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41.
Standard evaluations of air quality models rely heavily on a direct comparison of monitoring data matched with the model output for the grid cell containing the monitor's location. While such techniques may be adequate for some applications, conclusions are limited by such factors as the sparseness of the available observations (limiting the number of grid cells at which the model can be evaluated) and the incommensurability between volume-averages and pointwise observations. We examine several sets of simulations to illustrate the effect of incommensurability in a variety of cases distinguished by the type and extent of spatial correlation present. Block kriging, a statistical method which can be used to address the issue, is then demonstrated using the simulations. Lastly, we apply this method to actual data and discuss the practical importance of understanding the impact of spatial correlation structure and incommensurability.  相似文献   
42.
Previously we found that cloned cottonwood saplings (Populus deltoides) grew twice as large in New York, New York, USA, compared to surrounding rural environments and that soils, temperature, CO2, nutrient deposition, and microclimatic variables could not account for the greater urban plant biomass. Correlations between final season biomass and cumulative O3 exposures, combined with twofold growth reductions in an open-top chamber experiment provided strong evidence that higher cumulative O3 exposures in rural sites reduced growth in the country. Here, we assess the field gas exchange, growth and development, and allocation responses underlying the observed growth differences and compare them with isolated O3 responses documented in the open-top chamber experiment. Cottonwoods showed no visible foliar injury, reduced photosynthesis of recently expanded foliage, early leaf senescence, protective reduction in stomatal conductance, or compensatory allocation to shoot relative to root biomass for either the chamber or field experiment. Instead, O3-impacted chamber plants had significantly higher conductance and reduced photosynthesis of older foliage that led to reduced leaf area production and a twofold biomass reduction in the absence of visible injury. Rural-grown field plants showed the same pattern of significantly higher conductance in the absence of concomitant increases in photosynthesis that was indicative of a loss of stomatal control. Incremental changes in foliar production were also significantly inversely related to fluctuations in ambient O3 exposures. The similarity in biomass, gas exchange, phenological, and allocation responses between chamber and field experiments indicate that mechanisms accounting for reduced growth at rural sites were consistent with those in the open-top chamber O3 experiment. This study shows the limitation of visible symptoms as a sole diagnostic factor for documenting detrimental O3 impacts and points toward a new approach to show O3 impacts when visible injury is not present. Namely, O3-impacted vegetation showed an unusual inverse relationship of increased conductance with lower photosynthesis of older foliage that was indicative of a loss of stomatal control. This increased stomatal conductance of O3-impacted vegetation accentuates pollutant flux into affected foliage and has important implications for system water balance during warm, dry portions of the growing season when O3 concentrations are highest.  相似文献   
43.
    
We use a discourse network analysis approach to answer two questions about national news coverage of climate change policy debate in Canada during the period 2006–2010. First, what is the media visibility of actors relevant to policy development and advocacy on climate change? Second, given the political and economic context of climate policy-making in Canada, does greater or lesser media visibility reflect effectiveness in climate policy advocacy? Multiple interpretive frameworks characterize Canadian political discourse about climate change, with fragmentation between the federal government, opposition political parties, provincial governments, and environmental organizations. Contrary to expectations, environmental organizations had high levels of media visibility while the relative invisibility of fossil fuel corporations was notable in the media coverage of Canadian climate discussions. Our findings challenge optimistic accounts of the relationship between media power and political power, and suggest that media power does not necessarily translate to political efficacy.  相似文献   
44.
    
