全文获取类型
收费全文 | 22060篇 |
免费 | 267篇 |
国内免费 | 231篇 |
专业分类
安全科学 | 704篇 |
废物处理 | 967篇 |
环保管理 | 3620篇 |
综合类 | 2791篇 |
基础理论 | 5716篇 |
环境理论 | 9篇 |
污染及防治 | 6151篇 |
评价与监测 | 1439篇 |
社会与环境 | 992篇 |
灾害及防治 | 169篇 |
出版年
2022年 | 143篇 |
2021年 | 194篇 |
2020年 | 124篇 |
2019年 | 192篇 |
2018年 | 307篇 |
2017年 | 322篇 |
2016年 | 498篇 |
2015年 | 430篇 |
2014年 | 605篇 |
2013年 | 1992篇 |
2012年 | 739篇 |
2011年 | 979篇 |
2010年 | 777篇 |
2009年 | 875篇 |
2008年 | 1051篇 |
2007年 | 1093篇 |
2006年 | 957篇 |
2005年 | 777篇 |
2004年 | 810篇 |
2003年 | 772篇 |
2002年 | 751篇 |
2001年 | 826篇 |
2000年 | 655篇 |
1999年 | 393篇 |
1998年 | 298篇 |
1997年 | 278篇 |
1996年 | 328篇 |
1995年 | 324篇 |
1994年 | 311篇 |
1993年 | 289篇 |
1992年 | 268篇 |
1991年 | 223篇 |
1990年 | 249篇 |
1989年 | 223篇 |
1988年 | 209篇 |
1987年 | 203篇 |
1986年 | 185篇 |
1985年 | 179篇 |
1984年 | 215篇 |
1983年 | 214篇 |
1982年 | 198篇 |
1981年 | 214篇 |
1980年 | 175篇 |
1979年 | 175篇 |
1978年 | 129篇 |
1977年 | 112篇 |
1976年 | 97篇 |
1975年 | 107篇 |
1973年 | 98篇 |
1972年 | 104篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
641.
Spalinger SM von Braun MC Petrosyan V von Lindern IH 《Environmental monitoring and assessment》2007,130(1-3):57-72
House dust has been identified as a major exposure medium for lead (Pb) in children. High levels of Pb in soil and house dust
have been recorded at the Bunker Hill Superfund Site (BHSS) in northern Idaho, an historic mining and smelting district. Soil
and dust remediation at the site was required; however, regional background soil and dust Pb levels had not been well characterized.
The objective of this survey was to determine background house dust Pb levels and to compare those levels with concentrations,
and dust and Pb loading rates measured at the BHSS. Soil and house dust samples were collected in five towns demographically
similar to the BHSS but unaffected by the mining industry. The background concentrations and loading rates were significantly
lower than those observed at the site. House age was a significant factor affecting background soil and house dust Pb concentrations
and loading rates. 相似文献
642.
The temporal variability and bioaccumulation dynamics of C12–25 n-alkanes, isoprenoids and unresolved aliphatic hydrocarbons (UCM) were studied in a detritivorous fish (Sábalo: Prochilodus lineatus) collected from 1999 to 2005 in the sewage impacted Buenos Aires coastal area. Fish muscles contain huge amounts of n-C12–25 (165 ± 93, 70 ± 48 or 280 ± 134 μg g−1, dry, fresh and lipid weight, respectively) and UCM (931 ± 560, 399 ± 288 and 1567 ± 802 μg g−1) reflecting the chronic bioaccumulation of fossil fuels from sewage particulates. On a temporal basis, lipid normalized aliphatic concentrations peaked by the end of 2001–2002 during the rainiest period over the last four decades (1750 vs. 1083 ± 4.6 mm in 1999, 2004 and 2005), reflecting an enhanced exposition due to massive anthropogenic fluxes from Metropolitan Buenos Aires in wet years. The hydrocarbon composition in fish muscles is enriched in n-C15–17 and isoprenoids relative to a fresh crude oil and settling particulates, with fresher signatures during the 2001–2002 maxima. Fish/settling material bioaccumulation factors (BAFs: 0.4–6.4 dry weight or 0.07–0.94 lipid-organic carbon) plotted against Kow showed a parabolic pattern maximizing at n-C14–18 and isoprenoids. The optimal bioaccumulation window corresponds to highly hydrophobic (log Kow: 7.2–9.9), intermediate-size C14–18 n-alkanes and C15–20 isoprenoids (MW: 198–282; length: 17.9 to 25.4 Å) with melting points ranging from −19.8 to 28 °C. The uptake efficiency is inversely correlated to melting points and increased from 75% for n-C25 to above 90% for n-C14–15 and isoprenoids. 相似文献
643.
