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601.
Floress, Kristin, Jean C. Mangun, Mae A. Davenport, and Karl W.J. Williard, 2009. Constraints to Watershed Planning: Group Structure and Process. Journal of the American Water Resources Association (JAWRA) 45(6):1352‐1360. Abstract: The roles that agencies and other partners play in collaborative watershed management are not always clearly identified. Key factors contributing to group‐level outcomes in watershed groups include both structural and procedural elements. Structural elements include membership systems, project partners, and funding, while procedural elements include leadership, shared vision, and mission development. The current research reports on a case study conducted with a Midwestern watershed group that received Clean Water Act Section 319 funds to undertake a watershed planning process. Data come from focus groups, interviews, public comments, and meeting observation, and were analyzed using grounded theory. Findings of this study indicate that homogenous skill set, discord over group and partner roles, and failed problem identification contributed to the organizational inertia experienced by the watershed group. Implications of this research for groups receiving 319 funds are provided.  相似文献   
602.
Post combustion carbon dioxide (CO2) capture is one of the most commonly adopted technologies for reducing industrial CO2 emissions, which is now an important goal given the widespread concern over global warming. Research on amine-based CO2 capture has mainly focused on improving effectiveness and efficiency of the CO2 capture process. Our research work focuses on studying the relationships among the significant parameters influencing CO2 production because an enhanced understanding of the intricate relationships among the parameters involved in the process is critical for improving efficiency of the CO2 capture process. This paper presents a statistical study that explores the relationships among parameters involved in the amine-based post combustion CO2 capture process at the International Centre for CO2 Capture (ITC) located in Regina, Saskatchewan of Canada. A multiple regression technique has been applied for analysis of data collected at the CO2 capture pilot plant at ITC. The parameters have been carefully selected to avoid issues of multicollinearity, and four mathematical models among the key parameters identified have been developed. The models have been tested, and accuracy of the models is found to be satisfactory. The models developed in this study describe part of the CO2 capture process and can help to predict performance of the CO2 capture process at ITC under different conditions. Some results from a preliminary validation process will also be presented.  相似文献   
603.
Blends of zein and polyvinylpyrrolidone (PVP) were compared based on their tensile properties, thermal properties and morphology. Zein was blended with polyvinylpyrrolidone of varying molecular weights (10, 55, and 1,300 kDa) and films were cast from ethanol solutions. Films cast using the higher molecular weight polymers showed an improvement in tensile strength, up to a 24% increase, compared to control. Differential scanning calorimetry data for the blends showed single Tm and Tg values of an intermediate value between those of zein and PVP control samples. Field emission scanning electron microscopy images show no obvious inhomogeneities, and confocal fluorescence microscopy showed no decreased uniformity in the PVP/zein films compared to control. Electrospun fibers of the zein/PVP blends were also obtained. These findings suggest that zein and polyvinylpyrrolidone combine to form a compatible blend, the first such blend of zein with a synthetic polymer.  相似文献   
604.
A value of statistical life (VSL) is used in cost-benefit analysis (CBA) as a monetary measure of the benefits to people from small risk reductions that arise from safety projects. Despite its widespread use in a number of countries, the concept of a VSL remains controversial, not least because it implies acceptance of the underlying ethical assumptions of CBA together with the idea that ‘social welfare’ can be measured and aggregated in some manner. In addition, to comply with theory, variable VSLs for different groups within society would be advocated. However, without fail, empirically, it is the case that those countries that employ a willingness to pay based approach to cost-benefit analysis of a safety project appraisal tend to use a single value for that accident context that is independent of the per capita income level, or indeed other personal characteristics, of the sub-group in society to which the safety improvement will actually apply. This article presents a straightforward, but theoretically justified adaptation to the calculation of a VSL which allows empirical practice by policymakers i.e. the application of a “common” VSL for any particular hazard within a given society, to be compatible with a CBA decision making approach.  相似文献   
605.