Abstract

Reformulated gasoline (RFG) contains oxygen additives such as methyl tertiary butyl ether or ethanol. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering the emission of carbon monoxide (CO) and volatile organic compounds (VOCs). Because VOCs react with sunlight to form ozone (O3), the Clean Air Act requires severe O3 nonattainment areas such as southeastern Wisconsin to use RFG. On July 17, 2001, the U.S. Environmental Protection Agency (EPA) granted Milwaukee, WI, and Chicago, IL, a waiver from the VOC reduction requirement of Phase II RFG. The VOC reduction requirement was lowered from 27.4% of the 1990 baseline fuel to 25.4%. The assumption was that ethanol-blended RFG would lower summertime CO concentrations sufficiently to offset the increased VOC emissions. The waiver is estimated to increase VOC emissions by ~0.8%, or 0.4 t of VOC on a hot summer weekday. This study evaluates whether RFG has been effective in lowering southeastern Wisconsin ambient CO concentrations. Three years of ambient CO data before RFG was introduced were compared with the first three years of ambient CO data after RFG was introduced. This paper also evaluates how the meteorology, vehicle inspection/maintenance program, vehicle miles traveled, and stationary source emissions influence CO concentrations. The winter decrease in ambient CO concentrations was found to be statistically significant, while the summer data showed no statistically significant change, indicating that RFG is most effective lowering ambient CO concentrations in cold weather.  相似文献   
45.
Ozone is an ubiquitous air pollutant that affects both human health and vegetation. There is concern about the number of hours human populations in nonattainment areas in the United States are exposed to levels of 03 at which effects have been observed. As improvement in air quality is achieved, it is possible that 03 control strategies may produce distributions of 1-h 03 concentrations that result in different diurnal profiles that produce greater potential exposures to 03 at known effects levels for multiple hours of the day. These concerns have prompted new analysis of aerometric data. In this analysis, the change in the seasonally averaged diurnal pattern was investigated as changes in 03 levels occurred. For the data used in this analysis, 25 of the 36 sites that changed compliance status across years showed no statistically significant change in the shape of the average diurnal profile (averaged by 03 season). For 71 percent (10 out of 14) of the sites in southern California and Dallas-Fort Worth, Texas, that showed improvement in O3 levels (i.e., reductions in the number of exceedances over the years), but still remained in nonattainment, a statistically significant change in the shape of the seasonally averaged diurnal profile occurred. Based on the results obtained in this study, the evaluation of diurnal patterns may be useful for identifying the influence of changes in emission levels versus meteorological variation on attainment status. Using data from the southern California and Dallas-Fort Worth sites, which showed improvements in 03 levels, changes were observed in the seasonally averaged diurnal profiles. On the other hand, for the sites moving between attainment and nonattainment status, such a change in shape was generally not observed and it was possible that meteorology played a more important role than changes in emission levels relative to attainment status.  相似文献   
46.
    
