Physiological and developmental effects of O3 on cottonwood growth in urban and rural sites.

Previously we found that cloned cottonwood saplings (Populus deltoides) grew twice as large in New York, New York, USA, compared to surrounding rural environments and that soils, temperature, CO2, nutrient deposition, and microclimatic variables could not account for the greater urban plant biomass. Correlations between final season biomass and cumulative O3 exposures, combined with twofold growth reductions in an open-top chamber experiment provided strong evidence that higher cumulative O3 exposures in rural sites reduced growth in the country. Here, we assess the field gas exchange, growth and development, and allocation responses underlying the observed growth differences and compare them with isolated O3 responses documented in the open-top chamber experiment. Cottonwoods showed no visible foliar injury, reduced photosynthesis of recently expanded foliage, early leaf senescence, protective reduction in stomatal conductance, or compensatory allocation to shoot relative to root biomass for either the chamber or field experiment. Instead, O3-impacted chamber plants had significantly higher conductance and reduced photosynthesis of older foliage that led to reduced leaf area production and a twofold biomass reduction in the absence of visible injury. Rural-grown field plants showed the same pattern of significantly higher conductance in the absence of concomitant increases in photosynthesis that was indicative of a loss of stomatal control. Incremental changes in foliar production were also significantly inversely related to fluctuations in ambient O3 exposures. The similarity in biomass, gas exchange, phenological, and allocation responses between chamber and field experiments indicate that mechanisms accounting for reduced growth at rural sites were consistent with those in the open-top chamber O3 experiment. This study shows the limitation of visible symptoms as a sole diagnostic factor for documenting detrimental O3 impacts and points toward a new approach to show O3 impacts when visible injury is not present. Namely, O3-impacted vegetation showed an unusual inverse relationship of increased conductance with lower photosynthesis of older foliage that was indicative of a loss of stomatal control. This increased stomatal conductance of O3-impacted vegetation accentuates pollutant flux into affected foliage and has important implications for system water balance during warm, dry portions of the growing season when O3 concentrations are highest.     

Developing green infrastructure ‘thinking’: devising and applying an interactive group-based methodology for practitioners

Recent years have witnessed a wave of interest in the concept of green infrastructure (GI) as a means of applying an ecosystem approach to spatial planning practice; however, more limited attention has been paid to decision-making processes or tools to enhance GI within spatial plans and guidance. We address this deficit by reporting on the development and application of an interactive group-based methodology to enhance GI ‘thinking’ and interdisciplinary collaboration, drawing on the literature on the sociology of interactions. Our findings suggest that a game-based approach to GI problem-solving was successful in breaking down professional barriers by creating an informal learning arena, providing an enabling opportunity for participants to solve problems in an iterative, non-linear style to develop principles for action with transferability to ongoing plan formation. This style of problem-solving was characterised by shifting norms and routines of interaction, leading to problem re-framing and a search for alternative solutions.     

Media Access and Political Efficacy in the Eco-politics of Climate Change: Canadian National News and Mediated Policy Networks

We use a discourse network analysis approach to answer two questions about national news coverage of climate change policy debate in Canada during the period 2006–2010. First, what is the media visibility of actors relevant to policy development and advocacy on climate change? Second, given the political and economic context of climate policy-making in Canada, does greater or lesser media visibility reflect effectiveness in climate policy advocacy? Multiple interpretive frameworks characterize Canadian political discourse about climate change, with fragmentation between the federal government, opposition political parties, provincial governments, and environmental organizations. Contrary to expectations, environmental organizations had high levels of media visibility while the relative invisibility of fossil fuel corporations was notable in the media coverage of Canadian climate discussions. Our findings challenge optimistic accounts of the relationship between media power and political power, and suggest that media power does not necessarily translate to political efficacy.     

The Effect of Reformulated Gasoline on Ambient Carbon Monoxide Concentrations in Southeastern Wisconsin