Two cage designs and fingernail clams(Sphaerium fabale) were evaluated for theirsuitability for use in in situ bioassays toassess the ecological condition of a stream andpredict ecological recovery potential. One design(referred to as tray design) was a modified plastictray about one-fourth full of small gravels andcovered with 1 mm fiberglass mesh. The second design(referred to as tube-plates) consisted of shortplexiglass tubes about one-third full of small gravelsand attached horizontally to a plexiglass plate. Oneend of each tube faced into the current; both endswere covered with mesh. Cages containing clams weredeployed at reference and impacted (test) sites forperiods of 70 to 135 d. Growth and survival were theprimary endpoints evaluated, but the tube-platesallowed isolation of individual clams so that natalityalso could be evaluated as an endpoint. Results ofbenthic macroinvertebrate surveys, performed foranother study, were included to help validate bioassayresults. Both cage designs yielded good quantitative,site-specific results for clam survival and growth;results for natality, though, were less conclusive. Clam survival and growth results were in good generalagreement with the results for the benthicmacroinvertebrate community surveys. At a site wherethe macroinvertebrate community was the mostdepauperate, clam mortality was always rapid. At asite where the condition of the macroinvertebratecommunity was only slightly less impacted than themost impacted site, clam growth was almost alwayssignificantly lower than at reference sites. Survivalof clams was significantly reduced in <25 d at thissite in some trials, but in other trials there waslittle mortality. At a minimally impacted site, clamsurvival was similar to that found at reference sites,and differences in clam growth were not detectableuntil after 40 to 50 d of exposure. The tube-platedesign was easier to use, allowed more flexibility inselection of response parameters, and required lesshandling time of test animals, thus, this was thepreferred design. Our results demonstrated thateither in situ bioassay design can be used toaugment monitoring and assessment programs. Their useas a predictor of ecological recovery, however,requires further evaluation.  相似文献   
606.
Riparian buffer restorations are used as management tools to produce favorable water quality impacts, moreover among the many benefits riparian buffers may provide, their application as instruments for water quality restoration rests on a relatively firm foundation of research. However, the extent to which buffers can restore riparian ecosystems; their functionality and species composition, are essentially unknown. In light of the foregoing, two broad areas of research are indicated. First, data are needed to document the relative effectiveness of riparian buffers that differ according to width, length, and plant species composition. These questions, of managing buffer dimension and species composition for functionality, are of central importance even when attenuation of nutrient and sediment loads alone are considered. Second, where ecosystem restoration is the goal, effects to in-stream and terrestrial riparian biota need to be considered. Relatedly, the effects of the restoration on the landscape need to be considered. Particularly, at what rate do the effects of the riparian buffer on in-stream water quality, biota, and habitat diminish downstream from restored sites? Answers to these important questions are needed, for streams and watersheds of different size and for areas of differing soil type within watersheds. U.S. EPA-NRMRL has initiated as research project that will document the potential for buffers to restore riparian ecosystems; focusing on water quality effects, but also, importantly, documenting effects on biota. While substantial riparian buffer management initiatives are already underway, the extent of landscapes that influence riparian ecosystems in the eastern United States is large; leaving ample opportunity for this suggested research to provide improved buffer designs in the future. The ultimate goal of research projects developed under this paradigm of ecosystem restoration is to develop data that are needed to implement riparian buffer restorations in the mid-Atlantic and elsewhere, especially the eastern United States.  相似文献   
607.
Assessments of long-term relationships between changes innutrient inputs and wetland nutrient concentrations can becomplicated by fluctuations in other environmental factors aswell as by problems typical of long-term monitoring data.Consequently, statistical analysisof these types of data sets requirescareful consideration of environmental covariates, potentialbiases in the monitoring design, and irregularities caused bychanges in field sampling protocols. We evaluated therelationship between anthropogenic phosphorus (P) inputs andwater-column total P (TP) concentrations in a northernEverglades marsh by statistically analyzing available datacollected from several sampling programs over the past 20 years(1978–1997). Canal inputs of agricultural runoff contributemost of the P to the marsh and have produced a zone ofenrichment within the marsh during the past few decades.Regression analyses showed that both canal and marsh TPconcentrations increased during the 1980s and then decreased inthe 1990s. However, the statistical relationship between canal Pinputs and marsh TP, while significant, generally was weakexcept for marsh locations adjacent to the canal. Strongerrelationships existed between marsh TP and hydrologic parameterssuch as marsh water depth, which is controlled by changes inweather patterns and marsh management. In particular, dryconditions during the 1980s may have contributed to observedincreases in marsh P concentrations and the movement of a P`front' further into the marsh. Higher rainfall and water depthsand agricultural best management programs initiated during the1990s have been associated with reduced P concentrations incanal waters entering the marsh. While it is anticipated thatthis reduction eventually will result in lower marsh TPconcentrations, this effect is not yet evident, possibly due tointernal loading of P from enriched marsh soils. Our findingsillustrate some of the environmental factors that can complicateattempts to develop empirical relationships between P inputs andwetland P concentrations and to use such relationships to forecast changesin marsh concentrations based on past monitoring data alone.  相似文献   
608.
