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831.
Caught Between a Rock and a Hard Place: Reducing Shoreline Remediation Safety Hazards by Taking a Safety‐Based Approach to Fuel and Oil Spill Cleanup 下载免费PDF全文
Turlough F. Guerin 《补救:环境净化治理成本、技术与工艺杂志》2017,27(2):99-110
Fuel spills onto land or a hardstand area is one thing. Losing several metric tonnes of fuel onto an inaccessible rock batter that is in proximity to the open ocean is entirely different. The upshot of such loss of containment events need not be the disaster that an initial cursory assessment would have you think. By looking through a safety lens, this article demonstrates how developing a realistic model of the resulting contamination can help navigate an effective remediation program that meets the expectations of multiple stakeholders. Further, the mine where the spill occurred was able to continue using the impacted loading facility, therefore, enabling business continuity. ©2017 Wiley Periodicals, Inc. 相似文献
832.
833.
The study aims to compare the detection of 16S rRNA gene of Dehalococcoides species and the microcosm study for biotransformation in predicting reductive dechlorination of chlorinated ethenes in ground water at hazardous waste sites. A total of 72 ground water samples were collected from 12 PCE or TCE contaminated sites in the United States. The samples were analyzed and used to construct microcosms in the laboratory. The results showed that the presence of Dehalococcoides DNA was well associated with dechlorination to ethene in the field. Nearly half of the wells where Dehalococcoides DNA was detected had ethene as a dechlorination end product. In comparison, for ground water samples of 16 wells where ethene was detected, ethene was produced in 11 of the corresponding microcosms. For most microcosms, during two years of incubation, dechlorination was less extensive than that observed in the field. 相似文献
834.
Vinicius F. Farjalla André M. Amado Albert L. Suhett Frederico Meirelles-Pereira 《Environmental science and pollution research international》2009,16(5):531-538
Background, aim, and scope Dissolved humic substances (HS) usually comprise 50–80% of the dissolved organic carbon (DOC) in aquatic ecosystems. From
a trophic and biogeochemical perspective, HS has been considered to be highly refractory and is supposed to accumulate in
the water. The upsurge of the microbial loop paradigm and the studies on HS photo-degradation into labile DOC gave rise to
the belief that microbial processing of DOC should sustain aquatic food webs in humic waters. However, this has not been extensively
supported by the literature, since most HS and their photo-products are often oxidized by microbes through respiration in
most nutrient-poor humic waters. Here, we review basic concepts, classical studies, and recent data on bacterial and photo-degradation
of DOC, comparing the rates of these processes in highly humic ecosystems and other aquatic ecosystems.
Materials and methods We based our review on classical and recent findings from the fields of biogeochemistry and microbial ecology, highlighting
some odd results from highly humic Brazilian tropical lagoons, which can reach up to 160 mg C L−1.
Results and discussion Highly humic tropical lagoons showed proportionally lower bacterial production rates and higher bacterial respiration rates
(i.e., lower bacterial growth efficiency) than other lakes. Zooplankton showed similar δ13C to microalgae but not to humic DOC in these highly humic lagoons. Thus, the data reviewed here do not support the microbial
loop as an efficient matter transfer pathway in highly humic ecosystems, where it is supposed to play its major role.
In addition, we found that some tropical humic ecosystems presented the highest potential DOC photo-chemical mineralization
(PM) rates reported in the literature, exceeding up to threefold the rates reported for temperate humic ecosystems. We propose
that these atypically high PM rates are the result of a joint effect of the seasonal dynamics of allochthonous humic DOC input
to these ecosystems and the high sunlight incidence throughout the year. The sunlight action on DOC is positive to microbial
consumption in these highly humic lagoons, but little support is given to the enhancement of bacterial growth efficiency,
since the labile photo-chemical products are mostly respired by microbes in the nutrient-poor humic waters.
Conclusions HS may be an important source of energy for aquatic bacteria in humic waters, but it is probably not as important as a substrate
to bacterial growth and to aquatic food webs, since HS consumption is mostly channeled through microbial respiration. This
especially seems to be the case of humic-rich, nutrient-poor ecosystems, where the microbial loop was supposed to play its
major role. Highly humic ecosystems also present the highest PM rates reported in the literature. Finally, light and bacteria
can cooperate in order to enhance total carbon degradation in highly humic aquatic ecosystems but with limited effects on
aquatic food webs.
Recommendations and perspectives More detailed studies using C- and N-stable isotope techniques and modeling approaches are needed to better understand the
actual importance of HS to carbon cycling in highly humic waters. 相似文献
835.
L.J. Deacon L.J. Pankhurst G.H. Drew E.T. Hayes S. Jackson P.J. Longhurst J.W.S. Longhurst J. Liu S.J.T. Pollard S.F. Tyrrel 《Atmospheric environment (Oxford, England : 1994)》2009,43(35):5698-5701
Information on the particle size distribution of bioaerosols emitted from open air composting operations is valuable in evaluating potential health impacts and is a requirement for improved dispersion simulation modelling. The membrane filter method was used to study the particle size distribution of Aspergillus fumigatus spores in air 50 m downwind of a green waste compost screening operation at a commercial facility. The highest concentrations (approximately 8 × 104 CFU m−3) of culturable spores were found on filters with pore diameters in the range 1–2 μm which suggests that the majority of spores are emitted as single cells. The findings were compared to published data collected using an Andersen sampler. Results were significantly correlated (p < 0.01) indicating that the two methods are directly comparable across all particles sizes for Aspergillus spores. 相似文献
836.
