单甲脒水中溶解度及正辛醇／水分配系数的测定

有毒有机化合物在水中的溶解度(WS)及正辛醇/水分配系数(K_(ow)),是描述其在环境中行为的两个重要物理化学参数。本文用溶解度平衡曲线法和振荡法,测得单甲脒在水中的溶解度为21.8±1.3mg/1(25℃),其在正辛醇/水中的分配系数lgK_(ow)为2.92±0.06。     

新疆土壤盐渍化成因及其防治对策研究

论述了新疆土壤盐渍化形成的地质、地貌、土壤质地和人为灌溉方式不合理等原因,说明土壤盐渍化是一种自然现象。通过调查,目前新疆盐渍化土壤主要有稳定脱盐型、脱盐聚盐混合型、脱盐聚盐反复型、持续聚盐型和灌溉聚盐型,其中脱盐聚盐混合型和脱盐聚盐反复型分布最为广泛,稳定脱盐型仅分布于竖井排灌区。总结了新疆土壤盐渍化的治理研究过程及国内外防治土壤盐渍化的措施,提出了竖井排灌工程是防治新疆土壤盐渍化最有效的措施。通过工程实例,证明了竖井排灌具有降低地下水位和灌溉作用,且经济效益明显。     

土壤环境中砷污染的危害及其研究进展

本文综述了砷污染的危害及其形成原因，介绍了国内外土壤砷污染研究的现状，展望了21世纪砷污染研究的发展趋势．     

农药在土壤中迁移的研究方法

农药对地下水的污染已日益为人们密切关注，本文详细介绍了用土壤柱和土壤薄层层析法研究农药在土壤迁移行为用于预测或评价农药对地下水污染程度的研究方法。     

土壤污染研究现状与趋势

简要介绍了土壤污染研究领域的主要内容 ,归纳了土壤污染研究中一些主要方法。结合土壤污染发展特点 ,对今后土壤污染研究的重点方向作了一般性探讨。     

Characteristics and risk assessment of organochlorine pesticide residues in surface sediments collected at the Qingshitan Reservoir

ABSTRACT

An ultrasonic extraction – gas chromatography – electron capture detector analytical method was used to measure the concentration and types of organochlorine (OC) pesticides in sediment to obtain a better understanding of the characteristics and hidden ecological risks associated with OC pesticide exposure in surface sediment of the Qingshitan Reservoir. Fifteen types of OC pesticides were detected in the sediment, and the sum concentration of these chemicals was in the 149.32–490.19 ng/g range (mean value: 319.39 ng/g). The concentrations of detected OC pesticides occurred in the following order: hexachlorohexanes (HCHs) (mean value: 200.17 ng/g) > DDTs (mean value: 36.92 ng/g) > heptachlors (mean value: 32.74 ng/g) > methoxychlor (mean value: 24.13 ng/g). There was a 100% detection rate for HCH isomers, and their concentrations occurred in the following order: β-HCH > δ-HCH > γ-HCH > α-HCH. β-HCH was the main component of HCHs. Ratios between α-HCH/γ-HCH and β-/(α+γ)-HCH were used to investigate the sources of pollution. Most of the surveyed areas were polluted by lindane, which originated from past pesticide residue usage, and no new inputs of HCHs were found. DDT was the major component of the DDTs, and accounted for 52%–87% of the DDTs. The ratios of (DDE+DDD)/DDT at all sample collection points were less than 1, indicating that degradation rate of DDTs in sediment was low and there was a new input of DDTs in these surveyed areas. The ratio of DDD/DDE was less than 1 at most of the sample collection points, indicating that the degradation of DDT in the sediments primarily took place under aerobic conditions. Comparison of OC pesticide residual levels in the underwater sediment collected at the Qingshitan Reservoir to other states and countries showed the pollution level of these chemicals of the Qingshitan Reservoir was relatively high. The ecological risk was assessed based on guideline values of effects range-low (ERL) and effects range-medium (ERM). The results showed that DDD, DDE, DDTs and endrin residues in the sediment posed a moderate ecological risk, but DDT and γ-HCH showed high ecological risk. These OC pesticides might adversely affect biological systems, and need to be addressed.     

改性稻草吸附铜离子的热力学研究

研究表明稻草改性后吸附铜离子的能力得到很大提高。在4种温度下（15、27、37、50℃）,改性稻草吸附铜离子的最大吸附量分别为1．10、1．24、1．34、1．50mmol／g。不同温度下,吸附自由能△G大大小于零,吸附过程具有强烈的自发趋势。吸附焙△H和吸附熵△S都大于零,吸附过程是熵增加推动的。     

竖井排灌工程对环境影响的研究

新疆阿克苏地区乌什县依麻木竖井排灌工程是根据国务院批准的<塔里木河近期综合规划报告>、<阿克苏河流域灌区节水改造工程五年实施方案>中提出的在阿克苏河流域内新建的竖井排灌工程项目.项目的实施必将给乌什县秋格尔灌区的环境带来一定程度的影响.在系统地分析了项目区环境现状的基础上,从项目施工、水资源利用、地下水水位、灌区土壤盐渍化、社会环境等方面详细研究了工程实施后对灌区环境的影响.分析认为:竖井排灌工程不会对灌区的环境造成大的影响;不会影响灌区地下水资源的利用,相反还朝有利的方向发展;不会导致灌区地下水位的持续下降,更不会造成地下水资源的枯竭;工程的实施可以改善灌区内的土壤盐渍化问题.竖井排灌工程产生的灌溉效益达545.22×104元.最后为灌区的可持续发展提出了建议.      

O_3/木屑强化SBR法处理垃圾渗滤液的研究

木屑作为强化剂加入SBR反应器中,采用O3+SBR强化生化处理法组合工艺对垃圾渗滤液进行处理,结果表明:臭氧前处理垃圾渗滤液时,60 min内,空气流量为400 mL/min,臭氧浓度为10.4 mg/L时,垃圾渗滤液COD降低42%。加入木屑作为SBR强化剂,可在进水垃圾渗滤液COD为4 200 mg/L,有机负荷达到1.7 kg/(kg.d)时,COD的去除率稳定在80%,二级强化法串联使用,出水水质达到国家污水综合排放一级排放标准。