Abstract

Reformulated gasoline (RFG) contains oxygen additives such as methyl tertiary butyl ether or ethanol. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering the emission of carbon monoxide (CO) and volatile organic compounds (VOCs). Because VOCs react with sunlight to form ozone (O₃), the Clean Air Act requires severe O₃ nonattainment areas such as southeastern Wisconsin to use RFG. On July 17, 2001, the U.S. Environmental Protection Agency (EPA) granted Milwaukee, WI, and Chicago, IL, a waiver from the VOC reduction requirement of Phase II RFG. The VOC reduction requirement was lowered from 27.4% of the 1990 baseline fuel to 25.4%. The assumption was that ethanol-blended RFG would lower summertime CO concentrations sufficiently to offset the increased VOC emissions. The waiver is estimated to increase VOC emissions by ～0.8%, or 0.4 t of VOC on a hot summer weekday. This study evaluates whether RFG has been effective in lowering southeastern Wisconsin ambient CO concentrations. Three years of ambient CO data before RFG was introduced were compared with the first three years of ambient CO data after RFG was introduced. This paper also evaluates how the meteorology, vehicle inspection/maintenance program, vehicle miles traveled, and stationary source emissions influence CO concentrations. The winter decrease in ambient CO concentrations was found to be statistically significant, while the summer data showed no statistically significant change, indicating that RFG is most effective lowering ambient CO concentrations in cold weather.     

Changes in Diurnal Patterns Related to Changes in Ozone Levels

Ozone is an ubiquitous air pollutant that affects both human health and vegetation. There is concern about the number of hours human populations in nonattainment areas in the United States are exposed to levels of 03 at which effects have been observed. As improvement in air quality is achieved, it is possible that 03 control strategies may produce distributions of 1-h 03 concentrations that result in different diurnal profiles that produce greater potential exposures to 03 at known effects levels for multiple hours of the day. These concerns have prompted new analysis of aerometric data. In this analysis, the change in the seasonally averaged diurnal pattern was investigated as changes in 03 levels occurred. For the data used in this analysis, 25 of the 36 sites that changed compliance status across years showed no statistically significant change in the shape of the average diurnal profile (averaged by 03 season). For 71 percent (10 out of 14) of the sites in southern California and Dallas-Fort Worth, Texas, that showed improvement in O3 levels (i.e., reductions in the number of exceedances over the years), but still remained in nonattainment, a statistically significant change in the shape of the seasonally averaged diurnal profile occurred. Based on the results obtained in this study, the evaluation of diurnal patterns may be useful for identifying the influence of changes in emission levels versus meteorological variation on attainment status. Using data from the southern California and Dallas-Fort Worth sites, which showed improvements in 03 levels, changes were observed in the seasonally averaged diurnal profiles. On the other hand, for the sites moving between attainment and nonattainment status, such a change in shape was generally not observed and it was possible that meteorology played a more important role than changes in emission levels relative to attainment status.     

Evaluating greenhouse gas emissions inventories for agricultural burning using satellite observations of active fires

Fires in agricultural ecosystems emit greenhouse gases and aerosols that influence climate on multiple spatial and temporal scales. Annex 1 countries of the United Nations Framework Convention on Climate Change (UNFCCC), many of which ratified the Kyoto Protocol, are required to report emissions of CH4 and N2O from these fires annually. In this study, we evaluated several aspects of this reporting system, including the optimality of the crops targeted by the UNFCCC globally and within Annex 1 countries, and the consistency of emissions inventories among different countries. We also evaluated the success of individual countries in capturing interannual variability and long-term trends in agricultural fire activity. In our approach, we combined global high-resolution maps of crop harvest area and production, derived from satellite maps and ground-based census data, with Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) measurements of active fires. At a global scale, we found that adding ground nuts (e.g., peanuts), cocoa, cotton and oil palm, and removing potato, oats, rye, and pulse other from the list of 14 crops targeted by the UNFCCC increased the percentage of active fires covered by the reporting system by 9%. Optimization led to a different recommended list for Annex 1 countries, requiring the addition of sunflower, cotton, rapeseed, and alfalfa and the removal of beans, sugarcane, pulse others, and tuber-root others. Extending emissions reporting to all Annex 1 countries (from the current set of 19 countries) would increase the efficacy of the reporting system from 6% to 15%, and further including several non-Annex 1 countries (Argentina, Brazil, China, India, Indonesia, Thailand, Kazakhstan, Mexico, and Nigeria) would capture over 55% of active fires in croplands worldwide. Analyses of interannual trends from the United States and Australia showed the importance of both intensity of fire use and crop production in controlling year-to-year variations in agricultural fire emissions. Remote sensing provides an effective means for evaluating some aspects of the current UNFCCC emissions reporting system; and, if combined with census data, field experiments and expert opinion, has the potential to improve the robustness of the next generation inventory system.     

