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41.
Ana Elisa S. Vercelheze André L. M. Oliveira Maria Inês Rezende Carmen M. O. Muller Fábio Yamashita Suzana Mali 《Journal of Polymers and the Environment》2013,21(1):266-274
The objectives of this work were to develop biodegradable trays from cassava starch, sugarcane fibers and Na-montmorillonite (Na-MMT) using a baking process and to study the effects of these components on the physical properties, photo- and bio-degradation of the trays. The sample F20 (produced with 20 g fiber/100 g formulation) showed the maximum yield production (100 %). All formulations resulted in well-shaped trays with densities between 0.1941 and 0.2966 g/cm3. The addition of fibers and Na-MMT resulted in less dense and less rigid trays compared to control samples (only starch). The studied processing conditions resulted in good nanoclay dispersion, leading to the formation of an exfoliated structure. The evaluation of the photo-degradation stability of the trays under UV exposure for 336 h showed that a sample produced with a specific combination of fiber and nanoclay (20 g fiber and 5 g nanoclay/100 g formulation) had the highest loss in stress at break (91 %). Biodegradation assays showed that Control trays (starch) and F20 (20 g fiber/100 g formulation) lost a greater percentage of their weight after 90 days of incubation in soil, with losses of up to 85.50 and 82.70 %, respectively. 相似文献
42.
Sebastião Roberto Soares Alexandra Rodrigues Finotti Vamilson Prudêncio da Silva Rodrigo A.F. Alvarenga 《Waste management (New York, N.Y.)》2013,33(1):175-183
The establishment of rules to manage Health Care Waste (HCW) is a challenge for the public sector. Regulatory agencies must ensure the safety of waste management alternatives for two very different profiles of generators: (1) hospitals, which concentrate the production of HCW and (2) small establishments, such as clinics, pharmacies and other sources, that generate dispersed quantities of HCW and are scattered throughout the city. To assist in developing sector regulations for the small generators, we evaluated three management scenarios using decision-making tools. They consisted of a disinfection technique (microwave, autoclave and lime) followed by landfilling, where transportation was also included. The microwave, autoclave and lime techniques were tested at the laboratory to establish the operating parameters to ensure their efficiency in disinfection. Using a life cycle assessment (LCA) and cost analysis, the decision-making tools aimed to determine the technique with the best environmental performance. This consisted of evaluating the eco-efficiency of each scenario. Based on the life cycle assessment, microwaving had the lowest environmental impact (12.64 Pt) followed by autoclaving (48.46 Pt). The cost analyses indicated values of US$ 0.12 kg?1 for the waste treated with microwaves, US$ 1.10 kg?1 for the waste treated by the autoclave and US$ 1.53 kg?1 for the waste treated with lime. The microwave disinfection presented the best eco-efficiency performance among those studied and provided a feasible alternative to subsidize the formulation of the policy for small generators of HCW. 相似文献
43.
This work is a part of a wider study involving the economic and environmental implications of managing construction and demolition waste (CDW), focused on the operation of a large scale CDW recycling plant. This plant, to be operated in the Lisbon Metropolitan Area (including the Setúbal peninsula), is analysed for a 60 year period, using primary energy consumption and CO2eq emission impact factors as environmental impact performance indicators.Simplified estimation methods are used to calculate industrial equipment incorporated, and the operation and transport related impacts. Material recycling – sorted materials sent to other industries, to act as input – is taken into account by discounting the impacts related to industrial processes no longer needed.This first part focuses on calculating the selected impact factors for a base case scenario (with a 350 tonnes/h installed capacity), while a sensitivity analysis is provided in part two. Overall, a 60 year global primary energy consumption of 71.4 thousand toe (tonne of oil equivalent) and a total CO2eq emission of 135.4 thousand tonnes are expected. Under this operating regime, around 563 thousand toe and 1465 thousand tonnes CO2eq could be prevented by replacing raw materials in several construction materials industries (e.g.: ferrous and non-ferrous metals, plastics, paper and cardboard). 相似文献
44.
