Sixteen experimenmtal plots (5 m x 6 m = 30 m2) were designed with four different levels of heavy metals (HMs) concentration in soil. The concentrations of heavy metals in soils, and paddy plant during the different periods of growth were investigated. A relationship between the total HM content in plants and the HM level in soil was found for a wide range of concentrations. The exchangeable fraction of HMs extracted with 1 M MgCl2 solution according to Tessier's method increased correlation with the dosage of supplemented HMs, then decreased as time went on. The time-related variation of exchangeable HMs in soil demonstrated that the amount of effective HMs taken up by paddy differed at various growth phases. The amount of HMs accumulated in different parts of paddy followed the order of root > stem > grain, leaf. The transportation potential of the HMs in paddy in present study followed the order of Zn, Cr > Cd, Cu > Pb. The HM content in root, stem and leaf of paddy plant (dry weight) was low at time of seedling. The concentration in the root increased sharply at time of tillering, decreased thereafter. The concentrations in stem and leaf reached the highest at time of tillering, then decreased, while rose slightly at following time. 相似文献
In present study, atmospheric particles from Shanghai, the biggest city and the most important industrial base in China, were analyzed for polybrominated diphenyl ethers (PBDEs) and Dechlorane Plus (DP). Concentrations of ∑(20)PBDEs and DP both exhibited the changing trend of industrial area > urban areas. Jiading District had the highest levels of particulate PBDEs and DP with values of 744 ± 152 pg/m(3) and 5.48 ± 1.28 pg/m(3), respectively. Compared with similar data in other areas of the world, PBDEs in Shanghai were at medium pollution level, while DP was at lower level, which reflected their different production and use in Shanghai. The results from multiple linear regression analysis suggested that deca-BDE mixture was the most important contributor of particulate PBDEs in Shanghai. The fractions of anti-DP showed no significant differences to those of the technical mixtures (p > 0.05), which suggested that no obviously stereoselective process occurred in ambient air around Shanghai. 相似文献
Using molasses wastewater as partial acidifying agent, a new Fenton-like catalyst (ACRMsm) was prepared through a simple process of acidification and calcination using red mud as main material. With molasses wastewater, both the free alkali and the chemically bonded alkali in red mud were effectively removed under the action of H2SO4 and molasses wastewater, and the prepared ACRMsm was a near-neutral catalyst. The ACRMsm preparation conditions were as follows: for 3 g of red mud, 9 mL of 0.7 mol/L H2SO4 plus 2 g of molasses wastewater as the acidifying agent, calcination temperature 573 K, and calcination time 1 h. Iron phase of ACRMsm was mainly α-Fe2O3 and trace amount of carbon existed in ACRMsm. The addition of molasses wastewater not only effectively reduced the consumption of H2SO4 in acidification of red mud but also resulted in the generation of carbon and significantly improved the distribution of macropore in prepared ACRMsm. It was found that near-neutral pH of catalyst, generated carbon, and wide distribution of macropore were the main reasons for the high catalytic activity of ACRMsm. The generated carbon and wide distribution of macropore were entirely due to the molasses wastewater added. In degradation of orange II, ACRMsm retained most of its catalytic stability and activity after five recycling times, indicating ACRMsm had an excellent long-term stability in the Fenton-like process. Furthermore, the performance test of settling showed ACRMsm had an excellent settleability. ACRMsm was a safe and green catalytic material used in Fenton-like oxidation for wastewater treatment.