全文获取类型
收费全文 | 328篇 |
免费 | 25篇 |
国内免费 | 127篇 |
专业分类
安全科学 | 24篇 |
废物处理 | 26篇 |
环保管理 | 20篇 |
综合类 | 193篇 |
基础理论 | 41篇 |
环境理论 | 1篇 |
污染及防治 | 128篇 |
评价与监测 | 14篇 |
社会与环境 | 13篇 |
灾害及防治 | 20篇 |
出版年
2023年 | 11篇 |
2022年 | 31篇 |
2021年 | 28篇 |
2020年 | 13篇 |
2019年 | 15篇 |
2018年 | 13篇 |
2017年 | 26篇 |
2016年 | 16篇 |
2015年 | 20篇 |
2014年 | 29篇 |
2013年 | 34篇 |
2012年 | 22篇 |
2011年 | 30篇 |
2010年 | 22篇 |
2009年 | 17篇 |
2008年 | 11篇 |
2007年 | 17篇 |
2006年 | 26篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 10篇 |
2002年 | 5篇 |
2001年 | 7篇 |
2000年 | 11篇 |
1999年 | 7篇 |
1998年 | 1篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 11篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
排序方式: 共有480条查询结果,搜索用时 31 毫秒
341.
重庆市春季大气颗粒物浓度的对比监测分析 总被引:2,自引:1,他引:1
通过2012年春季在重庆大气超级站进行的PM10和PM2.5手工采样与自动仪器的对比监测,分析了自动监测与手工监测的一致性及造成偏差的原因,并对PM2.5与PM10浓度的比值关系进行了分析。结果表明:MP101M型颗粒物自动监测仪用于监测PM10时系统性误差偏高,仪器初始精密度存在负偏差;用于监测PM2.5时系统性误差在允许范围之内,仪器初始精密度存在较大负偏差;PM10和PM2.5的手工采样和自动仪器监测值之变化趋势具有非常高的一致性;PM2.5与PM10浓度比值范围在56.5%~90.4%,平均比值为(73.8±7.4)%。 相似文献
342.
343.
ASBR-SBR-Fenton氧化工艺处理均苯四甲酸生产废水 总被引:1,自引:1,他引:0
采用厌氧序批式反应器( ASBR)-SBR-Fenton氧化工艺处理均苯四甲酸生产废水,运行结果表明,在进水COD为4 200 ~5 100 mg/L,BOD5为1 500~1 800 mg/L的条件下,处理后出水COD为40 mg/L,出水水质达到GB8978-1996《中华人民共和国国家标准污水综合排放标准》的I级... 相似文献
344.
Factors that have an effect on degradation of diclofenac in aqueous solution by gamma ray irradiation 总被引:1,自引:0,他引:1
Liu Q Luo X Zheng Z Zheng B Zhang J Zhao Y Yang X Wang J Wang L 《Environmental science and pollution research international》2011,18(7):1243-1252
Purpose
Gamma ray irradiation is considered as an effective way to degrade diclofenac. However, due to the extensive coexisting substances in natural waters, the use of gamma ray irradiation for degradation is often influenced by multiple factors. The various factors that affect degradation efficiency, such as initial diclofenac concentration, initial pH, and the concentration of the additives including H2O2 (·OH radical promoter), CH3OH (·OH radical scavenger), thiourea (·OH, H·, and eaq− scavenger), humic acid, and NO3− (coexisting substances in natural waters), are investigated. Furthermore, possible intermediate products are identified and corresponding transformation pathways are proposed. 相似文献345.
346.
347.