Idris Zembouai Stéphane Bruzaud Mustapha Kaci Aida Benhamida Yves-Marie Corre Yves Grohens Aurélie Taguet José-Marie Lopez-Cuesta 《Journal of Polymers and the Environment》2014,22(1):131-139
Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and polylactide (PLA) with different PHBV/PLA weight ratios (100/0, 75/25, 50/50, 25/75, 0/100) were prepared by melt compounding. Their mutual contributions in terms of thermal stability, flammability resistance, mechanical properties and rheological behavior were investigated. The study showed that the increase in PLA content in PHBV/PLA blends leads to enhanced properties. Consequently, thermal stability and flammability resistance were improved. Further, the rheological measurements indicated an increase in storage modulus and loss modulus of PHBV matrix by addition of PLA. 相似文献
45.
Hydrogeochemical considerations about the origin of groundwater salinization in some coastal plains of Elba Island (Tuscany,Italy) 总被引:1,自引:0,他引:1
Elena Giménez-Forcada Alberto Bencini Giovanni Pranzini 《Environmental geochemistry and health》2010,32(3):243-257
Several coastal plains of the Elba Island (Marina di Campo, Portoferraio, Schiopparello, Mola, Porto Azzurro and Barbarossa
plains) in Tuscany (Italy) were studied to determine the causes of decline in groundwater quality, using major ion chemistry
to establish the causes of groundwater salinization. The study demonstrates that salinization of coastal plain alluvial aquifers
is not simply linked to seawater intrusion but is also intimately related to inflows from adjacent aquifers. Ionic ratios,
correlation graphs and distribution value maps were employed as the means to understand the hydrochemistry of the study areas.
The Mg/Cl ratio in particular can be considered a good tracer to distinguish the main salinization processes that control
groundwater chemistry. Seawater intrusion only partly determines the chemistry of some groundwaters, which generally belong
to a chloride facies where the salinity is derived principally from freshwater–seawater mixing and the participation of cation
exchange. Proceeding inland groundwater quality seems to be principally determined by the inflow of Mg, Ca-HCO3 or Ca, Na-HCO3 waters formed from the weathering of silicate minerals in adjoining aquifers. Hydrolysis of these minerals is of prime importance
in controlling groundwater chemistry in adjacent alluvial plains. The lateral recharge flows introduce water with a different
chemical composition and this variable of freshwater recharge changes the hydrochemistry as a result of mixing between two
or more waters types. This situation is further complicated when seawater and base exchange reactions participate, due to
seawater intrusion. 相似文献
46.
Humanity's future depends on the preservation of natural ecosystems that supply resources and absorb pollutants. Rural and urban productions are currently based on chemical products made from petroleum, which are responsible for high negative impacts on the Biosphere. In order to prevent those impacts, efficient public policies seeking for sustainable development are necessary. Aiming to assess the load on the environment (considering the gratuitous contributions of natural systems—a donor's perspective) due to human-dominated process, a scientific tool called Emergy Evaluation has been applied in different production systems, including crops and farms. However, there is still a lack of emergy studies in the context of watersheds, probably due to the difficulty of collecting raw data. The present work aims to carry out an assessment of Mogi-Guaçu and Pardo watershed, through the combined use of Emergy Evaluation and Geographical Information System. The agricultural and natural land uses were considered, while urban areas were excluded. Emergy flows (expressed in seJ ha−1 yr−1) obtained for all agricultural and natural land uses were expanded for the whole watershed and the emergy indices were calculated. The results show that the watershed has: low renewability (%R = 32%); low capture of natural resources through high external economic investment (EYR = 1.86); low dependence on natural resources (EIR = 1.16); and moderate load on the environment (ELR = 2.08). Considering a scenario where sugar-cane crops, orchards and pasture areas are converted from conventional to organic management, watershed's emergy performance improved, reaching a new renewability of 38%, but it is still not enough to be considered sustainable. 相似文献
47.
Gloria Massamba-N’Siala Roberto Simonini Piero Cossu Ferruccio Maltagliati Alberto Castelli Daniela Prevedelli 《Marine Biology》2011,158(7):1523-1535
The spatial scale of life-history and demographic variation was investigated in the opportunistic polychaete Ophryotrocha labronica La Greca and Bacci. Individuals were collected along the Italian coasts from three thermally different biogeographical regions
of the Mediterranean Sea. For each region, populations from four harbours were considered, and for each harbour, two sites
were examined. Life-history and demographic traits were investigated after one generation under a common garden experiment,
and their variation at the three spatial scales was assessed. All the traits showed high variability with regard to site.
