Characterisation of agroindustrial solid residues as biofuels and potential application in thermochemical processes

In the present work, selected agroindustrial solid residues from Brazil – biosolids from meat processing wastewater treatment and mixture of sawdust with these biosolids; residues from apple and orange juice industries; sugarcane bagasse; açaí kernels (Euterpe oleracea) and rice husk – were characterised as solid fuels and an evaluation of their properties, including proximate and ultimate composition, energy content, thermal behaviour, composition and fusibility of the ashes was performed. The lower heating value of the biomasses ranged from 14.31 MJ kg^?1 to 29.14 MJ kg^?1, on a dry and ash free basis (daf), all presenting high volatile matter content, varying between 70.57 wt.% and 85.36 wt.% (daf) what improves the thermochemical conversion of the solids. The fouling and slagging tendency of the ashes was predicted based on the fuel ash composition and on the ash fusibility correlations proposed in the literature, which is important to the project and operation of biomass conversion systems. The potential for application of the Brazilian agroindustrial solid residues studied as alternative energy sources in thermochemical processes has been identified, especially concerning direct combustion for steam generation.     

?kotoxikologie soll endlich wissenschaftliches Fach werden

Ohne Zusammenfassung     

Tillage, crop rotation, and organic amendment effect on changes in soil organic matter

Carbon sequestration in agricultural soils is controlled by the balance of added organic residues and microbial oxidation of both residues and native organic matter (OM) as moderated by management and tillage. The PC-based model CQESTR predicts decomposition of residues, organic amendments and soil OM, based on cropping practices. CQESTR uses RUSLE (Revised Universal Soil Loss Equation) crop rotation and management practice, crop production, and operation databases. These data are supplemented with residue nitrogen and soil OM, bulk density, and layer thickness. CQESTR was calibrated with soil carbon data from 70-year-long experiments at the Research Center at Pendleton, OR. The calibrated model provides estimates with a 95% confidence interval of 0.33% OM. Validation at 11 independent sites resulted in a matching of observed with calculated OM with a 95% confidence interval of 0.55% OM. A 12th site, with a history of severe erosion, provided a poor match.     

Removal of polychlorinated biphenyls from capacitors and pressure-sensitive paper by vacuum thermal recycling

This paper describes a new vacuum thermal recycling (VTR) method for treating discarded polychlorinated biphenyls (PCB)-contaminated capacitors and pressure-sensitive paper. Based on results demonstrating an exceptionally high PCB separation efficiency and recovery ratio from capacitors containing high-concentration PCBs, i.e. > 99.9%, respectively, the presented VTR method is verified to effectively remove PCBs. In addition, associated safety aspects of the employed procedure were confirmed.     

DESIGN AND IMPLEMENTATION OF A COOPERATIVE WATER QUALITY MONITORING PROGRAM IN COLORADO'S BIG THOMPSON WATERSHED1

ABSTRACT: In 1996, the Big Thompson Watershed Forum (BTWF) was formed “to assess and protect the quality of water” in the Big Thompson Watershed in northern Colorado. However, until 1999, water quality monitoring in the watershed was performed by many state, local, and federal agencies with no coordination among programs and with few efforts toward efficiency, data comparability, or information exchange. To better meet the needs of its stakeholders, the BTWF since 1999 has been actively pursuing the design and implementation of a cooperative water quality monitoring program. The program design involved consensus building among the funding participants, primarily drinking water providers. The final design included 38 parameters to be sampled 15 times per year at 24 stream and canal locations plus two reservoirs. Although the collaborative consensus based approach has been successful for the BTWF, this approach has its drawbacks; most notable among these are the time and labor this approach requires. Also, the BTWF struggled with achieving equal representation of all interests, since those agencies that provided funding had the greatest voice in the final product. While a collaborative approach may not always be best for monitoring program design, it should be appropriate for many watershed organizations that face the common problem of severe financial constraints.     

Characterization of composites based on expanded polystyrene wastes and wood flour

This paper aims to evaluate the potential for the use of recycled expanded polystyrene and wood flour as materials for the development of wood plastic composites. The effects of wood flour loading and coupling agent addition on the mechanical properties and morphology of wood thermoplastic composites were examined. In addition, a methodology for the thermo-mechanical recycling of expanded polystyrene waste was developed. The results show that the mechanical properties decreased as the wood flour loading increased. On the other hand, the use of poly(styrene-co-maleic anhydride), SMA, as a coupling agent improved the compatibility between the wood flour and polystyrene matrix and the mechanical properties subsequently improved. A morphological study revealed the positive effect of the coupling agent on the interfacial bonding. The density values obtained for the composites were compared with the theoretical values and showed agreement with the rule of mixtures. Based on the findings of this work, it appears that both recycled materials can be used to manufacture composites with high mechanical properties and low density.     

Exposure reduction of seed treatments through dehusking behaviour of the wood mouse <Emphasis Type="Bold">(</Emphasis><Emphasis Type="Italic">Apodemus sylvaticus</Emphasis><Emphasis Type="Bold">)</Emphasis>

Background, aim and scope  

Seed treatments are widely used on cereals and other annual crops throughout Europe. Most of the formulated pesticide is found on the outside of the seed, the husk. Risk assessments of seed treatments are especially needed for granivorous mice living in the agricultural landscape e.g. for registration using the guidance for risk assessment for birds and mammals (EFSA 2009). The dehusking of seeds before consumption is a known behaviour of these mammals, but so far, no quantitative data on the reduction of exposure of seed treatments by dehusking were published. Therefore, we aimed at providing a first quantitative estimate of this behaviour-related exposure reduction for the wood mouse (Apodemus sylvaticus) with different seed types.     

Lagrangian Sampling for Emerging Contaminants Through an Urban Stream Corridor in Colorado1

Abstract: Recent national concerns regarding the environmental occurrence of emerging contaminants (ECs) have catalyzed a series of recent studies. Many ECs are released into the environment through discharges from wastewater treatment plants (WWTPs) and other sources. In 2005, the U.S. Geological Survey and the City of Longmont initiated an investigation of selected ECs in a 13.8‐km reach of St. Vrain Creek, Colorado. Seven sites were sampled for ECs following a Lagrangian design; sites were located upstream, downstream, and in the outfall of the Longmont WWTP, and at the mouths of two tributaries, Left Hand Creek and Boulder Creek (which is influenced by multiple WWTP outfalls). Samples for 61 ECs in 16 chemical use categories were analyzed and 36 were detected in one or more samples. Of these, 16 have known or suspected endocrine‐disrupting potential. At and downstream from the WWTP outfall, detergent metabolites, fire retardants, and steroids were detected at the highest concentrations, which commonly exceeded 1 μg/l in 2005 and 2 μg/l in 2006. Most individual ECs were measured at concentrations less than 2 μg/l. The results indicate that outfalls from WWTPs are the largest but may not be the sole source of ECs in St. Vrain Creek. In 2005, high discharge was associated with fewer EC detections, lower total EC concentrations, and smaller EC loads in St. Vrain Creek and its tributaries as compared with 2006. EC behavior differed by individual compound, and some differences between sites could be attributed to analytical variability or to other factors such as physical or chemical characteristics or distance from contributing sources. Loads of some ECs, such as diethoxynonylphenol, accumulated or attenuated depending on location, discharge, and distance downstream from the WWTP, whereas others, such as bisphenol A, were largely conservative. The extent to which ECs in St. Vrain Creek affect native fish species and macroinvertebrate communities is unknown, but recent studies have shown that fish respond to very low concentrations of ECs, and further study on the fate and transport of these contaminants in the aquatic environment is warranted.