John E. Yorks Anne M. Thompson Everette Joseph Sonya K. Miller 《Atmospheric environment (Oxford, England : 1994)》2009,43(11):1827-1838
Ozone profiles are often used to investigate day-to-day and year-to-year variability in origins of free tropospheric ozone. With this in mind, more than 50 ozonesonde launches were conducted in Beltsville, MD, during the summers of 2004 through 2007. Budgets of free tropospheric ozone were calculated for each ozone profile in the four summers using a laminar identification (LID) method and unusual episodes were analyzed with respect to meteorological variables. The laminar method showed that stratosphere-to-troposphere transport (ST) accounted for greater than 50% of the free tropospheric ozone column on 17% of days sampled, a more pronounced influence than regional convective and lightning (RCL) sources. The ST origins were confirmed with trajectories, and tracers (water vapor and potential vorticity). The amount of free tropospheric ozone from ST and RCL sources varied from year-to-year (up to 13%) and can be explained by differences in mean meteorological patterns. On average, almost 30% of the free tropospheric column was attributed to ST influence, about twice as much as RCL, although the LID method may not capture weeks-old lightning influences as in a chemical model. The prevalence of ST ozone in summertime Beltsville soundings was similar to six sounding sites in the IONS-04 campaign [Thompson, A.M., et al., 2007b. Intercontinental Transport Experiment Ozonesonde Network Study (IONS, 2004): 1. Summertime upper tropospheric/lower stratosphere ozone over northeastern North America. J. Geophys. Res. 112, D12S12; Thompson, A.M., et al., 2007c. Intercontinental Transport Experiment Ozonesonde Network Study (IONS, 2004): 2. Tropospheric ozone budgets and variability over northeastern North America. J. Geophys. Res. 112, D12S13.] and to statistics from a 30 year climatology of European soundings [Collette, A., Ancellet, G., 2005. Impact of vertical transport processes on the tropospheric ozone layering above Europe. Part II: Climatological analysis of the past 30 years. Atmos. Environ. 39, 5423–5435]. The Beltsville record also demonstrated the value of soundings for air quality forecasting in an urban area. The 22 nighttime soundings collected over Beltsville in 2004–2007 can be divided into distinct polluted and unpolluted subsets, the former 20 ppbv higher in residual layer ozone (1 km) than the latter. These distinctions propagated to daytime differences of 10 ppbv at the surface in the Washington, DC, area, with the high-ozone residual layers leading to non-attainment of the National Ambient Air Quality Standard for ozone. More frequent ozone observations aloft appear essential for better understanding ozone variability and for enabling air quality modelers to achieve more accurate ozone forecasts. 相似文献
837.
838.
Collin A. Eagles-Smith Joshua T. Ackerman John Y. Takekawa 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):1993-2002
We evaluated mercury (Hg) in five waterbird species representing three foraging guilds in San Francisco Bay, CA. Fish-eating birds (Forster's and Caspian terns) had the highest Hg concentrations in thier tissues, but concentrations in an invertebrate-foraging shorebird (black-necked stilt) were also elevated. Foraging habitat was important for Hg exposure as illustrated by within-guild differences, where species more associated with marshes and salt ponds had higher concentrations than those more associated with open-bay and tidal mudflats. Importantly, Hg concentrations increased with time spent in the estuary. Surf scoter concentrations tripled over six months, whereas Forster's terns showed an up to 5-fold increase between estuary arrival and breeding. Breeding waterbirds were at elevated risk of Hg-induced reproductive impairment, particularly Forster's terns, in which 48% of breeding birds were at high risk due to their Hg levels. Our results highlight the importance of habitat and exposure timing, in addition to trophic position, on waterbird Hg bioaccumulation and risk. 相似文献
839.
M.A. Taggart R. Mateo F. Bahrami A.A. Meharg 《Environmental pollution (Barking, Essex : 1987)》2009,157(3):946-954
Arsenic is known to accumulate with iron plaque on macrophyte roots. Three to four years after the Aznalcóllar mine spill (Spain), residual arsenic contamination left in seasonal wetland habitats has been identified in this form by scanning electron microscopy. Total digestion has determined arsenic concentrations in thoroughly washed ‘root + plaque’ material in excess of 1000 mg kg−1, and further analysis using X-ray absorption spectroscopy suggests arsenic exists as both arsenate and arsenite. Certain herbivorous species feed on rhizomes and bulbs of macrophytes in a wide range of global environments, and the ecotoxicological impact of consuming arsenic rich iron plaque associated with such food items remains to be quantified. Here, greylag geese which feed on Scirpus maritimus rhizome and bulb material in areas affected by the Aznalcóllar spill are shown to have elevated levels of arsenic in their feces, which may originate from arsenic rich iron plaque. 相似文献
840.
F. Wang 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):2082-2090
A multi-trophic, multi-exposure phase assessment approach was applied to characterize the toxicity of sediments collected from two rivers in Guiyu, China, an e-waste recycling centre. Elutriate toxicity tests (bacterium Vibrio fischeri and microalga Selenastrum capricornutum) and whole sediment toxicity test (crustacean Heterocypris incongruens) showed that most sediments exhibited acute toxicity, due to elevated heavy metals and PAHs levels, and low pH caused by uncontrolled acid discharge. The survival rates of crustaceans were negatively (p < 0.05) correlated with total PAHs in sediments (411-1755 mg kg−1); EC50s of V. fischeri on the elutriates were significantly correlated with elutriate pH (p < 0.01). Significant (p < 0.05) correlations between the induction of hepatic metallothionein in tilapia (Oreochromis mossambicus) and metal concentrations (Cu, Zn, Pb) in sediments were also observed, when fish were fed with diets containing sediment. The results showed that uncontrolled e-waste recycling activities may bring adverse effects to local aquatic ecosystem. 相似文献