A model of mercury contamination in a woodland stream

A model for the accumulation of mercury in four compartments of woodland stream has been set up. The four components considered are sediments, detritus, invertebrates and fish. The model inputs are concentrations of dissolved monomethyl mercury and dissolved inorganic mercury (Hg²⁺) in the water. The model predicts that some reevaluation of current safe mercury concentrations in water may be needed in order to keep mercury concentrations in fish below current actions levels.     

Organochlorine and heavy metal residues in the water/sediment system of the Southeast Regional Park in Madrid, Spain

A study into levels of contamination by organochlorine compounds (insecticides and PCBs) and heavy metals (Cd and Pb) in the water/sediment system of the Southeast Regional Park (SERP) in Madrid, Spain, has been carried out. Residue levels of xenobiotics were determined in surface and underground waters and sediments from selected sites throughout the protected area. The results showed these contaminants to be widespread throughout the studied area. p,p'-DDT concentration levels were consistently higher than its metabolite p,p'-DDE, indicating a recent use of this organochlorine insecticide in the area. PCB levels exceeded, in the majority of the cases, the levels taken as the maximum (100 ng/microl) for highly polluted waters. Cd and Pb levels found in water samples were under the detection limits of the methodology used. Pb levels found in sediment samples were higher than Cd.     

Polychlorinated naphthalenes in sediments from the Venice and Orbetello lagoons, Italy

The purpose of this study was to evaluate the contamination caused by polychlorinated naphthalenes in two polluted Mediterranean lagoons. Surface sediment samples from Venice and Orbetello lagoons were analysed using HRGC-HRMS. The levels of the sum of mono- to octa-CN ranged from 0.03 to 1.51 ng/g. Differences in PCN levels were observed as a function of the sampling site, with levels at the industrial sites exceeding those at the control sites. Although the PCN patterns and profiles resembled one another in different sediment samples, they differed considerably when compared with those in the technical PCN formulation Halowax 1014.     

Heavy metal content and speciation in groundwater of the Guadiamar river basin

This work presents the conclusions of a speciation study concerning Zn, Cd, Pb and Cu in groundwater from ten wells in the alluvial aquifers of the Guadiamar river, affected by Aznalcollar mine tailing spill (April 1998). The sampling campaign took place in January 2000, almost two years after the mining accident. Four metal fractions were determined: labile metal forms, H+ exchangeable metal forms, strongly inert forms (associated with organic and inorganic matter in solution), and forms associated with suspended matter. Total metal concentration in groundwater followed the trend Cd < Pb < Cu < Zn. The speciation study showed that Zn and Cd were present to a great extent in available forms (labile and H+ exchangeable), while Pb and Cu were found mostly in the less available forms (strongly inert). These results can illustrate the potential value of the speciation tool for the follow-up of spill-induced pollution in the area.     

Geostatistical analysis of soil hydrologic properties in a field plot

A 91-m transect was set up in an irrigated field near Las Cruces, New Mexico to obtain soil water tension and water content data to investigate their spatial variability. A total of 455 sampling points were monitored along a grid consisting of 91 stations placed 1 m apart by 5 depths per station (at 0.3, 0.6, 0.9, 1.2 and 1.5 m below the surface). Post-irrigation tension and wetness measurements were recorded over 45 days at 11 time periods. Soil water tension was measured with tensiometers using a hand-held pressure transducer. A neutron probe was used to obtain volumetric water content. Using the observed wetness and tension data, unsaturated hydraulic conductivity values were derived (using a cubic spline function to estimate the gradient), and an exponential model was used to fit the calculated conductivity-tension curves to obtain hydraulic conductivity parameter values. The spatial and temporal variability of wetness, tension, saturated hydraulic conductivity and pore-size distribution parameters, and texture at the 0.3-m depth were examined using geostatistical techniques.The exponential model was found to inadequately describe the hydraulic conductivity/tension relationship for the full range of tension, particularly in the tension range near saturation. The derived values of the saturated hydraulic conductivity parameter were much greater than expected and do not correspond to reasonable saturated hydraulic conductivity values.All of the soil parameters studied exhibited large spatial variability horizontally and vertically in the field. Ranges of dependence determined from semivariogram analysis over the 44-day drainage period are 3–32 m for wetness, 6–34 m for soil water tension, 5–35 m for natural log of saturated hydraulic conductivity parameters, 5–11 m for pore-size distribution parameter, and 8–24 m for percent sand, silt and clay at the 0.3 m depth. An alternate hole-effect model is suggested to describe the texture semivariograms.It was determined that the variance of volumetric water content generally increased at each depth over the measured time periods, which is consistent with certain past field studies and a stochastic analysis of unsaturated flow in heterogeneous soils. Future research is recommended relating soil texture to soil hydrologic parameters with the goal of predicting soil behavior with less extensive sampling schemes.     