HPLC-DAD, HPLC-MS/MS, GC-MS and spectrophotometric methods are employed to investigate the degradation process of sodium 1-amino-5-naphthalene sulfonate (1A5NS) aqueous solutions, when exposed to sunlight and UV-lamp (254 nm) irradiations. Experimental results show that both sunlight and 254 nm UV-lamp irradiations destroy the chemical and give rise to major degradation products, characterised by the same m/z ratios. Degradation times are lower for sunlight irradiation, for which a t(1/2) value of 137.4 min has been evaluated, in comparison with the value of t(1/2) of 26.8 min, observed for UV-lamp irradiation. The degradation pathway and the structures of the degradation products are proposed. 相似文献
644.
In this work, the treatment of an actual industrial waste with three advanced oxidation processes (AOP) has been studied: conductive-diamond electrooxidation (CDEO), ozonation and Fenton oxidation. The wastewater comes from olive-oil mills (OMW) and contains a COD of nearly 3000 mg dm(-3). CDEO allowed achieving the complete mineralization of the waste with high current efficiencies. Likewise, both ozonation and Fenton oxidation were able to treat the wastes, but they obtained very different results in terms of efficiency and mineralization. The accumulation of oxidation-refractory compounds as final products excludes the use of ozonation and Fenton oxidation as a sole treatment technology. This confirms that besides the hydroxyl-radical mediated oxidation, CDEO combines other important oxidation processes such as the direct electro-oxidation on the diamond surface and the oxidation mediated by other electrochemically formed compounds generated on this electrode. 相似文献
645.
This work has examined cobalt(II) binding by a variety of solid humic acids (HAs) isolated from peat, plant and soil sources at temperatures down to 60K. The results confirm that X-ray absorption near-edge spectroscopy (XANES) measurements cannot distinguish between aquo and carboxylato ligands in the inner coordination sphere of Co(II). However, between 1 and 2 inner-sphere carboxylato ligands can be detected in all the peat, plant and soil-derived HA samples by extended X-ray absorption fine structure (EXAFS) measurements, indicating inner-sphere coordination of HA-bound Co(II). The precision of C(carboxylate) detection is limited by the extent and quality of the data and the contribution from inner-sphere O to the Fourier transformed peaks used to detect carbon. Putative chelate ring formation is consistent with a relatively negative entropy change in step A, the stronger Co(II) binding step by HA functional groups, and could relate to 'non-exchangeable' metal binding by HSs. 相似文献
646.
Polychlorinated biphenyl contamination trends in Lake Hartwell, South Carolina (USA): sediment recovery profiles spanning two decades 总被引:1,自引:0,他引:1
To assess the ca. 20-year polychlorinated biphenyl (PCB) contamination trends in Lake Hartwell, SC, sediment cores from the Twelve Mile Creek arm were collected in July 2004 at two sites (G30 and G33) first sampled in the mid-1980s. Congener-specific PCB data as a function of depth from the sediment-water interface for the 2004 sediment samples were compared to data obtained from 1987 and 1998 samples taken from the same locations. Despite modest decreases in total PCB levels near the G30 sediment-water interface, historical increases in average degrees of chlorination may elevate the overall toxic risk at this site. Unlike G30, the more rapid recovery in the near-surface sediment of G33 suggests that the effectiveness of the U.S. EPA natural attenuation record of decision is site-specific and is unlikely to result in uniform surface sediment recovery throughout the most contaminated regions of Lake Hartwell. 相似文献
647.
