MOBILITY AND AQUATIC TOXICITY OF COPPER IN AN URBAN WATERSHED1

ABSTRACT: Abundant use of copper based products has resulted in increased violation of copper water quality criteria in runoff from urban storm water systems. The objectives of this work were to understand the mobility and toxicity of copper in an urban watershed and to apportion the amount of copper entering the freshwater receiving stream from different urban land covers using a mass balance approach. Sixteen rainfall events collected from the University of Connecticut study watershed between August 1998 and September 2000 were analyzed to assess copper flux in an urban storm water system. Mean flow weighted dissolved copper concentrations observed in the study for copper based architectural material runoff, pervious area runoff, impervious area runoff, and in the receiving stream were 1210 ± 840, 9 ± 3, 8 ± 2, and 14 ± 7 μg/L, respectively. Mean dissolved copper concentrations in the receiving stream exceeded Connecticut's water quality criteria. Despite exceeding the dissolved concentration based criteria, cupric ion concentrations at the system outlet remained below 0.05 μg/L for all storms analyzed, and no acute toxicity (using Daphnia pulex as the test organism) was measured in samples collected from the stream.     

The role of motorized boats in fishers’ productivity in marine protected versus non-protected areas in Davao Gulf,Philippines

Environment, Development and Sustainability - The Philippine fisheries sector continues to play a critical role in the livelihood of coastal households; however, the country’s fisheries...     

Trace-metal contamination in the glacierized Rio Santa watershed,Peru

The objective of this research is to characterize the variability of trace metals in the Rio Santa watershed based on synoptic sampling applied at a large scale. To that end, we propose a combination of methods based on the collection of water, suspended sediments, and riverbed sediments at different points of the watershed within a very limited period. Forty points within the Rio Santa watershed were sampled between June 21 and July 8, 2013. Forty water samples, 36 suspended sediments, and 34 riverbed sediments were analyzed for seven trace metals. The results, which were normalized using the USEPA guideline for water and sediments, show that the Rio Santa water exhibits Mn concentrations higher than the guideline at more than 50% of the sampling points. As is the second highest contaminating element in the water, with approximately 10% of the samples containing concentrations above the guideline. Sediments collected in the Rio Santa riverbed were heavily contaminated by at least four of the tested elements at nearly 85% of the sample points, with As presenting the highest normalized concentration, at more than ten times the guideline. As, Cd, Fe, Pb, and Zn present similar concentration trends in the sediment all along the Rio Santa.The findings indicate that care should be taken in using the Rio Santa water and sediments for purposes that could affect the health of humans or the ecosystem. The situation is worse in some tributaries in the southern part of the watershed that host both active and abandoned mines and ore-processing plants.     

Strategic climate policy with offsets and incomplete abatement: Carbon taxes versus cap-and-trade

This paper provides a first analysis of a “policy bloc” of fossil fuel importers which implements an optimal climate policy, faces a (non-policy) fringe of other fuel importers, and an exporter bloc, and purchases offset from the fringe. We compare a carbon tax and a cap-and-trade scheme for the policy bloc, in either case accompanied by an efficient offset mechanism for reducing emissions in the fringe. The policy bloc is shown to prefer a tax over a cap, since only a tax reduces the fuel export price and by more when the policy bloc is larger. Offsets are also more favorable to the policy bloc under a tax than under a cap. The optimal offset price under a carbon tax is below the tax rate, while under a cap and free quota trading the offset price must equal the quota price. The domestic carbon and offset prices are both higher under a tax than under a cap when the policy bloc is small. When the policy bloc is larger, the offset price can be higher under a cap. Fringe countries gain by mitigation in the policy bloc, more under a carbon tax since the fuel import price is lower.     

Our disappearing past: a GIS analysis of the vulnerability of coastal archaeological resources in California’s Santa Barbara Channel region

Coastal archaeological resources around the world often coincide with dense contemporary human populations and a rapidly changing physical environment. Projected sea level rise and urban expansion during the 21^st century threaten to destroy much of our global coastal archaeological heritage. In this study, we adapt an environmental vulnerability analysis to quantify the threats of modern development and sea level rise on archaeological sites in California’s Santa Barbara Channel region. Using spatial and statistical techniques, we create a Cultural Resource Vulnerability Index that combines environmental factors, current and projected urban footprints, and archaeological site positioning. We illustrate the importance of this method for targeting threatened archaeological sites for mitigation and salvage research. In the process, we highlight the significance of coastal archaeological sites for helping better understand contemporary environmental and cultural issues, underscoring the need to preserve or salvage these sites for their significant research value.     

Linking noninvasive genetic sampling and traditional monitoring to aid management of a trans-border carnivore population

Noninvasive genetic sampling has been embraced by wildlife managers and ecologists, especially those charged with monitoring rare and elusive species over large areas. Challenges arise when desired population measures are not directly attainable from genetic data and when monitoring targets trans-border populations. Norwegian management authorities count individual brown bears (Ursus arctos) using noninvasive genetic sampling but express management goals in the annual number of bear reproductions (females that produce cubs), a measure that is not directly available from genetic data. We combine noninvasive genetic sampling data with information obtained from a long-term intensive monitoring study in neighboring Sweden to estimate the number of annual reproductions by females detected within Norway. Most female brown bears in Norway occur near the border with neighboring countries (Sweden, Finland, and Russia) and their potential reproduction can therefore only partially be credited to Norway. Our model includes a simulation-based method that corrects census data to account for this. We estimated that 4.3 and 5.7 reproductions can be credited to females detected with noninvasive genetic sampling in Norway in 2008 and 2009, respectively. These numbers fall substantially short of the national target (15 annual reproductions). Ignoring the potential for home ranges to extend beyond Norway's borders leads to an increase in the estimate of the number of reproductions by -30%. Our study shows that combining noninvasive genetic sampling with information obtained from traditional intensive/invasive monitoring can help answer contemporary management questions in the currency desired by managers and policy makers. Furthermore, combining methodologies and thereby accounting for space use increases the accuracy of the information on which decisions are based. It is important that the information derived from multiple approaches is applicable to the same focal population and that predictions are cross-validated. When monitoring and management are constrained to administrative units, census data should be adjusted by discounting portions of individual space utilization that extend beyond the focal jurisdiction. Our simulation-based approach for making such an adjustment may be useful in other situations where management authorities target portions of trans-border populations.     

The role of off-farm employment in tropical forest conservation: labor, migration, and smallholder attitudes toward land in western Uganda

The potential for off-farm employment (OFE) to contribute significantly to forest conservation in the tropics is a widely held logic among donors, governments, and social scientists. While an aggregate level examination of OFE cases can support this logic, there is disagreement as to the operative aspects of specific linkages and assumptions. This study examines the case of the tea industry in western Uganda, and uses a combination of fieldwork and remote sensing to pursue a more nuanced examination of the role of migration and non-monetary aspects of OFE on forest conservation in both a national park and unprotected forest contexts. Results indicate that the tea industry does serve as an off-farm employer to a limited number of local smallholders but these benefits are offset by the industry's overwhelming dependence on migrant labor which sees OFE as temporary, then seeks to settle locally. There is also evidence that the tea industry is contributing to conservation efforts of Kibale National Park by unintentionally serving as a physical buffer zone, which inhibits both human encroachment on the park and wildlife encroachment on smallholder crops. The latter represents a site-specific phenomenon that holds much potential for future management plans of the area and exemplifies the importance of considering the site-specific circumstances associated with OFE development.