Evaluation of a low-cost transient mass measurement system in vehicle inspection and maintenance testing: results of a Gordon-Darby Study

A study was performed at a Gordon-Darby centralized inspection and maintenance (I/M) test lane in Phoenix, AZ, in December 1999 for the purpose of evaluating the accuracy of production Vehicle Mass Analysis System (VMAS) equipment relative to standard IM240 equipment. Simultaneous transient mass measurements were made on random vehicles using VMAS and IM240 systems on two test lanes during regular I/M testing. Cumulative mass emissions for 846 valid tests were correlated using least-squares regression analysis. Correlation indices were > 0.99 for both carbon monoxide (CO) and nitric oxide (NO) and 0.93 for hydrocarbon (HC), and the standard errors of regression were 1.38 g/mi, 0.123 g/mi, and 0.245 g/mi for CO, NO, and HC, respectively. These strong correlation results are reflected by high excess emission identification rates of 99.4% for CO, 99.3% for NO, and 94.5% for HC when applying final IM240 cut points with a < 2% error of commission for all pollutants.     

The application of ground penetrating radar attenuation tomography in a vadose zone infiltration experiment

Cross-borehole ground penetrating radar (XBGPR) is used in monitoring a long-term vadose zone infiltration experiment at a test site in Socorro, NM in order to examine contaminant transport in the vadose zone. XBGPR attenuation tomography is conducted in order to test the ability of using images of electromagnetic attenuation for hydrogeologic investigations. The results of four pre-infiltration attenuation inversions shows standard deviations below 0.1 Np/m, and demonstrate the consistency of the XBGPR tomography technique for making time-lapse observations. Correlation to the core records indicates that XBGPR attenuation tomograms provide high-resolution images of clay distribution in the vadose zone. Water infiltration at the ground surface was initiated in February 1999 at a constant rate of 2.7 cm/day, and continued at this rate throughout the data collection experiment. Time-lapse attenuation tomograms show that attenuation increases by approximately 0.3 Np/m during the water infiltration, and indicate a snowplow effect may be occurring where salts are dissolved by the water and concentrated at the front of the plume. Seasonal temperature changes may also cause changes in electromagnetic attenuation images, and masking the evidence of water infiltration. Thus caution must be taken when using time-lapse attenuation images to interpret the movement of a water plume during a long-term experiment as temperature changes.     

Aquatic microcosm assessment of the effects of tylosin on Lemna gibba and Myriophyllum spicatum