Kröger R Holland MM Moore MT Cooper CM 《Environmental pollution (Barking, Essex : 1987)》2007,146(1):114-119
The beneficial uptake of nutrients by wetland plants is countered to some extent by nutrient release back into the aquatic environment due to vegetative die-back. This current study examined whether Leersia oryzoides, a common wetland plant, exhibits luxury uptake of nutrients from simulated farm runoff. The study also tested whether with subsequent decomposition, these nutrients are released back into the water column. When exposed to elevated (>2mg/L N and P) runoff, L. oryzoides assimilated significantly higher concentrations of nitrogen (p<0.001) and phosphorus (p<0.001) in above-ground biomass as compared to non-enriched treatments (<0.05 mg/L N and P). Subsequently, senescence of enriched above-ground biomass yielded significantly higher concentrations of phosphorus (2.19+/-0.84 mg P/L). Using L. oryzoides as our model, this study demonstrates nitrogen and phosphorus sequestration during the growing season and release of phosphorus in the winter. 相似文献
648.
Essential and non-essential element concentrations in two sleeper shark species collected in arctic waters 总被引:1,自引:0,他引:1
McMeans BC Borgå K Bechtol WR Higginbotham D Fisk AT 《Environmental pollution (Barking, Essex : 1987)》2007,148(1):281-290
A number of elements/metals have increased in arctic biota and are of concern due to their potential toxicity. Most studies on elements in the Arctic have focused on marine mammals and seabirds, but concentrations in the Greenland shark (Somniosus microcephalus) and Pacific sleeper shark (Somniosus pacificus), the only two shark species known to regularly inhabit arctic waters, have never been reported. To address this data gap, concentrations and patterns of 25 elements were analyzed in liver of Greenland sharks collected about Cumberland Sound (n=24) and Pacific sleeper sharks collected about Prince William Sound (n=14). Several non-essential elements differed between species/locations, which could suggest geographical exposure differences or ecological (e.g., diet) differences between the species. Certain essential elements also differed between the two sleeper sharks, which may indicate different physiological requirements between these closely related shark species, although information on such relationships are lacking for sharks and fish. 相似文献
649.
Makris KC Shakya KM Datta R Sarkar D Pachanoor D 《Environmental pollution (Barking, Essex : 1987)》2007,148(1):101-106
The efficiency of vetiver grass (Vetiveria zizanioides) in removing 2,4,6-trinitrotoluene (TNT) from aqueous media was explored in the presence of a common agrochemical, urea, used as a chaotropic agent. Chaotropic agents disrupt water structure, increasing solubilization of hydrophobic compounds (TNT), thus, enhancing plant TNT uptake. The primary objectives of this study were to: (i) characterize TNT absorption by vetiver in hydroponic media, and (ii) determine the effect of urea on chemically catalyzing TNT uptake by vetiver grass in hydroponic media. Results showed that vetiver exhibited a high TNT uptake capacity (1.026 mgg(-1)), but kinetics were slow. Uptake was considerably enhanced in the presence of urea, which significantly (p<0.001) increased the 2nd-order reaction rate constant over that of the untreated (no urea) control. Three major TNT metabolites were detected in the roots, but not in the shoot, namely 1,3,5-trinitrobenzene, 4-amino 2,6-dinitrotoluene, and 2-amino 4,6-dinitrotoluene, indicating TNT degradation by vetiver grass. 相似文献
650.
The apparent water solubility of pentachlorophenol was measured at pH=6 and at 25 degrees C in pure water, aqueous solutions of three salts (NaCl, KNO(3) and CaCl(2) at 0.010, 0.10 and 1.0M) and in aqueous solutions of three fulvic acids samples extracted from a natural soil (sFA), composted sewage sludge (csFA) and composted livestock's material (lsFA). A solubility enhancement method was developed for the measurement of partition coefficients (K(oc), L/kg organic carbon). Pentachlorophenol associates strongly with the fulvic acid samples and the calculated K(oc) were the following (averages and standard deviations): (sFA) (211+/-22) x 10(2), (csFA) (253+/-26) x 10(2), (lsFA) (235+/-10) x 10(2). For comparison purposes the K(oc) for pyrene were also calculated for the three FA samples and were the following: (sFA) (119+/-10) x 10(2), (csFA) (239+/-21) x 10(2), (lsFA) (92+/-10) x 10(2). The analysis of variance (one-way ANOVA) of the effect of the type of FA sample on the solubilization of pentachlorophenol and pyrene shows that this factor causes significant differences on the aqueous solubilization of these two organic substances. 相似文献