Zoos and aquariums are increasingly incorporating conservation education into their mission statements and visitor experiences to address global biodiversity loss. To advance knowledge and practice in the field, research is being conducted to evaluate the effect of zoo conservation-education experiences on visitor psychosocial outcomes (e.g., knowledge, attitude, emotions, motivations, behavior). Following recent discussions among scholars and practitioners concerning logistical and methodological challenges that likely undermine the conclusions of such research, we identified and reviewed the methods and reporting practices in peer-reviewed articles published in English from May 1998 to June 2016 that focused on adult visitor samples (47 articles, 48 studies). We examined elements of internal, external, construct, and statistical conclusion validity. Methodological quality of quantitative methods and reporting practices was determined using the Effective Public Health Practice Project Quality Assessment Tool. Each study was coded as either strong (no weak ratings), moderate (1 weak rating), or weak (≥2 weak ratings). The quantitative methods of 83.3% of studies were weak. The remaining 16.7% had methods of moderate quality. Using an existing checklist, we also assessed the quality and rigor of qualitative methods and reporting practices and found that some aspects of these methods were reported more comprehensively than others. For example, 69.6% of articles discussed methods for identifying key themes from the data, whereas only 34.8% reported how data verification was performed. We suggest increased application of intensive longitudinal methods (e.g., daily diary) to strengthen self-reported data, experimental and repeated-measures designs, and mixed-methods approaches. Our findings and recommendations could strengthen and guide the research and evaluation agenda for the field and ultimately enhance the contribution zoos make to global biodiversity conservation.  相似文献   
47.
Fires in agricultural ecosystems emit greenhouse gases and aerosols that influence climate on multiple spatial and temporal scales. Annex 1 countries of the United Nations Framework Convention on Climate Change (UNFCCC), many of which ratified the Kyoto Protocol, are required to report emissions of CH4 and N2O from these fires annually. In this study, we evaluated several aspects of this reporting system, including the optimality of the crops targeted by the UNFCCC globally and within Annex 1 countries, and the consistency of emissions inventories among different countries. We also evaluated the success of individual countries in capturing interannual variability and long-term trends in agricultural fire activity. In our approach, we combined global high-resolution maps of crop harvest area and production, derived from satellite maps and ground-based census data, with Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) measurements of active fires. At a global scale, we found that adding ground nuts (e.g., peanuts), cocoa, cotton and oil palm, and removing potato, oats, rye, and pulse other from the list of 14 crops targeted by the UNFCCC increased the percentage of active fires covered by the reporting system by 9%. Optimization led to a different recommended list for Annex 1 countries, requiring the addition of sunflower, cotton, rapeseed, and alfalfa and the removal of beans, sugarcane, pulse others, and tuber-root others. Extending emissions reporting to all Annex 1 countries (from the current set of 19 countries) would increase the efficacy of the reporting system from 6% to 15%, and further including several non-Annex 1 countries (Argentina, Brazil, China, India, Indonesia, Thailand, Kazakhstan, Mexico, and Nigeria) would capture over 55% of active fires in croplands worldwide. Analyses of interannual trends from the United States and Australia showed the importance of both intensity of fire use and crop production in controlling year-to-year variations in agricultural fire emissions. Remote sensing provides an effective means for evaluating some aspects of the current UNFCCC emissions reporting system; and, if combined with census data, field experiments and expert opinion, has the potential to improve the robustness of the next generation inventory system.  相似文献   
48.
Whilst future air temperature thresholds have become the centrepiece of international climate negotiations, even the most ambitious target of 1.5 °C will result in significant sea-level rise and associated impacts on human populations globally. Of additional concern in Arctic regions is declining sea ice and warming permafrost which can increasingly expose coastal areas to erosion particularly through exposure to wave action due to storm activity. Regional variability over the past two decades provides insight into the coastal and human responses to anticipated future rates of sea-level rise under 1.5 °C scenarios. Exceeding 1.5 °C will generate sea-level rise scenarios beyond that currently experienced and substantially increase the proportion of the global population impacted. Despite these dire challenges, there has been limited analysis of how, where and why communities will relocate inland in response. Here, we present case studies of local responses to coastal erosion driven by sea-level rise and warming in remote indigenous communities of the Solomon Islands and Alaska, USA, respectively. In both the Solomon Islands and the USA, there is no national government agency that has the organisational and technical capacity and resources to facilitate a community-wide relocation. In the Solomon Islands, communities have been able to draw on flexible land tenure regimes to rapidly adapt to coastal erosion through relocations. These relocations have led to ad hoc fragmentation of communities into smaller hamlets. Government-supported relocation initiatives in both countries have been less successful in the short term due to limitations of land tenure, lacking relocation governance framework, financial support and complex planning processes. These experiences from the Solomon Islands and USA demonstrate the urgent need to create a relocation governance framework that protects people’s human rights.  相似文献   
49.
50.
    
Blood was obtained by cordocentesis from a fetus with non-immune hydrops demonstrated by ultrasound scanning at 27 weeks' gestation. Abnormalities of serum transferrin isoelectric focussing (IEF) were identified, characteristic of a congenital disorder of glycosylation type I (CDG-Ia). A diagnosis of CDG-Ia was confirmed by enzyme analysis of cultured amniocytes. This is the first report of CDG-Ia diagnosed by serum analysis in a fetus. Previous reports have warned that diagnostic abnormalities do not appear in serum until several weeks after birth. The sensitivity of cordocentesis transferrin IEF is unknown but is less than 100% effective because cases have been diagnosed postnatally after normal prenatal or neonatal studies. Enzyme analysis or mutation analysis is required for diagnosis of congenital disorder of glycosylation (CDGs) regardless of whether a diagnostic transferrin pattern is identified prenatally. The analysis of a small sample of serum, from cordocentesis, performed to check for fetal anemia, simplified the investigation, diagnosis, and genetic counselling of a case of non-immune hydrops detected at 27 weeks' gestation. This might be a useful test for other cases in these circumstances, as fetal blood is usually collected to check for anemia. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
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