Tylosin is a macrolide antibiotic commonly used for therapeutic treatment and prophylaxis in livestock. As part of a larger ecotoxicological study, the potential phytotoxic effects of tylosin on the rooted macrophyte Myriophyllum spicatum and the floating macrophyte Lemna gibba were assessed under semi-field conditions using 15 12 000-L microcosms. Concentrations of 0, 10, 30, 300 microg/L (n = 3), and 600, 1000, and 3000 microg/L (n = 1) were evaluated as part of separate ANOVA and regression analyses over an exposure period of 35 days. Fate of tylosin was monitored over time in the highest three treatments, where dissipation followed pseudo-first order kinetics with associated half-lives ranging from 9 to 10 days. For both M. spicatum and L. gibba, tylosin was found to cause no biologically significant changes to any endpoint assessed compared to controls at a Type I error rate of 0.1. However, subsequent power analyses revealed that there was generally insufficient power to declare that there were no significant differences at a Type II error rate of 0.2. Conclusions concerning biologically significant impacts were therefore further assessed based on other statistical criteria including comparisons of percent differences between replicated treatments and controls, minimum significant and minimum detectable differences, and coefficients of variation. Based on these criteria, at an ecological effect size of >20% change, tylosin was concluded to elicit no biologically or ecologically significant toxicity to M. spicatum or L. gibba. A hazard quotient assessment indicated that tylosin poses little risk to either species of macrophyte, with an HQ value calculated to be nearly three orders of magnitude below 1 (0.002).     

Formation and stability of polychlorinated biphenyl Pickering emulsions

An emulsion stabilized by colloidal suspensions of finely divided solids is known as a Pickering emulsion. The potential for polychlorinated biphenyls (PCBs) to form Pickering emulsions ex situ when in contact with powdered solids, such as clays and metal oxides, is investigated here. Bentonite, iron oxide and magnesium oxide dispersions proved to be robust Pickering emulsion stabilizers, whereas manganese oxide dispersions were not. Batch experiments revealed that emulsions can be formed using a moderately low energy input and can be stabilized with solid concentrations as low as 0.5 wt.%. For the base conditions (volumetric oil fraction (phi(oil))=30 vol.%; solid concentration (chi)=2 wt.%), the formed emulsions were indefinitely stable and the initial average droplet diameters varied from 80 to 258 mum, depending on the solid used in the colloidal dispersion. The average droplet size varied at early time, but for most conditions stabilized to a steady-state value 1 week after preparation. The effect of Ostwald ripening was limited. At greater than 0.5 wt.% concentration, the efficiency of the solid dispersion as a stabilizer was dependant on the volumetric oil fraction but not on the solid concentration. Generally, systems with volumetric oil fractions outside of the 20-70 vol.% range were unstable. The emulsions' droplet stability, average droplet size and size distribution were observed to vary as a function of the amount of energy provided to the system, the volumetric oil fraction, and the concentration of the solid in the aqueous dispersion. It is hypothesized that drilling through fractured rock in the immediate vicinity of dense, non-aqueous phase liquid (DNAPL) PCBs may provide both the energy and solid material necessary to form Pickering emulsions.     

Review of light-duty diesel and heavy-duty diesel gasoline inspection programs

Emissions from diesel vehicles and gas-powered heavy-duty vehicles are becoming a new focus of many inspection and maintenance (I/M) programs. Diesel particulate matter (PM) is increasingly becoming more recognized as an important health concern, while at the same time, the public awareness of diesel PM emissions because of their visibility have combined to increase the focus on diesel emissions in the United States. This has resulted in an increased interest by some states in including heavy-duty vehicle testing in their I/M program. This paper provides an overview of existing I/M programs focused on testing light-duty diesel vehicles, heavy-duty diesel vehicles, and heavy-duty gasoline vehicles (HDGVs). Information on 39 I/M programs in 27 different states in the United States plus 9 international inspection programs is included. Information on the status of diesel emissions technology and current test procedures is also presented. The goal is to provide useful information for air quality managers as they work to decide whether such I/M programs would be worth pursuing in their respective areas and in evaluating the emissions measurement technology to be used in the program. Testing of HDGVs is generally limited to idle testing, because dynamometer testing of these vehicles is not practical, and most were not certified on a chassis basis. Testing of diesel vehicles has mostly been limited to SAE J1667 "snap-idle" opacity testing. Cost-effective technology for measuring diesel emissions currently does not exist, and, therefore, opacity-type measurements, although not effective at reducing the pollutants of most significant health concern, will continue to be used.