A number of life-history and all demographic traits also varied according to the biogeographical region. Conversely, no differences
were found between harbours, suggesting that geographical isolation did not contribute to phenotypic variation. Results confirmed
the central role of local conditions for the evolution of life history in species colonizing heterogeneous environments, but
they also pointed to the importance of large-scale factors in shaping the phenotypic responses of O. labronica, demonstrating the need for a multi-scale approach for obtaining a good measure of natural variation in widespread opportunistic
species. 相似文献
48.
Jorge Alberto Achcar Josmar Mazucheli Emílio Augusto Coelho-Barros 《Environmental and Ecological Statistics》2011,18(2):315-329
In this paper we present a hierarchical Bayesian analysis for a predator–prey model applied to ecology considering the use
of Markov Chain Monte Carlo methods. We consider the introduction of a random effect in the model and the presence of a covariate
vector. An application to ecology is considered using a data set related to the plankton dynamics of lake Geneva for the year
1990. We also discuss some aspects of discrimination of the proposed models. 相似文献
49.
José S. Antunes do Carmo Mechteld ten Voorde Maria G. Neves 《Journal of Coastal Conservation》2011,15(4):531-546
Surfing has becoming more and more attractive in the past few decades, constituting nowadays an important source of revenue
for many countries with extensive coastlines. For this purpose and also for environmental reasons, the conventional ways of
protecting a coastline appear to entail some disadvantages. An innovative and interesting way of improving surfing capacities
and contributing to protect a local coastal zone is by means of multifunctional artificial reefs. A multifunctional artificial
reef (MFAR) is a submerged structure that serves several purposes; in particular, it may enhance the surfing possibilities
and the environmental value of the local area. This structure has some promising new aspects, too: first, it provides an unimpaired
visual amenity; second, it offers tourist and economic benefits by improving the surfing conditions; third, it can enhance
the environmental value of the area where it is built, and fourth, if designed properly, the down drift erosion can be minimal.
An appropriate reef design in terms of ‘surfability’, i.e. the possibility to surf a wave, for the Leirosa beach, located
to the south of Figueira da Foz, midway along Portugal’s West Atlantic coast, has been investigated. In order to achieve the
best design several steps were conducted. First, the performance of the Boussinesq-type COULWAVE model is tested with experimental
data. Next, this numerical model is used to define the best values for three design parameters: reef angle; geometry of the
reef (without or with a platform), and horizontal dimensions for the appropriate geometry. A preliminary design was achieved
step by step, making use of the theory and of the state of the art of multifunctional reefs. This reef geometry is used in
the numerical study. In terms of ‘surfability’ and for the conditions of the local coastline of Leirosa, the following values
were found for the main parameters: a reef angle of 66°; a structure height of 3.20 m; a reef geometry composed of a delta
without a platform; a reef submergence of 1.50 m, and a structure seaward slope of 1:10. 相似文献
50.
José L. Mateos Paloma Fernández Del Pino Francisco J. Gutiérrez Mañero María Ruiz Palomino Juan J. Colon José A. Lucas García 《Chemistry and Ecology》2013,29(2):125-152
Microbial communities (phospholipid fatty acid pattern, bacterial growing strategies, eco-physiological index (EPI) and total bacteria counts, as a number of heterotrophic cuhurable bacteria), substrate-induced respiration (SIR), and nitrogen mineralization were studied in three Mediterranean soils at three different depth levels (A, B and C). Soils were experimentally treated with a final concentration of 1000 ppm of trace metals (Cu2+, Zn2+, Al3+, Fe2+, Pb2+, Ni2+, Mn2+, Cr3+ and Cd2+). Soils were stored in 571 plastic containers for one year, and watered with 1001 during this period. Leachate was recovered through a bottom tap. Samples of the three depths were studied. Soil microbial communities showed different effects to other studies presented in the literature, but carried out on non-Mediterranean soils. Dramatic differences were found between treated soils and untreated ones, but not between soils or horizons. the treated soil displayed a decrease in CFUs, SIR N-mineralization and EPI together with a dominance of r-growing strategists. the relative moles percent of several PLFAs, especially 15:0, 16: 1ω7, cy17: 0, br18:0 and 18: 1ω7 decreased because of the pollution of soils, whereas 10Me16, 18:2ω6, cy19:0, i16:0 and br17:0 showed higher values than in untreated soils. 相似文献