Heading for the hills: climate-driven community relocations in the Solomon Islands and Alaska provide insight for a 1.5 °C future

Whilst future air temperature thresholds have become the centrepiece of international climate negotiations, even the most ambitious target of 1.5 °C will result in significant sea-level rise and associated impacts on human populations globally. Of additional concern in Arctic regions is declining sea ice and warming permafrost which can increasingly expose coastal areas to erosion particularly through exposure to wave action due to storm activity. Regional variability over the past two decades provides insight into the coastal and human responses to anticipated future rates of sea-level rise under 1.5 °C scenarios. Exceeding 1.5 °C will generate sea-level rise scenarios beyond that currently experienced and substantially increase the proportion of the global population impacted. Despite these dire challenges, there has been limited analysis of how, where and why communities will relocate inland in response. Here, we present case studies of local responses to coastal erosion driven by sea-level rise and warming in remote indigenous communities of the Solomon Islands and Alaska, USA, respectively. In both the Solomon Islands and the USA, there is no national government agency that has the organisational and technical capacity and resources to facilitate a community-wide relocation. In the Solomon Islands, communities have been able to draw on flexible land tenure regimes to rapidly adapt to coastal erosion through relocations. These relocations have led to ad hoc fragmentation of communities into smaller hamlets. Government-supported relocation initiatives in both countries have been less successful in the short term due to limitations of land tenure, lacking relocation governance framework, financial support and complex planning processes. These experiences from the Solomon Islands and USA demonstrate the urgent need to create a relocation governance framework that protects people’s human rights.     

An integrated approach to the toxicity assessment of Irish marine sediments: application of porewater Toxicity Identification Evaluation (TIE) to Irish marine sediments

An integrated approach to the ecotoxicological assessment of Irish marine sediments was carried out between 2004 and 2007. Phase I Toxicity Identification Evaluation (TIE) of sediment porewaters from two sites on the east coast of Ireland were conducted. Initial Tier I screening of three Irish sites identified the need for TIE after significant toxicity was observed with Tisbe battagliai and the Microtox assay at two of the assayed sites (Alexandra Basin and Dunmore East). Porewaters classified as toxic were characterised using four manipulations, ethylenediaminetetraacetic acid (EDTA) chelation, sodium thiosulphate addition, C(18) Solid Phase Extraction (SPE) and Cation Exchange (CE) SPE. Prior to initial testing, and TIE manipulations, all porewater samples were frozen at -20 degrees C for several months until required. After initial Tier I testing Alexandra Basin porewater was classified as highly toxic by both assays while Dunmore East porewater only warranted a TIE with T. battagliai. Results of TIE manipulations for Alexandra Basin porewater and the Microtox Basic test were inconclusive. The toxicity of the porewater in this assay was significantly reduced after freezing. Three experimental episodes were conducted with one month between each for the Alexandra Basin porewater. After each month of freezing the baseline toxicity was further reduced in the Microtox assay, therefore it was not possible to draw accurate conclusions on the nature of the active contaminants in the sample. However, toxicity to T. battalgiai did not change after storage of the porewater. The C(18) and CE SPE decreased the toxicity of Alexandra Basin porewater to the copepod indicating that both organic and cationic compounds (e.g. metals) were active in the sample. Dunmore East porewater was assayed with T. battalgiai and again a combination of organic and inorganic compounds were found to be partly responsible for the observed toxicity (C(18), CE SPE and EDTA reduced toxicity). Results from these TIEs provide insight into the complexity of interpreting marine TIE data from porewater studies where mixtures of unknown substances are present.     

A model compound study: the ecotoxicological evaluation of five organic contaminants employing a battery of marine bioassays

This paper describes the ecotoxicological evaluation of five organic contaminants frequently detected in marine sediments (tributyltin, triphenyltin, benzo[a]pyrene, fluoranthene, and PCB 153) using three marine species (Vibrio fischeri, Tetraselmis suecica, and Tisbe battagliai). The sensitivity of each species varied for all compounds. The triorganotins were consistently the most toxic to all species. The applicability of each test system to assess the acute toxicity of environmental contaminants and their use in Toxicity Identification Evaluation (TIE) is discussed. Suitability of the Microtox and T. battagliai tests for employment in TIE studies were further assessed through spiking experiments with tributyltin. Results demonstrated that the most effective treatment to remove organotin toxicity from the sample was the C18 resin. The results of this study have important implications for risk assessment in estuarine and coastal waters in Ireland, where, at present the monitoring of sediment and water quality is predominantly reliant on chemical analysis alone.