fractionation results showed that hydrophobic acid and hydrophilic fraction were two main components among the sludge organic matter (accounting for 32.2% and 48.0% of the bulk organic matter,respectively),whereas transphilic acid,hydrophobic neutral and transphilic neutral were quite low (accounting for 9.2%,5.8% and 4.8%,respectively).Despite that the extractant of NH 3 ·H 2 O showed a relatively higher extraction efficiency of the aromatic components,the relatively low aromaticity of the organic fractions implied that those non-aromatic components could also be effectively extracted,especially for neutral and hydrophilic fractions.In addition,acidic fractions contained more aromatic humic-like components,whereas the neutral fractions had a greater content of aromatic proteins and soluble microbial byproduct-like components.Extraction of sludge organics with NH 3 ·H 2 O and subsequential fractionation using XAD resins could be a novel method for further characterization of sludge organics. 相似文献
590.