Total suspended particulate matter and deposition fluxes of particles were investigated in the town of Didouche Mourad which is located 13 km north of Constantine. Samples of air particulate matter were collected at one site located in the heart of the town and situated 3 km north of a cement plant. Samples were collected from 2 November 2002 to 28 April 2003 every 3 days using a high volume air sampler. Sampling intervals were 24 h in all cases. During the same period, samples of dust fallout were collected at the same site. Samples were collected at 30-day intervals. Lead, chromium, manganese, nickel, copper, cobalt and cadmium deposition fluxes were measured and both the soluble and insoluble fractions were determined. Furthermore, the information gathered by this study was correlated with the corresponding hourly weather data provided by a weather station installed at the study station. The possible sources for dust and trace metals were analyzed by comparing average contributions of wind aspects to the concentrations and depositions of mass and chemical species with the average frequencies of wind direction. The mean concentration was 300 μg/m3. The average dust deposition rate through the period of study was 221 mg/(m2.day). Results indicate that anthropogenic sources contribute greatly to trace elements. An exposure assessment to the heavy metals taking into account the inhalation route and soil dust ingestion was carried out and allowed direct comparison of trace metal intakes via these routes.  相似文献   
609.
Foran  J.  Brosnan  T.  Connor  M.  Delfino  J.  DePinto  J.  Dickson  K.  Humphrey  H.  Novotny  V.  Smith  R.  Sobsey  M.  Stehman  S. 《Environmental monitoring and assessment》2000,62(2):147-167
The International Life SciencesInstitute (ILSI) Risk Science Institute (RSI) convenedan expert panel of scientists to developrecommendations for a comprehensive monitoring programfor the Croton and Catskill/Delaware watersheds, whichprovide drinking water to New York City's residents. This effort was conducted as part of efforts topreserve and enhance the quality of New York City'sreservoir system through a watershed protectionprogram. The panel developed recommendations for astrategic framework on which to construct a monitoringprogram. As part of this activity, the paneldetermined whether existing monitoring activities weredeficient and, where activities were deficient, thepanel developed recommendations for additionalinformation that should be collected.The panel recommended the development and use of anintegrated approach to watershed monitoring, whichdraws on modeling, risk-based planning and analysis,statistical sampling and design, and basic compliancemonitoring. The approach should be designed toprovide an assessment of natural and anthropogenicsources of stress to the system as well as anassessment of water quality trends in response tostresses acting in concert, both over the long termand over the five-year New York City Memorandum ofAgreement (MOA) assessment time frame. It should alsoprovide an assessment of the human health andenvironmental risks posed by a variety of stressors,and the impact of management actions implemented toameliorate stressors.  相似文献   
610.
The long-term water quality monitoring program implemented by the Massachusetts Water Resources Authority in 1992 is extensive and has provide substantial understanding of the seasonality of the waters in both Boston Harbor and Massachusetts Bay and the response to improvements in effluent quality and offshore transfer of the effluent in September 2000. The monitoring program was designed with limited knowledge of spatial and temporal variability and long-term trends within the system. This led to an extensive spatial and temporal sampling program. The data through 2003 showed high correlation within physical parameters measured (e.g., salinity, dissolved oxygen) and in biological measures such as chlorophyll fluorescence. To address the potential sampling redundancies in the measurement program, an assessment of the impact of reduced levels of monitoring on the ability to make water quality decisions was completed. The optimization was conducted by applying statistical models that took into account whether there was evidence of a seasonal pattern in the data. The optimization used model survey average readings to identify temporal fixed effects, model survey-average-corrected individual station readings to identify spatial fixed effects, corrected the individual station readings for temporal and spatial fixed effects and derived a correlation model for the corrected data, and applied the correlation model to characterize the correlation of annual average readings from reduced monitoring programs with true parameter levels. Reductions in the number of sampling stations were found less detrimental to the quality of the data for annual decision-making than reductions in the number of surveys per year, although there is less of a difference in this regard for dissolved oxygen than there is for chlorophyll. The analysis led to recommendations for a substantially lower monitoring effort with minimal loss of information. The recommendation supported an annual budget savings of approximately $183,000. Most of the savings was from fewer surveys as approximately $21,000 came from the reduction in the number of stations monitored from 21 to 7 and associated laboratory analytical costs.  相似文献   
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