Exposure to metal mixtures and human health impacts in a contaminated area in Nanning, China 总被引:12,自引:0,他引:12
Cadmium and lead have been identified as very toxic metals, which are widely present in the environment due to natural and anthropogenic emissions. Many studies have shown that the food chain is the main pathway of cadmium and lead transfer from the environment to humans. It is well documented that many factors will affect their transfer through food chains. Previous investigations on heavy metals were mostly concentrated on one contaminant in isolation. However, in real environments, exposure to mixtures of metals is ubiquitous such that cadmium pollution is invariably being associated with lead and zinc, etc. This study focuses on the contamination and health effects of the metal mixtures. For this purpose, a dietary survey was taken for 3 groups in Nanning in October 2002. Samples of soils, plants (vegetables), urine and blood of humans were measured for Cd, Fe, Cu, Zn, Ca and Pb, in addition, the urinary indicators of renal dysfunction Albumin (ALB), N-acetyl-beta-D-glucosaminidase (NAG), Beta-2-microglobulin (beta2-MG) and Retinol-binding protein (RBP) in urine were also measured. Results showed that soil contamination with metal mixtures had caused significant renal dysfunction of the local residents living in the contaminated area, and the dose-response curve was somewhat altered by the mixed contamination of Cd and Pb as well as the intake of other minerals. The importance of mixtures of metal contamination and human health are also discussed in this paper. 相似文献
348.
我国目前正处于大气常规污染物治理与有毒有害污染物治理相互叠加的阶段,挥发性有机物等有毒有害大气污染物排放显著增加,大多城市环境赋存严重,而污染形势有待摸清。基于美国33种城市有毒有害大气污染物和日本23种大气优先控制污染物以及其他国家相关管控,根据我国企业化学品生产排放数据,综述了22种在我国东部经济带普遍存在的有毒有害大气污染物的环境赋存情况,对其在我国的环境检出、生产排放、污染物控制技术等进行了分析,发现苯、重金属等污染物检出浓度较高,多数污染物的最大检出浓度高于国外;国家管控有所不足,建议联合多种管理制度协同加强其风险管理,深度改善空气质量。 相似文献
349.
Di Meng Wei Jiang Jing Li Lin Huang Lixin Zhai Liyuan Zhang 《Journal of environmental science and health. Part. B》2019,54(4):336-343
In recent decades, biodegradation has been considered a promising and eco-friendly way to eliminate organophosphorus pesticides (OPs) from the environment. To enrich current biodegrading-enzyme resources, an alkaline phosphatase (AP3) from Bacillus amyloliquefaciens YP6 was characterized and utilized to test the potential for new applications in the biodegradation of five broad-spectrum OPs. Characterization of AP3 demonstrated that activity was optimal at 40?°C and pH 10.3. The activity of AP3 was enhanced by Mg2+, Ca2+, and Cu2+, and strongly inhibited by Mn2+, EDTA, and L-Cys. Compared to disodium phenyl phosphate, p-nitrophenyl phosphate (pNPP) was more suitable to AP3, and the Vm, Km, kcat, kcat/Km values of AP3 for pNPP were 4,033?U mg?1, 12.2?mmol L?1, 3.3?×?106 s?1, and 2.7?×?108 s?1mol?1L, respectively. Degradation of the five OPs, which included chlorpyrifos, dichlorvos, dipterex, phoxim, and triazophos, was 18.7%, 53.0%, 5.5%, 68.3%, and 96.3%, respectively, after treatment with AP3 for 1?h. After treatment of the OP for 8?h, AP3 activities remained more than 80%, with the exception of phoxim. It can be postulated that AP3 may have a broad OP-degradation ability and could possibly provide excellent potential for biodegradation and bioremediation in polluted ecosystems. 相似文献
350.
对某农药厂原厂区的有机污染地下水的水质特征进行了分析,采用小试确定了药剂投加量,并采用中试装置考察了混凝—气浮工艺的去除效果。小试结果表明,聚合氯化铝(PAC)的最佳投加量为300 mg/L,聚丙烯酰胺(PAM)的最佳投加量为3 mg/L。中试运行结果表明,当进水流量为0.25 ~1.00 m3/h时,对浊度的去除率为82.66%~90.13%,对悬浮固体的去除率为80.12%~90.11%;碳原子数在10~28范围内的石油烃的平均去除率为38.96%~51.46%;1,2-二氯乙烷、2-甲基萘、苯、萘、甲苯、邻苯二甲酸二甲酯的平均去除率分别为17.76%,67.49%,48.70%,54.56%,37.24%,62.53%。 相似文献