Sensitivity analysis of the asymptotic behavior of a model for the environmental movement of radionuclides

The asymptotic behavior of a linear compartment model for the environmental movement of radionuclides is investigated. Here, the expression asymptotic behavior is used to designate the behavior of q(t) as t → ∞, where q is the solution of a vector differential equation of the form dq/dt = h + Kq. The asymptotic behavior of such equations is described. For the model and conditions under consideration, each element of q converges monotonically to a steady-state value. A hydrologic system is defined and used to illustrate this behavior. An approach to sensitivity analysis employing Latin hypercube sampling, rank transformations and stepwise regression is presented and then applied to this system. A total of 20 independent variables is introduced and the following dependent variables are investigated for the various components of the system: amount of radionuclide present at steady state. concentration of radionuclide at steady state, and time required to reach 90% of steady state. Finally, an application of asymptotic behavior in the analysis of a hypothetical site for the geologic isolation of high-level radioactive waste is described and a brief discussion of differential sensitivity analysis is given.     

PCB congener-specific analysis: A critical evaluation of toxic levels in biota

Despite the fact that PCB congeners exhibit very different biochemical activities, it has been necessary, due to former difficulties in separation and quantitation, to assess toxic hazard to tissues in terms of the concentration of the PCB mixture present. This approach is justifiable provided that a dynamic equilibrium is established among all tissues for each congener. Recent biochemical studies, involving individual congeners indicate that this may not always be the case. Toxic PCB congeners, isostereomers of TCDD, are electron acceptors capable of binding to cytoplasmic protein (Ah receptor) and other cellular macromolecules associated with a particular tissue. Specific Congener analysis of snapping turtle tissues has indicated the possible selective disposition of 2,3,3′, 4,4′-pentachlorobiphenyl in the testes, a situation which may lead to a surreptious decrease in the population of that species, considering the longevity and wide distribution of these reptiles.     

Multi-level water governance – the case of the Morsa River Basin in Norway

Management of fresh water resources meets a range of often conflicting interests. Waterways usually run across political and administrative borders and hence make management difficult and collective action politically challenging. In order to meet these challenges, multi-level bioregional approaches to water management have been called for. Such an approach is institutionalised in the EU's Water Framework Directive (WFD). This paper presents the experiences of the Morsa water sub-district in southern Norway, a pilot for implementing the WFD. The paper discusses Morsa in the light of four principles for multi-level water governance: management on a bioregional scale; polycentric governance; public participation; and an experimental approach to water governance. Contrary to widely held assumptions that collective action in polycentric networks will be difficult because actors will follow their own narrow interests, the findings demonstrate how this is not an absolute truth, and how social action cannot be fully explained by rational action theories. The analysis concludes that the relative success of Morsa relates to a complex of factors, including openness of practices and active involvement of key actors, strong but including leadership, and a knowledge based ‘hybrid’ type of multi-level network combining horizontal and vertical network governance.     

Incidence and persistence of zoonotic bacterial and protozoan pathogens in a beef cattle feedlot runoff control vegetative treatment system

Determining the survival of zoonotic pathogens in livestock manure and runoff is critical for understanding the environmental and public health risks associated with these wastes. The occurrence and persistence of the bacterial pathogens Escherichia coli O157:H7 and Campylobacter spp. in a passive beef cattle feedlot runoff control-vegetative treatment system were examined over a 26-mo period. Incidence of the protozoans Cryptosporidium spp. and Giardia spp. was also assessed. The control system utilizes a shallow basin to collect liquid runoff and accumulate eroded solids from the pen surfaces; when an adequate liquid volume is attained, the liquid is discharged from the basin onto a 4.5-ha vegetative treatment area (VTA) of bromegrass which is harvested as hay. Basin discharge transported E. coli O157, Campylobacter spp., and generic E. coli into the VTA soil, but without additional discharge from the basin, the pathogen prevalences decreased over time. Similarly, the VTA soil concentrations of generic E. coli initially decreased rapidly, but lower residual populations persisted. Isolation of Cryptosporidium oocysts and Giardia cysts from VTA samples was infrequent, indicating differences in sedimentation and/or transport in comparison to bacteria. Isolation of generic E. coli from freshly cut hay from VTA regions that received basin discharge (12 of 30 vs. 1 of 30 control samples) provided evidence for the risk of contamination; however, neither E. coli O157 or Campylobacter spp. were recovered from the hay following baling. This work indicates that the runoff control system is effective for reducing environmental risk by containing and removing pathogens from feedlot runoff.     

Removal of Cr(VI) from Cr-contaminated groundwater through electrochemical addition of Fe(II)

The conventional chemical reduction-precipitation technique in the removal of Cr(VI) from contaminated groundwater involves a two-step process whereby Cr(VI) is first reduced to Cr(III) at an acidic pH by a reducing agent and in a subsequent step, Cr(III) is precipitated as insoluble hydroxide at an alkaline pH. In a variation of this method, Fe(II) is added electrochemically to the Cr(VI) containing water. From a pure iron electrode, Fe(2+) ions are released into the solution and bring forth the reduction of Cr(VI). At the cathode, H(2)O is reduced whereby the OH(-) ions entering the solution keep the pH of the solution in the alkaline range. This latter fact greatly facilitates simultaneous reduction of Cr(VI) to Cr(III) and co-precipitation of hydroxides of trivalent Cr and Fe. On the basis of a set of experimental data, it is shown that this process is both thermodynamically and kinetically efficient, meaning, with the electrochemical method, rapid and nearly complete removal of Cr(VI) from a groundwater source with both high and low levels of Cr-contamination can be achieved. These factors make the electrochemical process superior to the conventional chemical process in remediation of Cr-contaminated groundwater.